Citation: XU Jian, XIE Li-Xia, ZHANG Chang-Li. Structures and Magnetic Properties of Two Chiral Polynuclear Metal Clusters with Derivative of L-cysteine[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 807-812. doi: 10.11862/CJIC.2015.102 shu

Structures and Magnetic Properties of Two Chiral Polynuclear Metal Clusters with Derivative of L-cysteine

1.
1 School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171;
2.
2 College of Sciences, Henan Agricultural University, Zhengzhou 450002

Received Date: 17 October 2014
Available Online: 15 January 2015
Fund Project: 国家自然科学基金(No.21201057) (No.21201057)河南省青年骨干教师(No. 2013GGJS-042) (No. 2013GGJS-042)江苏省自然科学基金(No.BK20140090)资助项目。 (No.BK20140090)

An antiferromagnetic complexes based on Co(Ⅱ) or Mn(Ⅱ) and chiral ligand L-thioproline (LTP) with formula of [Co(LTP)₂]_n (1) and [Mn(LTP)₂]_n (2) were synthesized and structurally characterized. The ligand LTP forms a five-membered ring upon chelation to the metal ions. In the 2-D structure, each octahedral metal ion is linked to another four metal ions by four LTP ligands adopting a μ₂-N₁O₂:O₃ coordination mode. Complexes 1 and 2 are same in the coordination mode and network structure, and crystallize in the orthorhombic crystal system. Magnetic measurements show that a weak antiferromagnetic coupling occurs in the complexes. CCDC: 1042934, 1; 1042935, 2.
- coordination complex;magnetic behavior;chiral amino acid ligand
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