Citation: JIN Zhe, TANG Kai, HU Ya-Ping, LÜ Jing-Wen, CHEN Zhi-Jun. Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 725-730. doi: 10.11862/CJIC.2015.107 shu

Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5

JIN Zhe ^1,3 ,
TANG Kai ² ,
HU Ya-Ping ² ,
LÜ Jing-Wen ^1,, ,
CHEN Zhi-Jun ^2,,

1.
1 Material science and engineering institute, Changchun University of Science and Technology, Chuangchun 130031, China;
2.
2 Mechanical and Electrical Engineering Institute, Zhengzhou University of Light Industry, Zhengzhou 450002, China;
3.
3 Jilin Tobacco Industrial Co., Ltd., Yanji, Jilin 133001, China

Corresponding author: LÜ Jing-Wen, CHEN Zhi-Jun,
Received Date: 21 October 2014
Available Online: 25 December 2014
Fund Project: 河南省高校科技创新人才支持计划(No.2008HASTIT019)资助项目。 (No.2008HASTIT019)

The composite Multi-walled carbon nanotubes/Polyacrylic acid (MWCNTs/PAA) was prepared by chemical functionalization, and Zn₄O(1,4-benzenedicarboxylate)₃(MOF-5) and hybrid materials MWCNTs/PAA/MOF-5 were obtained by solvothermal method. The resulted samples were characterized by XRD, FTIR, TG, HRTEM, the specific surface area and porosity analyze. The experimental results show that the content of PAA uniformly coated on the surface of MWCNTs is 4.3%; the absorbance peaks of functional groups in PAA occured in the FTIR spectrum of composite MWCNTs/PAA; the morphology of MWCNTs/PAA/MOF-5 was similar to that of MOF-5; the thermal decomposition temperature of MWCNTs/PAA/MOF-5 raised 49℃ than MOF-5; N₂ adsorption curves of MOF-5 and MWCNTs/PAA/MOF-5 were typical Ⅰ; the maximum N₂ adsorption capacity of MWCNTs/PAA/MOF-5 and MOF-5 were respectively 265 and 299 cm³·g^-1 at 77 K and 100 kPa.
- solvothermal;multi-walled carbon nanotubes;polyacrylic acid;MOF-5;N₂ adsorption
1. [1]
  [1] Lee J Y, Farha O K, Roberts J, et al. Chem. Soc. Rev., 2009, 38(5):1450-1459
2. [2]
  [2] Saha D, Bao Z B, Jia F, et al. Environ. Sci. Technol., 2010, 44(5):1820-1826
3. [3]
  [3] HU Yun-Xia(胡云霞), ZHANG Wen-Wei(章文伟), WANG Li-Feng(王立锋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(7):1471-1479
4. [4]
  [4] Hamon L G, Jolimaitre E, Pirngruber G D. Ind. Eng. Chem. Res., 2010,49(16):7497-7503
5. [5]
  [5] Keskin S, Sholl D S. Ind. Eng. Chem. Res., 2008,48(2):914-922
6. [6]
  [6] Zhang Y J, Bhadbhade M, Scales N, et al. J. Solid State Chem., 2014,219:1-8
7. [7]
  [7] LIU Ming-Ming(刘明明), LÜ Wen-Miao(吕文苗), SHI Xiu-Feng(史秀锋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(3):579-584
8. [8]
  [8] Kaye S S, Dailly A, Yaghi O M, et al. J. Am. Chem. Soc., 2007,129(46):14176-14177
9. [9]
  [9] Yang S J, Choi J Y, Chae H K, et al. Chem. Mater., 2009,21(9):1893-1897
10. [10]
  [10] Yang S J, Cho J H, Nahm K S, et al. Int. J. Hydrogen Energy, 2010,35(23):13062-13067
11. [11]
  [11] Xiang Z H, Peng X, Cheng X, et al. J. Phys. Chem. C, 2011,115(40):19864-19871
12. [12]
  [12] Xiang Z H, Hu Z, Cao D P, et al. Angew. Chem. Int. Ed., 2011,50(2):491-494
13. [13]
  [13] Prasanth K P, Rallapalli P, Raj M C, et al. Int. J. Hydrogen Energy, 2011,36(13):7594-7601
14. [14]
  [14] Jiang H, Feng Y F, Chen M, et al. Int. J. Hydrogen Energy, 2013,38(25):10950-10955
15. [15]
  [15] Lee H, Choi Y N, Choi S B, et al. J. Phys. Chem. C, 2014, 118(11):5691-5699
16. [16]
  [16] GONG Shu-Sheng(龚书生), TANG Yi-Wen(唐一文), XU Liang(徐亮), et al. J. Huazhong Normal University: Natural Sciences(华中师范大学学报:自然科学版), 2008,42(1):77-80
17. [17]
  [17] Jasmina H, Morten B, Unni O, et al. J. Am. Chem. Soc., 2007,129(12):3612-3620
18. [18]
  [18] Chen J H, Li W Z, Wang D Z, et al. Carbon, 2002,40(8): 1193-1197
19. [19]
  [19] Hafizovic J, Bjrgen M, Olsbye U, et al. J. Am. Chem. Soc., 2007,129(12):3612-3620
1. [1]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
2. [2]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
3. [3]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
4. [4]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
5. [5]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
6. [6]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
7. [7]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
8. [8]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
11. [11]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
14. [14]
  Bin Chen , Chaoyang Zheng , Dehuan Shi , Yi Huang , Renxia Deng , Yang Wei , Zheyuan Liu , Yan Yu , Shenghong Zhong . p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction. Chinese Journal of Structural Chemistry, 2025, 44(1): 100468-100468. doi: 10.1016/j.cjsc.2024.100468
15. [15]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305
16. [16]
  Chaozheng He , Menghui Xi , Chenxu Zhao , Ran Wang , Ling Fu , Jinrong Huo . Highly N₂ dissociation catalyst: Ir(100) and Ir(110) surfaces. Chinese Chemical Letters, 2025, 36(3): 109671-. doi: 10.1016/j.cclet.2024.109671
17. [17]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
18. [18]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
19. [19]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
20. [20]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(555)
HTML views(132)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and N2 Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and N₂ Adsorption Properties of Multi-walled Carbon Nanotubes/Polyacrylic Acid/MOF-5