Citation: CHEN Hui-Min, HE Yun-Qiu, LI Yi-Ming, CAI Si-Qi. Preparation and Photoelectric Properties of Reduced Graphite Oxide(rGO)/ZnO Composite Films[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 429-438. doi: 10.11862/CJIC.2015.101 shu

Preparation and Photoelectric Properties of Reduced Graphite Oxide(rGO)/ZnO Composite Films

CHEN Hui-Min ¹ ,
HE Yun-Qiu ^1,2,, ,
LI Yi-Ming ¹ ,
CAI Si-Qi ¹

1.
1 School of Materials Science and Engineering, Tongji University, Shanghai 200092, China;
2.
2 Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 200092, China

Corresponding author: HE Yun-Qiu,
Received Date: 9 December 2014
Available Online: 18 January 2015
Fund Project: 国家自然科学基金(No.51175162)资助项目。 (No.51175162)

The rGO/ZnO (reduced graphite oxide/ZnO) composite films were synthesized by using different reduction treated graphite oxides (GOs) as precursors, and then their visible-light excitation photoelectric conversion performance was investigated. In this work, we used the two reducing agents, KOH or NaBH₄, to reduce graphite oxide, then the reduced graphite oxide was mixed with zinc oxide sol. rGO/ZnO composite films were prepared by spin-coating and heat treatment on FTO(fluorine-doped tin oxide)conductive glass substrates. The as-prepared samples were characterized by XRD, FTIR, FE-SEM, XPS, UV-Vis, etc. Pretreatment process of graphite oxide had a great influence on the structure of composite films, reduction treatment by NaBH₄ was more conducive to form a uniform thin film. Photocurrent test results showed that different composite films can produce photocurrent under visible-light irradiation, the principle was photo-excited electron transition from rGO to ZnO to achieve the separation of photo-generated carriers. The GO after NaBH₄-reduction with ZnO composite film showed the largest photocurrent density with a value of 6×10^-7 A·cm^-2.
- graphite oxide;zinc oxide;sol-gel;films;photoelectric property
1. [1]
  [1] Novoselov K S, Geim A K, Morozov S, et al. Science, 2004, 306(5696):666-669
2. [2]
  [2] Neto A C, Guinea F, Peres N, et al. Rev. Mod. Phys., 2009, 81(1):109
3. [3]
  [3] Mayorov A S, Gorbachev R V, Morozov S V, et al. Nano Lett., 2011,11(6):2396-2399
4. [4]
  [4] Nair R, Blake P, Grigorenko A, et al. Science, 2008,320 (5881):1308-1308
5. [5]
  [5] Hontoria-Lucas C, Lopez-Peinado A, López-González J de D, et al. Carbon, 1995,33(11):1585-1592
6. [6]
  [6] Dreyer D R, Park S, Bielawski C W, et al. Chem. Soc. Rev., 2010,39(1):228-240
7. [7]
  [7] WAN Chen(万臣), PENG Tong-Jiang(彭同江), SUN Hong-Juan(孙红娟), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012,28(5):915-921
8. [8]
  [8] Loh K P, Bao Q, Eda G, et al. Nat. Chem., 2010,2(12):1015-1024
9. [9]
  [9] Eda G, Mattevi C, Yamaguchi H, et al. J. Phys. Chem. C, 2009,113(35):15768-15771
10. [10]
  [10] Fan X, Peng W, Li Y, et al. Adv. Mater., 2008,20(23):4490-4493
11. [11]
  [11] Shin H J, Kim K K, Benayad A, et al. Adv. Funct. Mater., 2009,19(12):1987-1992
12. [12]
  [12] Stankovich S, Dikin D A, Piner R D, et al. Carbon, 2007,45 (7):1558-1565
13. [13]
  [13] Venugopal G, Krishnamoorthy K, Mohan R, et al. Mater. Chem. Phys., 2012,132(1):29-33
14. [14]
  [14] Zhan Z, Zheng L, Pan Y, et al. J. Mater. Chem., 2012,22(6): 2589-2595
15. [15]
  [15] Liu H, Sun Q Q, Chen L, et al. Chin. Phys. Lett., 2010,27 (7):077201,DOI:10.1088/0256-307X/27/7/070201
16. [16]
  [16] Liang Y, Wang H, Casalongue H S, et al. Nano Res., 2010, 3(10):701-705
17. [17]
  [17] ZHANG Xiao-Yan(张晓艳), LI Hao-Peng(李浩鹏), CUI Xiao-Li(崔晓莉). Chinese J. Inorg. Chem.(无机化学学报), 2009,25(11):1903-1907
18. [18]
  [18] CHEN Xiao-Gang(陈小刚), HE Yun-Qiu(贺蕴秋), ZHANG Qiong(张琼), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(11):1953-1959
19. [19]
  [19] Zhang Y, Li H, Pan L, et al. J. Electroanal. Chem., 2009, 634(1):68-71
20. [20]
  [20] Singh G, Choudhary A, Haranath D, et al. Carbon, 2012,50 (2):385-394
21. [21]
  [21] Marcano D C, Kosynkin D V, Berlin J M, et al. ACS Nano, 2010,4(8):4806-4814
22. [22]
  [22] LI Le(李乐), HE Yun-Qiu(贺蕴秋), CHU Xiao-Fei(储晓菲), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2013,29(8): 1681-1690
23. [23]
  [23] Wang J, Tsuzuki T, Tang B, et al. ACS Appl. Mater. Interfaces, 2012,4(6):3084-3090
24. [24]
  [24] Luo Q P, Yu X Y, Lei B X, et al. J. Phys. Chem. C, 2012, 116(14):8111-8117
25. [25]
  [25] Bagri A, Mattevi C, Acik M, et al. Nat. Chem., 2010,2(7): 581-587
26. [26]
  [26] Tan Z, Chua D H. J. Electrochem. Soc., 2011,158(4):K112-K116
1. [1]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
2. [2]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
3. [3]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
6. [6]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
7. [7]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
8. [8]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
9. [9]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
10. [10]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
11. [11]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
12. [12]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
13. [13]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
14. [14]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
18. [18]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
19. [19]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
20. [20]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(179)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142