Citation: HE Zhong-Bing, LIU Shao-You, YANG Hong-Yun, MIN Zong-Yi, NIE Xin. Sulfur Doped Tin Oxide Nanoparticles: Solid State Synthesis and Performance for Visible-Light Driven Photocatalytic Degradation of Paraquat[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 649-658. doi: 10.11862/CJIC.2015.117 shu

Sulfur Doped Tin Oxide Nanoparticles: Solid State Synthesis and Performance for Visible-Light Driven Photocatalytic Degradation of Paraquat

1.
1 College of Chemistry and Materials Engineering, Kaili University, Kaili, Guizhou 556011, China;
2.
2 College of Envirnomental Science and Engineering, Hunan University, Changsha 410082, China;
3.
3 School of Envirnomental Studies, Guangxi University, Nanning 530004, China

Corresponding author: LIU Shao-You,
Received Date: 1 September 2014
Available Online: 8 February 2015
Fund Project: 贵州省科技创新人才团队建设基金项目(黔科人字[2013]4029) (黔科人字[2013]4029)贵州省材料物理与化学特色重点学科建设基金项目(黔教高发[2011]208) (黔教高发[2011]208)贵州省教育厅特色重点实验室建设基金项目(黔教高发[2012]196) (黔教高发[2012]196)贵州省教育厅市州地普通本科高校教育质量提升科研项目(黔教高发 [2011]278-01)资助。 (黔教高发 [2011]278-01)

Sulfur doped tin oxide (S-SnO₂) nanoparticles with high visible light-driven activity was synthesized by a facile solid state synthesis approach at low temperature using sodium dodecyl benzene sulfonate (SDBS) as a template. The samples were characterized by XRD, XPS, SEM, UV-Vis, HR-TEM, and FTIR. The doping mechanism and photocatalytic degradation of paraquat under visible light irradiation were investigated. The results show that the SDBS has a significant regulating effect on the surficial structure for both SnO₂ and S-SnO₂ prepared by solid state synthesis. The S element is successfully incorporated into the lattice of SnO₂ with S(Ⅳ) and S(Ⅵ) rather than embeds into the interstice of SnO₂ lattice. S-doping enhances the photocatalytic activity of SnO₂ due to the presence of a large number of hydroxyls on the surface and S(Ⅵ) in the lattice of SnO₂ benefiting the light absorption and effective charge separation, and it follows an order of SnO₂ < S-SnO₂ < SnO_2(SDBS) < S-SnO_2(SDBS).
- S-doped;SnO₂;solid state synthesis;photocatalytic degradation;paraquat
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