Citation: HUA Yi-Xiang, LIU Wen-Jin, WANG Hong-Ning, CHEN Ruo-Yu. Preparation of Sulfonic Acid-Functionalized Silica-Pillared Zirconium Phosphate with the Self-Assembly Method and Cocondensation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (3): 493-500. doi: 10.11862/CJIC.2015.065 shu

Preparation of Sulfonic Acid-Functionalized Silica-Pillared Zirconium Phosphate with the Self-Assembly Method and Cocondensation

1.
School of Petrochchemical Engineering, Changzhou University, Changzhou, Jiangsu 213164, China

Corresponding author: CHEN Ruo-Yu,
Received Date: 12 September 2014
Available Online: 17 November 2014
Fund Project: 国家自然科学基金(No.21101017/B0107)资助项目。 (No.21101017/B0107)

A series of sulfonic acid-functionalized silica-pillared zirconium phosphate materials with ordered layer structure were synthesized using the hexadecylamine (HDA) intercalated α-ZrP as raw material, dodecyl dimethyl benzyl ammonium chloride (DDBAC) as templet agent, tetraethyl orthosilicate (TEOS) and 3-mercaptopropyltrimethoxysilane (MPTMS) as the mixed silicon source, hydrogen peroxide as oxidant. The structure of the sulfonic acid-functionalized materials were characterized by XRD, SEM, N₂ adsorption-desorption and FTIR. Pillared layered structure and pore structure were optimized by adjusting the length of long chain in organic amine and templet. Meanwhile, the specific surface area and pore diameter of the resulting materials are about 163 m²·g^-1 and 2.17 nm, and the materials have ordered layer structure and pillared structure. The acid site property was adjusted, and the number of sulfonic acid groups and the total acid value respectively increase to 2.71 mmol·g^-1 and 5.20 mmol·g^-1. Due to the special steric effect and abundant Brönsted acid sites, the material shows excellent performance with 95.74% conversion in the esterification of citric acid with n-butanol.
- thiol-functionalized;sulfonic acid-functionalized;pillared;cocondensation;oxidation;esterification
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沈阳化工大学材料科学与工程学院沈阳 110142