Citation: JIN Zhe, TANG Kai, HU Ya-Ping, LÜ Jing-Wen, CHEN Zhi-Jun. Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 725-730. doi: 10.11862/CJIC.2015.107 shu

Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5

JIN Zhe ^1,3 ,
TANG Kai ² ,
HU Ya-Ping ² ,
LÜ Jing-Wen ^1,, ,
CHEN Zhi-Jun ^2,,

1.
1 Material science and engineering institute, Changchun University of Science and Technology, Chuangchun 130031, China;
2.
2 Mechanical and Electrical Engineering Institute, Zhengzhou University of Light Industry, Zhengzhou 450002, China;
3.
3 Jilin Tobacco Industrial Co., Ltd., Yanji, Jilin 133001, China

Corresponding author: LÜ Jing-Wen, CHEN Zhi-Jun,
Received Date: 21 October 2014
Available Online: 25 December 2014
Fund Project: 河南省高校科技创新人才支持计划(No.2008HASTIT019)资助项目。 (No.2008HASTIT019)

The composite Multi-walled carbon nanotubes/Polyacrylic acid (MWCNTs/PAA) was prepared by chemical functionalization, and Zn₄O(1,4-benzenedicarboxylate)₃(MOF-5) and hybrid materials MWCNTs/PAA/MOF-5 were obtained by solvothermal method. The resulted samples were characterized by XRD, FTIR, TG, HRTEM, the specific surface area and porosity analyze. The experimental results show that the content of PAA uniformly coated on the surface of MWCNTs is 4.3%; the absorbance peaks of functional groups in PAA occured in the FTIR spectrum of composite MWCNTs/PAA; the morphology of MWCNTs/PAA/MOF-5 was similar to that of MOF-5; the thermal decomposition temperature of MWCNTs/PAA/MOF-5 raised 49℃ than MOF-5; N₂ adsorption curves of MOF-5 and MWCNTs/PAA/MOF-5 were typical Ⅰ; the maximum N₂ adsorption capacity of MWCNTs/PAA/MOF-5 and MOF-5 were respectively 265 and 299 cm³·g^-1 at 77 K and 100 kPa.
- solvothermal;multi-walled carbon nanotubes;polyacrylic acid;MOF-5;N₂ adsorption
1. [1]
  [1] Lee J Y, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38(5):1450-1459
2. [2]
  [2] Saha D, Bao Z B, Jia F, et al. Environ. Sci. Technol., 2010, 44(5):1820-1826
3. [3]
  [3] HU Yun-Xia(胡云霞), ZHANG Wen-Wei(章文伟), WANG Li-Feng(王立锋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(7):1471-1479
4. [4]
  [4] Hamon L G, Jolimaitre E, Pirngruber G D. Ind. Eng. Chem. Res., 2010,49(16):7497-7503
5. [5]
  [5] Keskin S, Sholl D S. Ind. Eng. Chem. Res., 2008,48(2):914-922
6. [6]
  [6] Zhang Y J, Bhadbhade M, Scales N, et al. J. Solid State Chem., 2014,219:1-8
7. [7]
  [7] LIU Ming-Ming(刘明明), LÜ Wen-Miao(吕文苗), SHI Xiu-Feng(史秀锋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(3):579-584
8. [8]
  [8] Kaye S S, Dailly A, Yaghi O M, et al. J. Am. Chem. Soc., 2007,129(46):14176-14177
9. [9]
  [9] Yang S J, Choi J Y, Chae H K, et al. Chem. Mater., 2009,21(9):1893-1897
10. [10]
  [10] Yang S J, Cho J H, Nahm K S, et al. Int. J. Hydrogen Energy, 2010,35(23):13062-13067
11. [11]
  [11] Xiang Z H, Peng X, Cheng X, et al. J. Phys. Chem. C, 2011,115(40):19864-19871
12. [12]
  [12] Xiang Z H, Hu Z, Cao D P, et al. Angew. Chem. Int. Ed., 2011,50(2):491-494
13. [13]
  [13] Prasanth K P, Rallapalli P, Raj M C, et al. Int. J. Hydrogen Energy, 2011,36(13):7594-7601
14. [14]
  [14] Jiang H, Feng Y F, Chen M, et al. Int. J. Hydrogen Energy, 2013,38(25):10950-10955
15. [15]
  [15] Lee H, Choi Y N, Choi S B, et al. J. Phys. Chem. C, 2014, 118(11):5691-5699
16. [16]
  [16] GONG Shu-Sheng(龚书生), TANG Yi-Wen(唐一文), XU Liang(徐亮), et al. J. Huazhong Normal University: Natural Sciences(华中师范大学学报:自然科学版), 2008,42(1):77-80
17. [17]
  [17] Jasmina H, Morten B, Unni O, et al. J. Am. Chem. Soc., 2007,129(12):3612-3620
18. [18]
  [18] Chen J H, Li W Z, Wang D Z, et al. Carbon, 2002,40(8): 1193-1197
19. [19]
  [19] Hafizovic J, Bjrgen M, Olsbye U, et al. J. Am. Chem. Soc., 2007,129(12):3612-3620
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Preparation and N2 Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5

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Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5