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Citation: LI Ai-Chang, ZHU Ning-Ning, LI Jing-Hong, YANG Xiao-Yan, WANG Shuang, YANG Liu. Preparation of Ag3PO4/Ni Thin Films and Their Photocatalytic Activity and Reaction Mechanism for Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 681-688. doi: 10.11862/CJIC.2015.094 shu

Preparation of Ag3PO4/Ni Thin Films and Their Photocatalytic Activity and Reaction Mechanism for Rhodamine B

  • 1.

    Faculty of chemistry and Material Science, Langfang Teachers College, Langfang, Hebei 065000, China

  • Corresponding author: LI Ai-Chang, 
  • Received Date: 18 September 2014
    Available Online: 29 December 2014

    Fund Project: 河北省科技支撑计划项目(No.11276732) (No.11276732)廊坊师范学院重点科学研究项目(No.LSZZ201303)资助。 (No.LSZZ201303)

  • Ag3PO4/Ni thin films were prepared by electrochemical method. The surface morphology, phase structure, optical characteristics and band structure of the thin film were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS), respectively. Its photocatalytic properties and stability were evaluated with Rhodamine B (RhB) as a model compound. Using a method of adding active species scavenger to the solution, mechanism of photocatalytic degradation of the film was explored. The results show that the Ag3PO4/Ni thin film prepared under optimum condition has a compact layer structure composed by polymouphous nanoparticles. The thin film exhibits high photocatalytic activity and excellent photocatalytic stability to decompose Rhodamine B. The photodegradation rate is about 2.3 times that of porous P25 TiO2/ITO nanofilm under the visible light in 60 min. The film maintains nearly 100% of their corresponding initial photocatalytic activity after 6 cycles. Furthermore, the photodegradation mechanism of the film for Rhodamine B under the visible light was proposed.
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