Citation: GU Xiao-Min, WANG Lei, SHAN Yue-Xia, ZHANG Wen-Li, CHEN Qin, NI Liang, YAO Jia. Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 555-564. doi: 10.11862/CJIC.2015.091 shu

Frameworks of Metal Dicarboxylate Complexes: from Nuclear Structures to Double Chains Based on N-containing Ligands

  • Corresponding author: ZHANG Wen-Li, 
  • Received Date: 1 September 2014
    Available Online: 6 January 2015

    Fund Project: 江苏大学高级人才启动基金项目(No.14JDG053) (No.14JDG053)江苏省博士后科学基金(No.1401176C)资助项目。 (No.1401176C)

  • Three complexes have been obtained by the reaction of metal (Mn(Ⅱ), Cd(Ⅱ)), 5,6-substituted 1,10-phen derivatives with two carboxylic acids, 4,4'-oxybis(benzoic acid)(4,4'-H2oba) and oxalic acid (H2ox). The crystal structures of the resulting complexes, namely {[Mn(4,4'-oba)(Medpq)]Medpq}n (1), [Mn2(4,4'-oba)2(MOPIP)4]·2H2O (2), and [Cd(ox)(MOPIP)2]·2H2O (3) (Medpq=2-methyldipyrido-[3,2-f:2,3'-h]quinoxaline, MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline]), have been elucidated using their single-crystal X-ray diffraction analysis. Diverse structures are observed for these complexes. Compound 1 contains double chains, which are further stacked via hydrogen bonding interactions to form layers. Compound 2 features dinuclear structures, which are connected by strong ππ and hydrogen bonding interactions to result in layer structures. Compound 3 contains mononuclear structures and extended to chain and layer structures by ππ and hydrogen bonding interactions. The differences among these structures indicate that the size of the rigid chelating ligands and the flexibility of carboxylate have important effects on the structures of their complexes. The fluorescent properties of 2 and 3 were studied in the solid state at room temperature.
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