Citation: WANG Peng, CHEN Shang-Xing, HUANG Min, ZHAO Zhen-Dong, WANG Zong-De, FAN Guo-Rong. Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 767-773. doi: 10.11862/CJIC.2015.105 shu

Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt

1.
1 College of Forestry, Jiangxi Agricultural University, Nanchang 330045, China;
2.
2 Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China

Corresponding author: CHEN Shang-Xing,
Received Date: 5 November 2014
Available Online: 12 January 2015
Fund Project: 教育部博士学科点专项科研基金课题(No.20133603120002)资助项目。 (No.20133603120002)

Ordered hexagonal supermicroporous silica with nanosheet morphology was successfully synthesized using rosin-based quaternary ammonium salt (dehydroabietyltrimethyl ammonium bromine, short for DTAB) as template agent, tetraethyl orthosilicate as silicate source, and ammonia as alkaline medium. XRD, N₂ adsorption-desorption, TEM, and SEM were used to characterize the samples. The results indicated that the dosage amount of template agent, silicate source, alkaline medium, crystallization temperature and stirring time had great effects on the regularity of the pore structure. When the mole ratio of n_SiO₂:n_DTAB:n_NH₃:n_H₂O was 1.0:0.1:11.3:924.0; crystallization temperature was 373 K; stirring time was 24 h, the sample got the hightest regularity. After the calcination, the synthesized material possessed large surface area (1 024 m²·g^-1), high pore volume (0.56 cm³·g^-1) and narrow pore size distribution (centered at about 1.80 nm).
- rosin-based quaternary ammonium salt;supermicroporous;silica
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