Advanced Search

Citation: Lotfia-El Majdoub, YAO Fang-Tao, SHI Ya-Sai, LI Tian-Tian, XU Qing-Hong. Supporting of Fe3+ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 479-484. doi: 10.11862/CJIC.2015.082 shu

Supporting of Fe3+ on Surface of Activated Silica Gel and Its Catalytic Oxidation Performance to Formaldehyde

  • 1.

    State Key Laboratory of Chemical Resource Engineering, Beijing University of ChemicalTechnology, Beijing 100029, China

  • Corresponding author: XU Qing-Hong, 
  • Received Date: 20 August 2014
    Available Online: 2 November 2014

    Fund Project: 国家自然科学基金(No.U1362113)资助项目。 (No.U1362113)

  • After heated at 400 ℃, the activated silica gel reacted with silicon tetrachloride to obtain chlorinated silica gel in anhydrous tetrahydrofuran. And a modified silica gel with carbonyl and amino groups on its surface was obtained by the reaction between chlorinated silica gel and acetamide. The modification has good coordination ability to Fe3+, and a supported catalyst with catalytic active site of Fe3+ evenly distributed was then prepared by coordination between Fe3+ and the surface organic modified silica gel. The synthesized catalyst has good catalytic oxidation performance to formaldehyde, and a maximum conversion of formaldehyde is about 91.3%.
  • 加载中
    1. [1]

      [1] Johnson L K, Killian C M, Brookhart M. J. Am. Chem. Soc., 1995,117:6414-6415

    2. [2]

      [2] Dong L J, Ge C L, Qin P Y, et al. Solid State Sci., 2014,31: 8-15

    3. [3]

      [3] Saleh J M, Hussian S M. J. Chem. Soc., Faraday Trans., 1986,82(1):2221-2234

    4. [4]

      [4] Christoskova S G, Danova N, Georgieva M, et al. Appl. Catal. A: Gen., 1995,128(2):219-229

    5. [5]

      [5] Sekine Y, Nishimura A. Atmos. Environ., 2001,35(11):2001-2007

    6. [6]

      [6] Álvarez-Galván M C, de la Peña O'Shea V A, Fierro J L G, et al. Catal. Commun., 2003,4(5):223-228

    7. [7]

      [7] TANG Xin-Fu(唐幸福), HUANG Xiu-Min(黄秀敏), SHAO Jian-Jun(邵建军), et al. Chinese J. Catal.(催化学报), 2006, 2:97-99

    8. [8]

      [8] Chen H, He J, Zhang C, et al. J. Phys. Chem. C, 2007,111 (49):18033-18038

    9. [9]

      [9] Chen T, Dou H Y, Li X L, et al. Microporous Mesoporous Mater., 2009,122(1/2/3):270-274

    10. [10]

      [10] Yang J J, Li D X, Zhang Z, et al. J. Photochem. Photobiol., A: Chem., 2000,137:197-202

    11. [11]

      [11] Tang X, Li Y, Huang X, et al. Appl. Catal. B: Environ, 2006,62(3/4):265-273

    12. [12]

      [12] Kecsk S T, Rask J, Kiss J. Appl. Catal. A: Gen., 2004,273 (1/2):55-62

    13. [13]

      [13] ZHang J, Jin Y, Li C, et al. Appl. Catal. B: Environ., 2009, 91(1/2):11-20

    14. [14]

      [14] Gurubasavaraj P M, Roesky H W. Inorg. Chem., 2008,47 (12):5324-5331

    15. [15]

      [15] Zhuravlev L T. Colloids Surf. A, 1993,74:7190

    16. [16]

      [16] WU Li-Qiang(武利强), YAN Fu-Lin(闫福林), YANG Chun-Guang (杨春广), et al. Chinese J. Org. Chem.(有机化学), 2010,30(11):1764-1767

    17. [17]

      [17] JIA Yun-Jie(贾云洁), LI Ming-Lei(李明磊), CUI Ji-Li(崔纪 利), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29 (3):465-473

  • 加载中
    1. [1]

      Yongmei Liu ,  Lisen Sun ,  Zhen Huang ,  Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

    2. [2]

      Xiaomei Ning ,  Liang Zhan ,  Xiaosong Zhou ,  Jin Luo ,  Xunfu Zhou ,  Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085

    3. [3]

      Xiyuan Zhang ,  Rui Dong ,  Yang Yang ,  Jiapeng Ding ,  Zhiwei Miao . Palladium-Catalyzed Tandem Cyclization of 4-Vinylbenzoxazinone and Indene-2-carbaldehyde: A Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(9): 361-367. doi: 10.12461/PKU.DXHX202410062

    4. [4]

      Xiaogang Liu ,  Mengyu Chen ,  Yanyan Li ,  Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007

    5. [5]

      Zhenxing Liu ,  Jiaen Hu ,  Zishi Cheng ,  Xinqi Hao . 基础有机化学教学中烯烃的氧化反应. University Chemistry, 2025, 40(6): 139-144. doi: 10.12461/PKU.DXHX202408107

    6. [6]

      . 

      CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化

      . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.

    7. [7]

      Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438

    8. [8]

      . 

      CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级

      . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.

    9. [9]

      Jiaming Xu ,  Yu Xiang ,  Weisheng Lin ,  Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093

    10. [10]

      Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO4. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104

    11. [11]

      Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO2 Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026

    12. [12]

      Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO2 Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049

    13. [13]

      Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi4Ti3O12 Coupling with g-C3N4 for Photocatalytic H2O2 Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009

    14. [14]

      Feng Han ,  Fuxian Wan ,  Ying Li ,  Congcong Zhang ,  Yuanhong Zhang ,  Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

    15. [15]

      Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi2WO6 for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050

    16. [16]

      Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO2 Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046

    17. [17]

      Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036

    18. [18]

      Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044

    19. [19]

      Jiajie Li ,  Xiaocong Ma ,  Jufang Zheng ,  Qiang Wan ,  Xiaoshun Zhou ,  Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117

    20. [20]

      Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(317)
  • HTML views(29)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return