Citation: HAO Xiao-Min, GU Chang-Sheng, HAN Si-Yin, FAN Run-Zhen, LI Yong, SONG Wen-Dong. Syntheses, Crystal Structures of Zn(Ⅱ) and Mn(Ⅱ) Complexes with Flexible Sulfur Containing Aromatic Acid and Nitrogen Heterocyclic Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 369-376. doi: 10.11862/CJIC.2015.052 shu

Syntheses, Crystal Structures of Zn(Ⅱ) and Mn(Ⅱ) Complexes with Flexible Sulfur Containing Aromatic Acid and Nitrogen Heterocyclic Ligands

1.
1. Department of Applied Chemistry, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China;
2.
2. College of Food Science and Technology, Guangdong Ocean University, Zhanjiang, Guangdong 524088, China;
3.
3. School of Petrochemical & Energy Engineering, Zhejiang Ocean University, Zhoushan, Zhejiang 316000, China

Corresponding author: GU Chang-Sheng, SONG Wen-Dong,
Received Date: 2 September 2014
Available Online: 2 November 2014
Fund Project: 广东省自然科学基金(No.S2012020011054) (No.S2012020011054)2011年省部产学研结合引导项目(No.102011B090400415) (No.102011B090400415)2011年度湛江市第八批科技攻关计划项目(No.2011C3108001)资助 (No.2011C3108001)

Two coordination polymers [Zn(EBLA)(2,2'-bipy)(H₂O)] (1) and [Mn(EBSA)(im)₂(H₂O)]_n (2) were synthesized by hydrothermal and evaporation methods using₂,2'-dithiosalicylic acid(EBSA), 2,2'-dipyridyl, imidazole, Zn(NO₃)₂·6H₂O and Mn(NO₃)₂·4H₂O. And the complexes were characterized by elemental analysis, FT-IRand thermogravimetrie analysis (TGA), meanwhile the crystal structures and fluorescence properties of the complex 1 have been studied. In complex 1, 2,2'-dicarboxydiphenylthioether (EBLA) was prepared with 2,2'-dithiosalicylic acid(EBSA) in situ reaction by hydrothermal method. The complex 1 is a dinuclear structure and Zn²⁺ ion is five-coordination in a distorted square pyramidal geometry; The complex 2 is a one-dimensional infinite linear chain and Mn²⁺ ion is six-coordination in a distorted octahedral geometry. Hydrogen bonding and π-π interactions are observed in these complexes. CCDC: 998513, 1; 1000616, 2.
- 2,2'-dithiosalicylic acid;2,2'-dicarboxydiphenylthioether;in situ reaction;crystal structure
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