Citation: GUAN Ming-Yun, JIAN Yan, SUN Jian-Hua, XU Zheng. Flower-Like Mesocrystal Cobalt: Controllable Synthesis in Large Scale and Magnetic Property[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 619-626. doi: 10.11862/CJIC.2015.084 shu

Flower-Like Mesocrystal Cobalt: Controllable Synthesis in Large Scale and Magnetic Property

GUAN Ming-Yun ^1,2 ,
JIAN Yan ¹ ,
SUN Jian-Hua ^1,2 ,
XU Zheng ²

1.
1 Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China;
2.
2 State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

Received Date: 3 November 2014
Available Online: 23 December 2014
Fund Project: 国家973重点建设项目基础研究项目(No.2007CB936302) (No.2007CB936302) 国家自然科学基金-面上项目(No.21373103) (No.21373103) 江苏省自然科学基金-面上项目 (No.BK2011260)资助项目。 (No.BK2011260)

Using diethylenetriamine (DETA) as coordination agent, a well-defined flower-like cobalt mesocrystal was synthesized rapidly by nanoparticles self assembly in oriented fashion. By adjusting reaction rate and kind of coordination agents, morphologies of cobalt can be transformed from nice-look flower, via poor-look dendrite, to microsphere composed of nanoparticles or nanoplates. DETA plays an important role in the formation process of cobalt mesocrystal. The possible formation mechanism is proposed. The cobalt mesocrystals not only exhibit Co nanocrystals property (an enhanced coercive force being 260 Oe at 300 K), but also have bulk Co property (saturation magnetization being 168 emu·g^-1). The synthesis method in large scale is facile and effective with high yield.
- cobalt;crystallization assembly;mesocrystal;oriented attachment
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