Citation: GU Xiao-Min, WANG Lei, SHAN Yue-Xia, ZHANG Wen-Li, CHEN Qin, NI Liang, YAO Jia. Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 555-564. doi: 10.11862/CJIC.2015.091 shu

Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands

GU Xiao-Min ¹ ,
WANG Lei ¹ ,
SHAN Yue-Xia ¹ ,
ZHANG Wen-Li ^1,, ,
CHEN Qin ¹ ,
NI Liang ¹ ,
YAO Jia ²

1.
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China;
2.
2 Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: ZHANG Wen-Li,
Received Date: 1 September 2014
Available Online: 6 January 2015
Fund Project: 江苏大学高级人才启动基金项目(No.14JDG053) (No.14JDG053)江苏省博士后科学基金(No.1401176C)资助项目。 (No.1401176C)

Three complexes have been obtained by the reaction of metal (Mn(Ⅱ), Cd(Ⅱ)), 5,6-substituted 1,10-phen derivatives with two carboxylic acids, 4,4'-oxybis(benzoic acid)(4,4'-H₂oba) and oxalic acid (H₂ox). The crystal structures of the resulting complexes, namely {[Mn(4,4'-oba)(Medpq)]Medpq}_n (1), [Mn₂(4,4'-oba)₂(MOPIP)₄]·2H₂O (2), and [Cd(ox)(MOPIP)₂]·2H₂O (3) (Medpq=2-methyldipyrido-[3,2-f:2,3'-h]quinoxaline, MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline]), have been elucidated using their single-crystal X-ray diffraction analysis. Diverse structures are observed for these complexes. Compound 1 contains double chains, which are further stacked via hydrogen bonding interactions to form layers. Compound 2 features dinuclear structures, which are connected by strong π…π and hydrogen bonding interactions to result in layer structures. Compound 3 contains mononuclear structures and extended to chain and layer structures by π…π and hydrogen bonding interactions. The differences among these structures indicate that the size of the rigid chelating ligands and the flexibility of carboxylate have important effects on the structures of their complexes. The fluorescent properties of 2 and 3 were studied in the solid state at room temperature.
- fluorescent property;structural diversity;interactions;NBO analysis
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