Citation: HE Zhong-Bing, LIU Shao-You, YANG Hong-Yun, MIN Zong-Yi, NIE Xin. Sulfur Doped Tin Oxide Nanoparticles: Solid State Synthesis and Performance for Visible-Light Driven Photocatalytic Degradation of Paraquat[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 649-658. doi: 10.11862/CJIC.2015.117 shu

Sulfur Doped Tin Oxide Nanoparticles: Solid State Synthesis and Performance for Visible-Light Driven Photocatalytic Degradation of Paraquat

1.
1 College of Chemistry and Materials Engineering, Kaili University, Kaili, Guizhou 556011, China;
2.
2 College of Envirnomental Science and Engineering, Hunan University, Changsha 410082, China;
3.
3 School of Envirnomental Studies, Guangxi University, Nanning 530004, China

Corresponding author: LIU Shao-You,
Received Date: 1 September 2014
Available Online: 8 February 2015
Fund Project: 贵州省科技创新人才团队建设基金项目(黔科人字[2013]4029) (黔科人字[2013]4029)贵州省材料物理与化学特色重点学科建设基金项目(黔教高发[2011]208) (黔教高发[2011]208)贵州省教育厅特色重点实验室建设基金项目(黔教高发[2012]196) (黔教高发[2012]196)贵州省教育厅市州地普通本科高校教育质量提升科研项目(黔教高发 [2011]278-01)资助。 (黔教高发 [2011]278-01)

Sulfur doped tin oxide (S-SnO₂) nanoparticles with high visible light-driven activity was synthesized by a facile solid state synthesis approach at low temperature using sodium dodecyl benzene sulfonate (SDBS) as a template. The samples were characterized by XRD, XPS, SEM, UV-Vis, HR-TEM, and FTIR. The doping mechanism and photocatalytic degradation of paraquat under visible light irradiation were investigated. The results show that the SDBS has a significant regulating effect on the surficial structure for both SnO₂ and S-SnO₂ prepared by solid state synthesis. The S element is successfully incorporated into the lattice of SnO₂ with S(Ⅳ) and S(Ⅵ) rather than embeds into the interstice of SnO₂ lattice. S-doping enhances the photocatalytic activity of SnO₂ due to the presence of a large number of hydroxyls on the surface and S(Ⅵ) in the lattice of SnO₂ benefiting the light absorption and effective charge separation, and it follows an order of SnO₂ < S-SnO₂ < SnO_2(SDBS) < S-SnO_2(SDBS).
- S-doped;SnO₂;solid state synthesis;photocatalytic degradation;paraquat
1. [1]
  [1] SU Shao-Quan(苏少泉), GENG He-Li(耿贺利). Pesticide (农药), 2008,47(4):244-247
2. [2]
  [2] WANG Zhai-Yu(王载宇). J. Medical Frontier(医药前沿), 2011,1(12):61-62
3. [3]
  [3] JIAO Jian(焦剑), SONG Ji-Mei(宋继梅), ZHANG Xiao-Xia (张小霞), et al. Guangzhou Chemical Industry(广州化工), 2010,8(3):138-141
4. [4]
  [4] ZHENG Wen(郑文), TANG Wen-Hao(唐文浩). Anhui Agricultural Sciences(安徽农业科学), 2007,35(8):2370-2371
5. [5]
  [5] LIU Chun-Ming(刘春明), FANG Li-Mei(方丽梅), ZU Xiao-Tao(祖小涛). Acta Phys. Sin.(物理学报), 2009,58(2):936-940
6. [6]
  [6] Emons T T, Li J, Nazar L F. J. Am. Chem. Soc., 2002,124(29):8516-8517
7. [7]
  [7] Monredon S, Cellot A, Delattre L, et al. J. Mater. Chem., 2002,12:2396-2400
8. [8]
  [8] Rockenberger J, Zum F U, Tischer M, et al. J. Chem. Phys., 2000,112(9):4296-4304
9. [9]
  [9] LU Yao(逯瑶), WANG Pei-Ji(王培吉), ZHANG Chang-Wen (张昌文), et al. Acta Phys. Sin.(物理学报), 2011,60(6):223-229
10. [10]
  [10] LU Yao(逯瑶), WANG Pei-Ji(王培吉), ZHANG Chang-Wen (张昌文), et al. Acta Phys. Sin.(物理学报), 2012,61(2): 23101-23106
11. [11]
  [11] CHI Jun-Hong(池俊红), WANG Juan(王娟). Acta Phys. Chim. Sin.(物理化学学报), 2010,26(8):2306-2310
12. [12]
  [12] OUYANG Pan(欧阳攀), ZHANG Hong(张鸿), LI Gen(李根), et al. Electronic Components and Materials(电子元器件及材料), 2012,6(31):10-14
13. [13]
  [13] XU Ke-Jing(许珂敬), SHANG Chao-Feng(尚超峰), LI Fang (李芳). Chinese J. Nonferrous Metals(中国有色金属学报), 2008,18(5):884-889
14. [14]
  [14] ZHOU Wu-Yi(周武艺), CAO Qing-Yun(曹庆云), TANG Shao-Qiu(唐绍裘), et al. J. Inorganic Materials(无机材料学报), 2006,21(4):776-782
15. [15]
  [15] LIU Shou-Xin(刘守新), LIU Hong(刘鸿). Foundation and Application of Photocatalysis and Photoelectro-Catalysis(光催化及与光电催化基础与应用). Beijing: Beijing Chemical Industry Press, 2005:135
16. [16]
  [16] CHANG Jian-Hua(常建华), DONG Qi-Gong(董绮功). Princ-iple and Analysis of Spectrum(波谱原理与解析). Beijing: Beijing Science Press, 2006:84
17. [17]
  [17] ZHANG Yi-Hua(张义华), ZHANG Jing-Xin(张景新), WANG Xue-Qing(王学勤), et al. J. Dalian University of Technology (大连理工大学学报), 2000,40(1):64-66
18. [18]
  [18] Wark M, Ekloff G S, Jaeger N I. Stud. Surf. Sci. Catal., 1991, 69:189-197
19. [19]
  [19] Adans D M. Metal-Ligand and Related Vibrations. London: Edward Arnold, 1967.
20. [20]
  [20] Socrates G. Infrared Characteristic Group Freqencies. New York: Wiley, 1980.
21. [21]
  [21] Randeniya L K, Murphy A B, Plumb I C. J. Mater. Sci., 2008,43:1389-1399
22. [22]
  [22] Themlin J M, Chtaib M, Henrard L, et al. Phys. Rev. B, 1992, 46(4):2460-2466
23. [23]
  [23] Satish C B M, Samuel J T, Glenn A, et al. Geochim. Cosmochim. Acta, 1998,62(21/22):3499-3514
24. [24]
  [24] Slade P. Nature, 1965,207:515-516
25. [25]
  [25] XUE Yong-Qiang(薛永强). Thesis for The Doctorate of Taiyuan University of Technology(太原理工大学博士学位论文), 2005.
26. [26]
  [26] Daghrir R, Drogui P, Robert D. Ind. Eng. Chem. Res., 2013, 52:3581-3599
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