Citation: WANG Ji-Xiao, WANG Che, GAO Xue, WANG Zhi-Nan, ZHANG Xiao-Xi, FENG Xiao-Dong, WEI Si-Yue, XING Yong-Heng, SHI Zhan. Copper(Ⅱ) and Cobalt(Ⅱ) Complexes with Arene-Linked Pyrazolyl Methane: Syntheses, Structures and Mimicking Catalytic Activity in Brominating Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 923-929. doi: 10.11862/CJIC.2015.122 shu

Copper(Ⅱ) and Cobalt(Ⅱ) Complexes with Arene-Linked Pyrazolyl Methane: Syntheses, Structures and Mimicking Catalytic Activity in Brominating Reaction

1.
1 College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China;
2.
2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: WANG Che, XING Yong-Heng,
Received Date: 17 November 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(No.21071071、21371086) (No.21071071、21371086)辽宁省科学事业公益基金(No.2014003019) (No.2014003019)无机合成与制备化学国家重点实验室(吉林大学)开放课题基金(No.2013-05)资助项目。 (吉林大学)开放课题基金(No.2013-05)

Two complexes [Cu(L₁)Cl₂]·0.5C₂H₅OH (1) and Co(L₁)Cl₂ (2) (L₁=1,4-bis((1H-pyrazol-1-yl)methyl)benzene) were designed and synthesized in the anhydrous ethanol system. The spectrum and structural characters of the two complexes were analyzed by elemental analysis, IR spectrum, thermogravimetric analysis, powder X-ray diffraction and single crystal X-ray diffraction analysis. The structural analysis shows that the coordination numbers of metal in complexes 1 and 2 are five and four to form square pyramidal and distorted tetrahedron geometry, respectively, and ligand L1 is in bidentate coordination mode. In addition, complexes 1 and 2 had the mimic catalytic activity during brominating reaction process.
- 1,4-bis((1H-pyrazol-1-yl)methyl)benzene;mimic catalytic activity;copper complex;cobalt complex;crystal structure
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