Citation: YE Hong-De, XING Ze-Sheng, HU Jiu-Rong, PENG Hua-Nan, XIE Jia-Lin, LIU Lin-Hai. Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone[J]. Chinese Journal of Inorganic Chemistry, ;2015, 31(8): 1534-1538. doi: 10.11862/CJIC.2015.138 shu

Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone

1.
1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao, Jiangxi 334001, China;
2.
2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Corresponding author: YE Hong-De,
Received Date: 28 January 2015
Available Online: 20 March 2015
Fund Project: 国家自然科学基金(No.21361022、21261020) (No.21361022、21261020)江西省教育厅2014年度普通本科高校大学生创新创业教育计划项目,南京大学配位化学国家重点实验室第25批开发课题,第54批中国博士后科学基金面上基金(No.2013M541640)资助项目。 (No.2013M541640)

o-Carborane reacts with n-butyllithium, sulfur powder and Me₄CpCo(CO)I₂ respectively to give the half-sandwich 16e carborane compound Me₄CpCoS₂C₂B₁₀H₁₀ (1). The reaction of 1 with ferrocenyne ketone in dichloro-methane leads to the product {(Me₄CpCoS₂C₂B₁₀H₁₀)[FcC(O)CHCCHCC(O)Fc]} (2) (Fc=ferrocenyl). 2 is a 1:2 adduct. The alkynone is twofold inserted into one Co-S bond of 2 in a head-tail mode. 1 and 2 have been characterized by IR, NMR, elemental analysis, mass spectrum and single-crystal X-ray diffraction analysis. CCDC: 1045890, 1; 1045891, 2.
- half-sandwich;carborane;ferrocenyne ketone;characterization
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Reactivity of Half-Sandwich 16e Carborane Compound Me₄CpCoS₂C₂B₁₀H₁₀ with Ferrocenyne Ketone