Citation: CUI Ya-Juan, FANG Rui-Mei, SHANG Hong-Yan, SHI Zhong-Hua, GONG Mao-Chu, CHEN Yao-Qiang. Effect of Support Materials on Property and Catalytic Performance of Pd-Only Three-Way Catalyst[J]. Chinese Journal of Inorganic Chemistry, ;2015, (5): 989-1002. doi: 10.11862/CJIC.2015.120 shu

Effect of Support Materials on Property and Catalytic Performance of Pd-Only Three-Way Catalyst

CUI Ya-Juan ¹ ,
FANG Rui-Mei ² ,
SHANG Hong-Yan ² ,
SHI Zhong-Hua ^3,4,5 ,
GONG Mao-Chu ^3,4,5 ,
CHEN Yao-Qiang ^1,2,3,4,5,,

1.
1 College of Architecture and Environment, Sichuan University, Sichuan, Chengdu 610065, China;
2.
2 College of Chemical Engineering, Sichuan University, Sichuan, Chengdu 610065, China;
3.
3 Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Sichuan, Chengdu 610064, China;
4.
4 Center of Engineering of Vehicular Exhaust Gases Abatement, Sichuan Province, Sichuan, Chengdu 610064, China;
5.
5 Center of Engineering of Environmental Catalytic Material, Sichuan Province, Sichuan, Chengdu 610064, China

Corresponding author: CHEN Yao-Qiang,
Received Date: 8 November 2014
Available Online: 13 February 2015
Fund Project: 国家自然科学基金(No.21173153) (No.21173153)四川省科技厅科技支撑项目(2011GZ0035)资助。 (2011GZ0035)

Four kinds of support materials, i.e. a thermally stable material La₂O₃-Al₂O₃(LA), three oxygen storage materials CeO₂-ZrO₂-La₂O₃-Al₂O₃(CZLA), CeO₂-ZrO₂-La₂O₃+La₂O₃-Al₂O₃(CZL+LA) and CeO₂-ZrO₂-La₂O₃(CZL) with ceria content of 15%, 33% and 47%, respectively, were prepared by co-precipitation. The corresponding Pd-only catalysts Pd/LA, Pd/CZLA, Pd/CZL+LA and Pd/CZL were obtained by wet-impregnation and further fabricated as three-way catalysts in a monolith form. The support materials were characterized by low temperature nitrogen adsorption-desorption and H₂-temperature programmed reduction (H₂-TPR). The catalysts were characterized by H₂-TPR and XPS, and were evaluated with a simulated automobile exhaust in terms of the relationships of three way performance with the air/fuel operation window and with temperatures. The results indicate that the support material CZLA integrates the advantages of ceria-based and alumina-based materials effectively thus having superior textural property, thermal stability and reduction property. Additionally, Pd/CZLA catalyst shows little difference in low temperature reducibility, surface elemental distribution and elemental oxidation states before and after aging treatment. As a result, Pd/CZLA exhibits the widest air/fuel operation window and the lowest light-off temperature among the four catalysts, especially after aging treatment, the light-off temperature of C₃H₈, NO_x and CO is 370 ℃, 257 ℃, 223 ℃, respectively. Then material CZLA is the most suitable support for Pd-only three-way catalyst compared with the other three supports.
- palladium;catalysts;Heterogeneous catalysis;support materials;textural properties;thermal stability;Pd-only three-way catalysts;catalytic performance
1. [1]
  [1] Wang Q Y, Li G F, Zhao B, et al. Appl. Catal. B: Environ., 2010,101(1/2):150-159
2. [2]
  [2] Matsumoto S I. Catal. Today, 2004,90(3/4):183-190
3. [3]
  [3] Shelef M, McCabe R W. Catal. Today, 2000,62(1):35-50
4. [4]
  [4] Kašpar J, Fornasiero P. J. Solid State Chem., 2003,171(1/2): 19-29
5. [5]
  [5] Farrauto R J, Heck R M. Catal. Today, 1999,51(3/4):351-360
6. [6]
  [6] Tomašić V, Jović F. Appl. Catal. A: Gen., 2006,311:112-121
7. [7]
  [7] Gandhi H S, Graham G W, McCabe R W. J. Catal., 2003, 216(1/2):433-442
8. [8]
  [8] Lan L, Chen S H, Zhao M, et al. J. Mol. Catal. A:Chem. 2014,394:10-21
9. [9]
  [9] Talo A, Lahtinen J, Hautojärvi P. Appl. Catal. B:Environ., 1995,5(3):221-231
10. [10]
  [10] CAI Li(蔡黎), CHEN Shan-Hu(陈山虎), ZHAO Ming(赵明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(3): 474-479
11. [11]
  [11] Iwamoto M, Zengyo T, Hernandez A M, et al. Appl.Catal. B: Environ., 1998,17(3):259-266
12. [12]
  [12] Kolli T, Lassi U, Rahkamaa-Tolonen K, et al. Appl. Catal. A: Gen., 2006,298:65-72
13. [13]
  [13] HE Sheng-Nan(何胜楠), CUI Ya-Juan(崔亚娟), YAO Yan-Ling(姚艳玲), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2011,27(5):1157-1162
14. [14]
  [14] Wilcox L, Burnside G, Kiranga B, et al. Chem. Mater., 2003, 15(1):51-56
15. [15]
  [15] Kašpar J, Fornasiero P, Hickey N. Catal. Today, 2003,77(4): 419-449
16. [16]
  [16] Kašpar J, Fornasiero P, Graziani M. Catal. Today, 1999,50 (2):285-298
17. [17]
  [17] Morikawa A, Suzuki T, Kanazawa T, et al. Appl. Catal. B: Environ., 2008,78(3/4)210-221
18. [18]
  [18] CUI Ya-Juan(崔亚娟), HE Sheng-Nan(何胜楠), FANG Rui-Mei(方瑞梅), et al. Chinese. J. Catal.(催化学报), 2013,33 (6):1020-1026
19. [19]
  [19] WANG Xing-Yi(王幸宜), LU Guan-Zhong(卢冠忠), JIN Liu-Wei(金柳伟). J. Chinese Rare Earth Soc.(中国稀土学报), 1995,13(2):128-131
20. [20]
  [20] Papavasiliou A, Tsetsekou A, Matsouka V, et al. Appl. Catal. B: Environ., 2009,90(1/2):162-174
21. [21]
  [21] Li C L, Gu X, Wang Y Q, et al. J. Rare Earth, 2009,27(2): 211-215
22. [22]
  [22] López Granados M, Gurbani A, Mariscal R, et al. J. Catal., 2008,256(2):172-182
23. [23]
  [23] Leofanti G, Padovan M, Tozzola G, et al. Catal. Today, 1998, 41(1/2/3):207-219
24. [24]
  [24] Wang Q Y, Zhao B, Li G F, et al. Environ. Sci. Technol, 2010,44(10):3870-3875
25. [25]
  [25] Jen H W, Graham G W, Chun W, et al. Catal. Today, 1999, 50(2):309-328
26. [26]
  [26] TANG Shi-Yun(唐石云), JIAO Yi(焦毅), LI Xiao-Shuang (李小双), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(5):965-970
27. [27]
  [27] Rumruangwong M, Wongkasemjit S. Appl. Organomet. Chem., 2006,20(10):615-625
28. [28]
  [28] Mejía-Centeno I, Castillo S, Fuentes G A. Appl. Catal. B:Environ., 2012,119-120:234-240
29. [29]
  [29] Guo Y, Lu G Z, Zhang Z G, et al. Catal. Today, 2007,126(3/4):296-302
30. [30]
  [30] Sun K P, Lu W W, Wang M, et al. Appl. Catal. A:Gen., 2004,268(1/2):107-113
31. [31]
  [31] Barrera A, Viniegra M, Fuentes S, et al. Appl. Catal. B: Environ., 2005,56(4),279-288
32. [32]
  [32] Luo M F, Zheng X M. Appl. Catal. A:Gen., 1999,189(1):15-21
33. [33]
  [33] Costa C N, Christou S Y, Georgiou G, et al. J. Catal., 2003, 219(2):259-272
34. [34]
  [34] Lambrou P S, Efatathiou A M. J. Catal., 2006,240(2): 182-193
35. [35]
  [35] Li G F, Wang Q Y, Zhao B, et al. Appl. Catal. B:Environ., 2011,105(1/2):151-162
36. [36]
  [36] Nelson A E, Schulz K H. Appl. Surf. Sci., 2003,210(3/4): 206-221
37. [37]
  [37] Zhao B, Li G F, Ge C H, et al. Appl. Catal. B:Environ., 2010,96(3/4):338-349
38. [38]
  [38] Bozo C, Guilhaume N, Herrmann J M. J. Catal., 2001,203 (2):393-406
39. [39]
  [39] Polona V, Fornasiero P, Kašpar J, et al. J. Catal., 1997, 171(1):160-168
40. [40]
  [40] Winkler A, Dimopoulos P, Hauert R, et al. Appl. Catal. B: Environ., 2008,84(1/2):162-169
41. [41]
  [41] Weng X L, Zhang J Y, Wu Z B, et al. Appl. Catal. B: Environ., 2011,103(3/4):453-461
42. [42]
  [42] Liu Y Y, Hayakawa T, Ishii T, et al. Appl. Catal. A:Gen., 2001,210(1/2):301-314
43. [43]
  [43] Hu Z, Wan C Z, Lui Y K, et al. Catal. Today, 1996,30(1/2/3):83-89
44. [44]
  [44] He H, Dai H X, Au C T. Catal. Today, 2004,90(3/4):245-254
45. [45]
  [45] Wang X Y, Kang Q, Li D. Appl. Catal. B:Environ., 2009, 86(3/4):166-175
46. [46]
  [46] Bourane A, Derrouiche S, Bianchi D. J. Catal., 2004,228 (2):288-297
47. [47]
  [47] YANG Chun-Yan(杨春雁), YANG Wei-Ya(杨卫亚), LING Feng-Xiang(凌凤香), et al. Chem. Ind. Eng. Prog.(化工进展), 2010,29(8):1468-1473
48. [48]
  [48] Sekizawa K, Widjaja H, Maeda S, et al. Appl. Catal. A: Gen., 2000,200(1/2):211-217
49. [49]
  [49] SHANG Hong-Yan(尚鸿燕), WAGN Yun(王云), GONG Mao-Chu(龚茂初), et al. J. Energ. Chem.(能源化学:英文版), 2012,21(4):393-399
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
4. [4]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
5. [5]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
6. [6]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
7. [7]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
8. [8]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
9. [9]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
10. [10]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
13. [13]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
16. [16]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
17. [17]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
18. [18]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
19. [19]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
20. [20]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(393)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142