Citation: ZHAO Can, ZHANG You, XIE Meng-Lin, WU Meng-Qin, WEN Yi-Hang. Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 781-788. doi: 10.11862/CJIC.2015.095 shu

Two Metal-Organic Frameworks Based on Tricarboxylic Acid: Syntheses, Structures and Fluorescent Properties

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Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: WEN Yi-Hang,
Received Date: 13 October 2014
Available Online: 1 January 2015
Fund Project: 浙江省自然科学基金(No.LY12B01002) (No.LY12B01002)浙江师范大学“浙江省省属高校化学重中之重学科”和“先进催化材料教育部重点实验室”开放课题基金项目(No.ZJHX201406) 资助项目。 (No.ZJHX201406)

Two metal-organic frameworks (MOFs), formulated as [Cd₂(CH₃COO)(L)(H₂O)₃]_n (2) and [Na(H₂L)]_n (2) (H₃L=1,3-bis(4'-carboxylphenoxy)benzoic acid) were successfully prepared by hydrothermal reaction of H₃L ligand with metal salts. Because of the various coordination modes of the H₃L ligand, these compounds display structural diversity. Compound 1 crystallizes in triclinic system with P1 space group and 2 in monoclinic system with C2/c space group. The single crystal structures show that 1 possesses a 3D structural framework, in which the secondary building units(SBUs) are bridged by the L^3- ligands, 2 features a 3D 5-connected network with (4⁶·6⁴) topology. Moreover, the luminescent property of compound 1 has been investigated. CCDC: 1009539, 1; 1009540, 2.
- metal-organic frameworks;1,3-bis(4'-carboxylphenoxy)benzoic acid;hydrothermal reaction;topology;luminescent property
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