Citation: Lotfia-El Majdoub, YAO Fang-Tao, SHI Ya-Sai, LI Tian-Tian, XU Qing-Hong. Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 479-484. doi: 10.11862/CJIC.2015.082 shu

Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of ChemicalTechnology, Beijing 100029, China

Corresponding author: XU Qing-Hong,
Received Date: 20 August 2014
Available Online: 2 November 2014
Fund Project: 国家自然科学基金(No.U1362113)资助项目。 (No.U1362113)

After heated at 400 ℃, the activated silica gel reacted with silicon tetrachloride to obtain chlorinated silica gel in anhydrous tetrahydrofuran. And a modified silica gel with carbonyl and amino groups on its surface was obtained by the reaction between chlorinated silica gel and acetamide. The modification has good coordination ability to Fe³⁺, and a supported catalyst with catalytic active site of Fe³⁺ evenly distributed was then prepared by coordination between Fe³⁺ and the surface organic modified silica gel. The synthesized catalyst has good catalytic oxidation performance to formaldehyde, and a maximum conversion of formaldehyde is about 91.3%.
- activated silica gel;organic surface;supported;catalytic oxidation;formaldehyde
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Supporting of Fe3+ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde

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通讯作者: 陈斌, bchen63@163.com

Supporting of Fe³⁺ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde