Citation:
TANG Li-Zhi-Peng, YANG Ming-Wei, CHENG Mei-Ling, LIU Qi. Syntheses, Crystal Structures and Luminescent Properties of Two Cadmium Supramolecular Complexes Based on Water-Carboxylate Chains[J]. Chinese Journal of Inorganic Chemistry,
;2015, (3): 603-610.
doi:
10.11862/CJIC.2015.070
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Two cadmium supramolecular complexes, [Cd(HMPCA)2(2,2'-bpy)]·2H2O (1) and [Cd(HMPCA)2(phen)]·2.5H2O (2) (H2MPCA=5-methyl-1H-pyrazole-3-carboxylic acid, 2,2'-bpy=2,2'-bipyridine, phen=1,10-phenanthro-line), have been synthesized and characterized by elemental analysis, IR spectra and X-ray diffraction analysis. In 1 and 2, the mononuclear units are expanded to 3D supramolecular structures via O(C, N)-H…O hydrogen bonds, C-H…π interaction and π…π interaction. More interestingly, the water-carboxylate hydrogen bonded chains constructed by lattice water molecules and carboxylate groups play important role in the assembly of two supramolecular complexes. Besides, the thermal and luminescent properties of two complexes were also investigated.
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