Citation: LI Xin, ZHOU Shang-Yong, TIAN Li. Zinc(Ⅱ) Coordination Polymers Based on Aromatic Tetracarboxylate: Syntheses, Structures, and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 338-344. doi: 10.11862/CJIC.2015.057 shu

Zinc(Ⅱ) Coordination Polymers Based on Aromatic Tetracarboxylate: Syntheses, Structures, and Properties

1.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China

Corresponding author: TIAN Li,
Received Date: 11 August 2014
Available Online: 25 November 2014
Fund Project: 国家自然科学基金(No.21371133) (No.21371133)天津市自然科学基金资助项目(No.12JCZDJC27600)资助项目 (No.12JCZDJC27600)

Two coordination compounds, namely {[Zn₂(bptc)(DMF)₂(H₂O)]·DMF·H₂O}_n(1) and{[Zn(bte)(bptc)_0.5]·DMF·0.5H₂O}_n(2) (bte=bis(1,2,4-triazol^-1-yl)ethane, H₄bptc=biphenyl-3,3',5,5'-tetracarboxylic acid), have been synthesized and structurally characterized. 1 features a 3Dframework with PtS-type topology, in which each binuclear second-building-unit (SBU){Zn₂(O₂CR)₄} is linked to four biphenyl connectors (and vice versa). 2 is 2Dlayers, which are interconnected by weak C-H…Ointeractions to lead to 3Dsupramolecular framework. The thermal stability, and fluorescent emission of the two complexes have also been discussed. CCDC:1018691, 1; 1018790, 2.
- bis(1,2,4-triazol-1-yl)ethane;biphenyl-3,3,5,5-tetracarboxylic acid;3-D framework;supramolecular structure
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