Citation: SUN Yin-Xia, LU Rui-E, LI Xin-Ran, ZHAO Ya-Yuan, LI Chun-Yu. A Schiff Base Ligand Containing Oxime Group and its Cu(Ⅱ) Complex: Syntheses and Supramolecular Structures[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1055-1062. doi: 10.11862/CJIC.2015.134 shu

A Schiff Base Ligand Containing Oxime Group and its Cu(Ⅱ) Complex: Syntheses and Supramolecular Structures

1.
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: SUN Yin-Xia,
Received Date: 3 January 2015
Available Online: 28 March 2015
Fund Project: 兰州交通大学青年科学基金(No.2011007) (No.2011007)兰州交通大学研究生教改项目(No.160012)资助。 (No.160012)

A Schiff base chelating ligand containing oxime group, 1-(4-{[(E)-5-chloro-2-hydroxybenzylidene]amino}phenyl)ethanone O-benzyloxime (HL, C₁₅H₁₆N₂O) and its Cu(Ⅱ) complex ([CuL₂]) have been synthesized and characterized by elemental analyses, IR spectra, UV-Vis spectra and X-ray single crystal diffraction method. In the crystal structure of HL, the intermolecular Cl…Cl halogen bonding interaction links a pair of HL molecules to form a dimer unit with the Cl…Cl distance of 0.3459(3) nm, and every dimer further links four other adjacent dimer units into an infinite 3D supramolecular networks structure containing 1D rectangle channels by intermolecular C-H…π interactions. The structure of the Cu(Ⅱ) complex is a mononuclear, consists of one Cu(Ⅱ) atoms, two bidentate L^- units. The Cu(Ⅱ) atom is in a square-planar geometry. And each Cu(Ⅱ) complex molecule links four other molecules into an infinite 2D layer supramolecular structure by intermolecular C-H…π interactions. This linkage is further stabilized by π…π stacking interactions with the centroid-centroid distances of 0.3689(3) nm.
- Schiff base ligand;crystal structure;Cu(Ⅱ) complex
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沈阳化工大学材料科学与工程学院沈阳 110142