Citation: QI Xiao-Jiao, WANG Qian, GAO Hai-Yan, LI Guo-Dong. Hollow Spindle-Shaped CuO/Cu₂(OH)₂CO₃ Nanocomposites: Synthesis and Gas Sensing Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1010-1018. doi: 10.11862/CJIC.2015.129 shu

Hollow Spindle-Shaped CuO/Cu₂(OH)₂CO₃ Nanocomposites: Synthesis and Gas Sensing Property

QI Xiao-Jiao ¹ ,
WANG Qian ¹ ,
GAO Hai-Yan ¹ ,
^1,, ,
LI Guo-Dong ²

1.
1 Tianjin Key Laboratory of Fiber Modification and Functional Fiber, School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin, 300387, China;
2.
2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: ,
Received Date: 26 November 2014
Available Online: 10 February 2015
Fund Project: 国家自然科学基金(No.21271138,21371070,21071060) (No.21271138,21371070,21071060)天津自然科学基金(No.14JCYBJC17500,14JCQNJC02500) (No.14JCYBJC17500,14JCQNJC02500)吉林大学无机合成与制备化学国家重点实验室开放课题(No.2015-02) (No.2015-02)国家大学生创新创业计划项目(201410058003)资助。 (201410058003)

Hollow spindle-shaped CuO/Cu₂(OH)₂CO₃ composites were fabricated via a templateless hydrothermal route with Cu₂(OH)₃NO₃ as the precursor. XRD measurements and TEM observations reveal that the as-prepared CuO/Cu₂(OH)₂CO₃ is hollow spindle-shaped with size of 1~2 μm. HRTEM image indicates that the shell of each particle is highly dispersive mixtures of nanoscale CuO and Cu₂(OH)₂CO₃. Time dependent experiments disclose that the formation of hollow spindle-shaped CuO/Cu₂(OH)₂CO₃ composites particles is driven by self-transformation and Ostwald ripening. The gas sensing performances were investigated with ethanol and acetone as the target gases. The as-prepared hollow CuO/Cu₂(OH)₂CO₃ composites exhibit improved gas sensing properties in comparison with the commercial CuO powders, which can be ascribed to the decreased grain-to-grain contacts of the highly dispersive mixtures.
- hollow particles;solvothermal synthesis;CuO;Cu₂(OH)₂CO₃;gas sensor
1. [1]
  [1] Steinhauer S, Brunet E, Maier T, et al. Sens. Actuators B, 2013,187:50-57
2. [2]
  [2] Chen J J, Wang K, Hartman L, et al. J. Phys. Chem. C, 2008,122(41):17-21
3. [3]
  [3] Lee J H. Sens. Actuators B, 2009,140(1):319-336
4. [4]
  [4] Zhou L J, Zou Y C, Zhao Y J, et al. Sens. Actuators B, 2013,188:533-539
5. [5]
  [5] Qin Y, Zhang F, Chen Y, et al. J. Phys. Chem. C, 2012,116 (22):1994-2000
6. [6]
  [6] Steinhauer S, Brunet E, Maier T, et al. Procedia Eng., 2012,47(9):17-20
7. [7]
  [7] Zhu G X, Xu H, Xiao Y Y, et al. ACS Appl. Mater. Interfaces, 2012,4(2):744-751
8. [8]
  [8] Wang X Q, Xi G C, Xiong S L, et al. Cryst. Growth Des., 2007,7(5):930-934
9. [9]
  [9] Shin H S, Song J Y, Yu J. Mater. Lett., 2009,63(3):397-399
10. [10]
  [10] L iu Y, Huang H W, Peng X S. Electrochim. Acta, 2013, 104:89-94
11. [11]
  [11] Liu J P, Huang X T, Li Y Y. Cryst. Growth Des., 2006,6(7): 1691-1696
12. [12]
  [12] Duan Y Y, Liu X, Han L, at el. J. Am. Chem. Soc., 2014, 136(20):7193-7196
13. [13]
  [13] Li D, He Y J, Wang S. J. Phys. Chem. C, 2009,133(30): 12927-12929
14. [14]
  [14] Yang R C, Tang D X, Tao T X, et al. Mater. Lett., 2013, 113:156-158
15. [15]
  [15] Wang S L, Li P G, Zhu H W, et al. Powder Technol., 2012,230:48-53
16. [16]
  [16] Dey K K, Kumar A, Shanker R, et al. RSC Adv., 2012,2(4): 1387-1403
17. [17]
  [17] Zhang Y, Wang S T, Qian Y T, et al. Solid State Sci., 2006,8(5):462-466
18. [18]
  [18] Kim S J, Na C W, Hwang I S, et al. Sens. Actuators B, 2012, 168(1):83-89
19. [19]
  [19] Wang C X, Yin L W, Zhang L Y, et al. Sensors, 2010,10(3): 2088-2106
20. [20]
  [20] Zhang Y, He X L, Li J P, et al. Sens. Actuators B, 2007, 128(1):293-298
21. [21]
  [21] Dubal D P, Gund G S, Lokhande C D, et al. Mater. Res. Bull., 2013,48(2):923-928
22. [22]
  [22] Zhang W X, Wang H, Zhang Y M, et al. Electrochim. Acta, 2013,113:63-68
23. [23]
  [23] WU Jian-Peng(吴建鹏), CAO Li-Yun(曹丽云), ZHANG Guo-Yun(张国运), et al. J. Instrum. Anal. (仪器分析学报), 2006,25(4): 95-97
24. [24]
  [24] Juodkazyte J, Sebeka B, Savickaja I, et al. Electrochim. Acta, 2013,98:109-115
25. [25]
  [25] Endut Z, Hamdi M, Basirun W J. Thin Solid Films, 2013,528(1):213-216
26. [26]
  [26] Harish S, Navaneethan M, Archana J, et al. Mater. Lett., 2014,121(4):129-132
27. [27]
  [27] Anandan S, Lee G J, Wu J J. Ultrason. Sonochem., 2012,19 (3):682-686
28. [28]
  [28] Dar M A, Ahsanulhaq Q, Kim Y S, et al. Appl. Surf. Sci., 2009,255(12):6279-6284
29. [29]
  [29] Li R, Du J M, Luanc Y X, et al. Sens. Actuators B, 2012, 168:56-64
30. [30]
  [30] Kim J, Kim W, Yong K J. J. Phys. Chem. C, 2012,116(29): 15682-15691
31. [31]
  [31] Yang C, Su X T, Wang J D, et al. Sens. Actuators B, 2013, 185:59-65
32. [32]
  [32] Barsan N, Simion C, Heine T, et al. J. Electroceram., 2010,25(1):11-9
1. [1]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
2. [2]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
5. [5]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
6. [6]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
7. [7]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
8. [8]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
9. [9]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
10. [10]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
11. [11]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
12. [12]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
13. [13]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
14. [14]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
15. [15]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
16. [16]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
17. [17]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
18. [18]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
19. [19]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
20. [20]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(408)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hollow Spindle-Shaped CuO/Cu2(OH)2CO3 Nanocomposites: Synthesis and Gas Sensing Property

Metrics

通讯作者: 陈斌, bchen63@163.com

Hollow Spindle-Shaped CuO/Cu₂(OH)₂CO₃ Nanocomposites: Synthesis and Gas Sensing Property