Citation: ZHU Xiao-Ming, FENG Yong-Lan, ZHANG Fu-Xing, YU Jiang-Xi, JIANG Wu-Jiu, TAN Yu-Xing, ZHANG Zhi-Jian, KUANG Dai-Zhi. Syntheses, Crystal Structures, Thermal Stability and Herbicidal Activity of Two Organotin 4-Iodobenzoates[J]. Chinese Journal of Inorganic Chemistry, ;2015, (4): 761-766. doi: 10.11862/CJIC.2015.085 shu

Syntheses, Crystal Structures, Thermal Stability and Herbicidal Activity of Two Organotin 4-Iodobenzoates

1.
1 Department of Chemistry and Material Science, Hengyang Normal University, Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province, Hengyang, Hunan 421008, China;
2.
2 Department of Lifes Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Corresponding author: KUANG Dai-Zhi,
Received Date: 26 November 2014
Available Online: 13 December 2014
Fund Project: 湖南省自然科学基金(No.13JJ3112) (No.13JJ3112)科技计划项目(No. 2013TZ2025,2014NK3086,2014FJ3060) (No. 2013TZ2025,2014NK3086,2014FJ3060)功能金属有机材料湖南省普通高校重点实验室开放基金(No.13K105,14K014,13K01-05,GN14K01) (No.13K105,14K014,13K01-05,GN14K01)衡阳市科技计划(No.2012KJ30) (No.2012KJ30)衡阳师范学院青年骨干教师培养计划(2012) 及科技项目(No.12C45)资助项目。 (2012) 及科技项目(No.12C45)

The two organotin 4-iodobenzoates, Ph₃Sn(p-I-C₆H₄O₂) (1) and {[n-Bu₂Sn(p-I-C₆H₄O₂)]₂O}₂ (2) have been synthesized by the reaction of triphenyltin hydroxide and dibutyltin oxide with 4-Iodobenzoic acid in ethanol and benzene, respectively. IR, ¹H NMR, Elemental analysis and X-ray diffraction for the title complexes were presented. The crystal of complex 1 belongs to triclinic, space group P1. The tin atom has a distorted tetrahedral geometry and the dimeric structure is formed by intermolecular hydrogen bonds and C-I…π. The crystal of complex 2 belongs to monoclinic, space group C2/c. The dimer structure is shaped by one Sn₂O₂ planar four-membered ring and one-dimensional coordination polymer chain is formed by intermolecular I…I interaction. The thermal gravimetric analysis has showed that: the complexes 1 and 2 are stable below 230℃. It is found that the inhibitory activity of compounds 1 and 2 on weeds Amaranthus spinosus and Portulaca oleracea are greater than the effect on crop mung bean, and inhibitory activity of the compound 2 is higher than 1. It provides a method to study the herbicide for Amaranthus spinosus and Portulaca oleracea. CCDC: 1039846, 1; 1039847, 2.
- organotin 4-iodobenzoate;synthesis;crystal structure;thermal stability;herbicidal activity
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