Citation: WANG Peng, CHEN Shang-Xing, HUANG Min, ZHAO Zhen-Dong, WANG Zong-De, FAN Guo-Rong. Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 767-773. doi: 10.11862/CJIC.2015.105 shu

Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt

1.
1 College of Forestry, Jiangxi Agricultural University, Nanchang 330045, China;
2.
2 Institute of Chemical Industry of Forestry Products, CAF, Nanjing 210042, China

Corresponding author: CHEN Shang-Xing,
Received Date: 5 November 2014
Available Online: 12 January 2015
Fund Project: 教育部博士学科点专项科研基金课题(No.20133603120002)资助项目。 (No.20133603120002)

Ordered hexagonal supermicroporous silica with nanosheet morphology was successfully synthesized using rosin-based quaternary ammonium salt (dehydroabietyltrimethyl ammonium bromine, short for DTAB) as template agent, tetraethyl orthosilicate as silicate source, and ammonia as alkaline medium. XRD, N₂ adsorption-desorption, TEM, and SEM were used to characterize the samples. The results indicated that the dosage amount of template agent, silicate source, alkaline medium, crystallization temperature and stirring time had great effects on the regularity of the pore structure. When the mole ratio of n_SiO₂:n_DTAB:n_NH₃:n_H₂O was 1.0:0.1:11.3:924.0; crystallization temperature was 373 K; stirring time was 24 h, the sample got the hightest regularity. After the calcination, the synthesized material possessed large surface area (1 024 m²·g^-1), high pore volume (0.56 cm³·g^-1) and narrow pore size distribution (centered at about 1.80 nm).
- rosin-based quaternary ammonium salt;supermicroporous;silica
1. [1]
  [1] Corma A. Chem. Rev., 1997,97(6):2373-2420
2. [2]
  [2] Charnay C, Bégu S, Tourné-Péteilh C, et al. Eur. J. Pharm. Biopharm., 2004,57(3):533-540
3. [3]
  [3] Fan J, Yu C, Gao F, et al. Angew. Chem., 2003,115(27): 3254-3258
4. [4]
  [4] Crossland E J, Noel N, Sivaram V, et al. Nature, 2013,495(7440):215-219
5. [5]
  [5] Kresge C, Leonowicz M, Roth W, et al. Nature, 1992,359(6397):710-712
6. [6]
  [6] Beck J, Vartuli J, Roth W, et al. J. Am. Chem. Soc., 1992, 114(27):10834-10843.
7. [7]
  [7] Huo Q, Margolese D I, Stucky G D. Chem. Mater., 1996,8(5):1147-1160
8. [8]
  [8] Yu C, Tian B, Fan J, et al. J. Am. Chem. Soc., 2002,124(17):4556-4557
9. [9]
  [9] Zhao D, Feng J, Huo Q, et al. Science, 1998,279(5350):548-552
10. [10]
  [10] Tanev P T,Pinnavaia T J. Science, 1995,267(5199):865-867
11. [11]
  [11] Bagshaw S A, Prouzet E, Pinnavaia T J. Science, 1995,269(5228):1242-1244
12. [12]
  [12] Yu C, Yu Y, Zhao D. Chem. Commun., 2000(7):575-576
13. [13]
  [13] Liu X, Tian B, Yu C, et al. Angew. Chem. Int. Ed., 2002,41(20):3876-3878
14. [14]
  [14] Fan J, Yu C, Wang L, et al. J. Am. Chem. Soc., 2001,123(48):12113-12114
15. [15]
  [15] Zhou G, Chen Y, Yang J, et al. J. Mater. Chem., 2007,17(27):2839-2844
16. [16]
  [16] Bagshaw S, Hayman A. Adv. Mater., 2001,13(12/13):1011-1013
17. [17]
  [17] Davis M E. Nature, 2002,417(6891):813-821
18. [18]
  [18] Zhao S X, Lu G Q M, Hu X. Chem. Commun., 1999(15): 1391-1392
19. [19]
  [19] Serrano D P, Aguado J, Garagorri E. Chem. Commun., 2000(20):2041-2042
20. [20]
  [20] Kruk M, Jaroniec M, Sayari A. J. Phys. Chem. B, 1997,101(4):583-589
21. [21]
  [21] Beck J, Vartuli J, Kennedy G, et al. Chem. Mater., 1994,6(10):1816-1821
22. [22]
  [22] Bagshaw S A, Hayman A R. Microporous Mesoporous Mater., 2001,44:81-88
23. [23]
  [23] Ryoo R, Park I S, Jun S, et al. J. Am. Chem. Soc., 2001,123(8):1650-1657
24. [24]
  [24] Wang R, Han S, Hou W, et al. J. Phys. Chem. C, 2007,111(29):10955-10958
25. [25]
  [25] Zhou Y, Antonietti M. Adv. Mater., 2003,15(17):1452-1455
26. [26]
  [26] Zhou Y, Antonietti M. Chem. Mater., 2004,16(3):544-550
27. [27]
  [27] Di Y, Meng X, Wang L, et al. Langmuir, 2006,22(7):3068-3072
28. [28]
  [28] ZENG Tao(曾韬), PENG Shu-Jing(彭淑静). J. Nanjing For. Univ.: Nat. Sci. Ed.(南京林业大学学报:自然科学版), 1996(01):26-28
29. [29]
  [29] CHEN Xiao-Yin(陈晓银), DING Guo-Zhong(丁国忠), CHEN Hai-Ying(陈海鹰), et al. Chem. J. Chinese Universities(高等学校化学学报), 1997(02):186-189
30. [30]
  [30] Brunauer S, Deming L S, Deming W E, et al. J. Am. Chem. Soc., 1940,62(7):1723-1732
1. [1]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
2. [2]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
3. [3]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
4. [4]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
5. [5]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
6. [6]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
7. [7]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
8. [8]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
9. [9]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
10. [10]
  Yinuo Wang , Siran Wang , Yilong Zhao , Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063
11. [11]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
12. [12]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
13. [13]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
14. [14]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
15. [15]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
16. [16]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
17. [17]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
18. [18]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
19. [19]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
20. [20]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(410)
HTML views(79)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Ordered Supermicroporous Silica Using Rosin-Based Quaternary Ammonium Salt

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com