Citation: ZHU Hui-Min, WANG Dong, YU Yong, DUAN Yong-Xin, PANG Shu-Ping, CUI Guang-Lei. Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1003-1009. doi: 10.11862/CJIC.2015.126 shu

Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor

1.
1 Key Laboratory of Rubber and Plastics Ministry of Education, Institute of polymer, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;
2.
2 Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology, Qingdao Institute of Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong 266101, China

Corresponding author: PANG Shu-Ping,
Received Date: 13 November 2014
Available Online: 1 March 2015
Fund Project: 国家自然科学基金(No.51202266) (No.51202266)青岛研究项目(No.13-1-4-228-jch)资助。 (No.13-1-4-228-jch)

Formamidine lead iodine becomes extremely promising for its highly thermal stability and narrow band gap. In this work, we have employed a hydroxyl iodine lead precursor to replace lead chloride and lead iodide to fabricate a pure phase formamidine lead iodine perovskite in mesoscopic solar cells based on the one-step solution processing method and then studied the effect of annealing temperature on the material crystallinity, the morphology of capping layer and devices efficiency etc. Compared with the traditional solution processing methods, the hydroxyl iodine lead derived formamidine lead iodine film delivers an improved textured structure and thermal stability. As a result, a short circuit photocurrent density of 18.6 mA·cm^-2, an open circuit voltage of 0.67 mV, fill factor of 0.47, and a power conversion efficiency of 5.8% are achieved under the simulated AM 1.5G one sun illumination.
- Pb(OH)I;FAPbI₃;perovskite;one-step spin-coating
1. [1]
  [1] Chen H W, Pan X, Liu W Q, et al. Chem. Commun., 2013, 49:7277-7279
2. [2]
  [2] Stranks S D, Eperon G E, Grancini G, et al. Science, 2013, 342(6156):341-344
3. [3]
  [3] Park N G. J. Phys. Chem. Lett., 2013,4(15):2423-2429
4. [4]
  [4] Qiu J H, Qiu Y C, Yan K Y, et al. Nanoscale, 2013,5(8): 3245-3248
5. [5]
  [5] Rhee J H, Chung C C, Diau EW-G, et al. NPG Asia Mater., 2013,5(10):e68 (DOI:10.1038/am.2013.53)
6. [6]
  [6] Lee J W, Seol D J, Cho A N, et al. Adv. Mater., 2014,26 (29):4991-4998
7. [7]
  [7] Jeon N J, Lee J, Noh J H, et al. J. Am. Chem. Soc., 2013,135(51):19087-19090
8. [8]
  [8] Krishnamoorthy T, Kunwu F, Boix P P, et al. J. Phys. Chem. A, 2014,2(18):6305-6309
9. [9]
  [9] Hodes G, Cahen D. Nat. Photon., 2014,8(2):87-88
10. [10]
  [10] Koh Teck Ming, Fu Kunwu, Fang Yanan, et al. J. Phys. Chem. C, 2014,118(30):16458-16462
11. [11]
  [11] Eperon G E, Stranks S D, Menelaou C, et al. Energy Environ. Sci., 2014,7(3):982-988
12. [12]
  [12] Pang S P, Hu H, Zhang J, et al. Chem. Mater., 2014,26(3): 1485-1491
13. [13]
  [13] Lü S L, Pang S P, Zhou Y Y, et al. Phys. Chem. Chem. Phys., 2014,16(36):19206-19211
14. [14]
  [14] Zhu G Q, Liu P, Hojamberdiev M, et al. Appl. Phys. A., 2009,98(2):299-304
15. [15]
  [15] WANG Dong(王栋), ZHU Hui-Min(朱慧敏), ZHOU Zhong-Min(周忠敏), et al. Acta Phys. Sin. (物理学报), 2015,3(64): 38403-38411
16. [16]
  [16] Pellet N, Gao P, Gregori G, et al. Angew. Chem. Int. Ed., 2014,53(12):3151-3157
17. [17]
  [17] YANG Zhi-Sheng(杨志胜), YANG Li-Gong(杨立功), WU Gang(吴刚), et al. Acta Chim. Sin.(化学学报), 2011,6 (69):627-632
18. [18]
  [18] Chen Q, Zhou H P, Hong Z R, et al. J. Am. Chem. Soc., 2014,136(2):622-625
19. [19]
  [19] Conings B, Baeten L, De Dobbelaere C, et al. Adv. Mater., 2014,26(13):2041-2046
20. [20]
  [20] Zhao Y X, Zhu K. J. Phys. Chem. Lett., 2014,23(5):4175-4186
1. [1]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
2. [2]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
3. [3]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
4. [4]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
5. [5]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
6. [6]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
7. [7]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
8. [8]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
9. [9]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
10. [10]
  Xiaojun Wu , Kai Hu , Faqiong Zhao . Laying the Groundwork for General Chemistry Experiment Teaching: Exploration and Summary of Assisting Experiment Preparatory Work through Online and Offline Integration. University Chemistry, 2024, 39(8): 23-27. doi: 10.3866/PKU.DXHX202312052
11. [11]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
12. [12]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
13. [13]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
14. [14]
  Botao Gao , He Qi , Hui Liu , Jun Chen . Role of polarization evolution in the hysteresis effect of Pb-based antiferroelecrtics. Chinese Chemical Letters, 2024, 35(4): 108598-. doi: 10.1016/j.cclet.2023.108598
15. [15]
  Runze Xu , Rui Liu . U-Pb Dating in the Age of Dinosaurs. University Chemistry, 2024, 39(9): 243-247. doi: 10.12461/PKU.DXHX202404083
16. [16]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
17. [17]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
18. [18]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
19. [19]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
20. [20]
  Xin Li , Xuan Ding , Junkun Zhou , Hui Shi , Zhenxi Dai , Jiayi Liu , Yongcun Ma , Penghui Shao , Liming Yang , Xubiao Luo . Utilizing synergistic effects of bifunctional polymer hydrogel PAM-PAMPS for selective capture of Pb(Ⅱ) from wastewater. Chinese Chemical Letters, 2024, 35(7): 109158-. doi: 10.1016/j.cclet.2023.109158

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(838)
HTML views(175)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142