Citation: Somboon Chaemchuen, ZHOU Kui, YAO Chen, LUO Zhi-xiong, Francis Verpoort. Lithium Incorporating Simultaneous with MOF-5 Synthesis for CO₂/CH₄ Mixed-Gas Separation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 509-513. doi: 10.11862/CJIC.2015.078 shu

Lithium Incorporating Simultaneous with MOF-5 Synthesis for CO₂/CH₄ Mixed-Gas Separation

1.
1 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China;
2.
2 School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China;
3.
3 School of Chemistry-Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China

Corresponding author: Francis Verpoort,
Received Date: 22 September 2014
Available Online: 25 December 2014
Fund Project: 国家自然科学基金(No.41140051)资助项目。 (No.41140051)

Variance lithium content MOF-5 (xLi-MOF-5, x=0, 1, 3, 5) were prepared by using solvothermal method. Lithium cation can be incorporated with MOF-5 during its crystallization process. The experiment demonstrated that lithium incorporation have significantly led different structure and surface chemistry in MOF-5. Different xLi-MOF-5 can reduce framework interpenetration level dissimilarly and lead material with substantially different adsorption separation properties. The 3Li-MOF-5 shows the highest CO₂ capacity (5.47 mmol·g^-1) and the best selectivity on 40% CO₂/60% CH₄ mixed gas.
- MOF-5;CO₂/CH₄ separation;lithium incorporation;interpenetration structure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Lithium Incorporating Simultaneous with MOF-5 Synthesis for CO2/CH4 Mixed-Gas Separation

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通讯作者: 陈斌, bchen63@163.com

Lithium Incorporating Simultaneous with MOF-5 Synthesis for CO₂/CH₄ Mixed-Gas Separation