Citation: LIU Ying-Chun, MA Zhi-Hong, SHANG Cheng-Xi, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Ruthenium Carbonyl Complexes Containing Alkyl-Substituted Indenyl Ligands: Syntheses and Structures[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 774-780. doi: 10.11862/CJIC.2015.088 shu

Ruthenium Carbonyl Complexes Containing Alkyl-Substituted Indenyl Ligands: Syntheses and Structures

1.
1 The College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;
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2 College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China;
3.
3 Chengde Nursing Vocational College, Chengde, Hebei 067000, China

Received Date: 11 December 2014
Available Online: 14 January 2015
Fund Project: 国家自然科学基金(No.21372061) (No.21372061)河北省自然科学基金(No.B2013205025,B2014205018) (No.B2013205025,B2014205018)河北师范大学重点基金(No.L2012Z02)资助项目。 (No.L2012Z02)

Reactions of the alkyl-substituted indenyl ligands [C₉H₇R] (R=CH₂CH₂CH₃ (1), CH(CH₃)₂ (2), C₅H₉ (3), CH₂C₆H₅ (4), CH₂CH=CH₂ (5)) with Ru₃(CO)₁₂ in refluxing xylene or heptane gave the responding dinuclear metal carbonyl complexes [(η⁵-C₉H₆R)Ru(CO)(μ-CO)]₂ (R=CH₂CH₂CH₃ (6), CH(CH₃)₂ (7), C₅H₉ (8), CH₂C₆H₅ (9), CH₂CH=CH₂ (10)), respectively, as well as the bridged diruthenium complex [(η⁵-C₉H₆)(H₃CH₂C)CHCH(CH₂CH₃)(η⁵-C₉H₆)][Ru(CO)(μ-CO)]₂ (11). These complexes have been characterized by elemental analysis, IR, and 1H NMR spectroscopy. The molecular structures of 6, 9, 10 and 11 were determined by X-ray diffraction analysis. CCDC: 937499, 6; 972340, 9; 944111, 10; 970734, 11.
- indenyl;ruthenium carbonyl;X-ray diffraction;structure
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沈阳化工大学材料科学与工程学院沈阳 110142