Citation:
ZHU Hui-Min, WANG Dong, YU Yong, DUAN Yong-Xin, PANG Shu-Ping, CUI Guang-Lei. Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor[J]. Chinese Journal of Inorganic Chemistry,
;2015, (5): 1003-1009.
doi:
10.11862/CJIC.2015.126
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Formamidine lead iodine becomes extremely promising for its highly thermal stability and narrow band gap. In this work, we have employed a hydroxyl iodine lead precursor to replace lead chloride and lead iodide to fabricate a pure phase formamidine lead iodine perovskite in mesoscopic solar cells based on the one-step solution processing method and then studied the effect of annealing temperature on the material crystallinity, the morphology of capping layer and devices efficiency etc. Compared with the traditional solution processing methods, the hydroxyl iodine lead derived formamidine lead iodine film delivers an improved textured structure and thermal stability. As a result, a short circuit photocurrent density of 18.6 mA·cm-2, an open circuit voltage of 0.67 mV, fill factor of 0.47, and a power conversion efficiency of 5.8% are achieved under the simulated AM 1.5G one sun illumination.
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