Citation: TANG Li-Zhi-Peng, YANG Ming-Wei, CHENG Mei-Ling, LIU Qi. Syntheses, Crystal Structures and Luminescent Properties of Two Cadmium Supramolecular Complexes Based on Water-Carboxylate Chains[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 603-610. doi: 10.11862/CJIC.2015.070 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Cadmium Supramolecular Complexes Based on Water-Carboxylate Chains

1.
1 School of Petrochemical Engineering and Jiangsu Key Labroratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou, Jiangsu 213164, China;
2.
2 State Key Labroratory of Coordination, Nanjing University, Nanjing 210093, China

Corresponding author: CHENG Mei-Ling,
Received Date: 14 October 2014
Available Online: 12 December 2014
Fund Project: 江苏省高校自然科学研究面上项目(No.13KJB150001) (No.13KJB150001)

Two cadmium supramolecular complexes, [Cd(HMPCA)₂(2,2'-bpy)]·2H₂O (1) and [Cd(HMPCA)₂(phen)]·2.5H₂O (2) (H₂MPCA=5-methyl-1H-pyrazole-3-carboxylic acid, 2,2'-bpy=2,2'-bipyridine, phen=1,10-phenanthro-line), have been synthesized and characterized by elemental analysis, IR spectra and X-ray diffraction analysis. In 1 and 2, the mononuclear units are expanded to 3D supramolecular structures via O(C, N)-H…O hydrogen bonds, C-H…π interaction and π…π interaction. More interestingly, the water-carboxylate hydrogen bonded chains constructed by lattice water molecules and carboxylate groups play important role in the assembly of two supramolecular complexes. Besides, the thermal and luminescent properties of two complexes were also investigated.
- cadmium;water cluster;luminescent property;5-methyl-1H-pyrazole-3-carboxylic acid;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142