Citation: ZHU Hui-Min, WANG Dong, YU Yong, DUAN Yong-Xin, PANG Shu-Ping, CUI Guang-Lei. Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 1003-1009. doi: 10.11862/CJIC.2015.126 shu

Solution Processed Hybrid Formamidine Lead Iodine Solar Cells Based on Pb(OH)I Precursor

1.
1 Key Laboratory of Rubber and Plastics Ministry of Education, Institute of polymer, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China;
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2 Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology, Qingdao Institute of Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong 266101, China

Corresponding author: PANG Shu-Ping,
Received Date: 13 November 2014
Available Online: 1 March 2015
Fund Project: 国家自然科学基金(No.51202266) (No.51202266)青岛研究项目(No.13-1-4-228-jch)资助。 (No.13-1-4-228-jch)

Formamidine lead iodine becomes extremely promising for its highly thermal stability and narrow band gap. In this work, we have employed a hydroxyl iodine lead precursor to replace lead chloride and lead iodide to fabricate a pure phase formamidine lead iodine perovskite in mesoscopic solar cells based on the one-step solution processing method and then studied the effect of annealing temperature on the material crystallinity, the morphology of capping layer and devices efficiency etc. Compared with the traditional solution processing methods, the hydroxyl iodine lead derived formamidine lead iodine film delivers an improved textured structure and thermal stability. As a result, a short circuit photocurrent density of 18.6 mA·cm^-2, an open circuit voltage of 0.67 mV, fill factor of 0.47, and a power conversion efficiency of 5.8% are achieved under the simulated AM 1.5G one sun illumination.
- Pb(OH)I;FAPbI₃;perovskite;one-step spin-coating
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沈阳化工大学材料科学与工程学院沈阳 110142