Citation: JI Ke-Ming, MENG Fan-Hui, GAO Yuan, LI Zhong. Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 267-274. doi: 10.11862/CJIC.2015.050 shu

Solution Combustion Prepared Ni-Based Catalysts and Their Catalytic Performance for Slurry Methanation

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Zhong,
Received Date: 4 August 2014
Available Online: 7 November 2014
Fund Project: 国家"973"计划(No.2012CB723105) (No.2012CB723105)山西省青年基金(No.2013021007-4) (No.2013021007-4)中国博士后科学基金(2013M541210) (2013M541210)太原理工大学校青年团队基金(No.2013T091)资助项目 (No.2013T091)

Ni-Al₂O₃, Ni-ZrO₂, Ni-La₂O₃ and Ni-CeO₂ catalysts were prepared by solution combustion method using Al(NO₃)₃, ZrO(NO₃)₂, La(NO₃)₃ and Ce(NO₃)₃ (mixed with Ni(NO₃)₂ and urea in aqueous solution) as the support precursor, respectively. The COmethanation performances of catalysts were studied in slurry-bed reactor, and the catalysts were characterized by low temperature N₂ adsorption-desorption, XRD, SEM, TEM, H₂-TPRand H₂ chemsorption. The results show that the combustion preparation process of Ni-Al₂O₃ catalyst using Al(NO₃)₂ as the precursor is stable for long-duration(up to 23 s) and the catalyst has larger surface area (468 m²·g^-1) and metal surface area (10 m²·g^-1), smaller Ni particle (3~5 nm), excellent dispersion of Ni, and the catalyst has good catalytic performance, whose COconversion and CH₄ selectivity are 94% and 95%, respectively, and no catalyst deactivation is observed in 100h. The preparation process for catalysts using ZrO(NO₃)₂ and La(NO₃)₃ as precursors does not show obvious flame and burning time is also shorter (12 s and 5 s), the surface areas, metal surface areas and catalytic performances are lower than that of Ni-Al₂O₃ while that for the catalyst using Ce(NO₃)₂ as the precursor has high intensity combustion. The catalyst obtained from Ce(NO₃)₂ precursor shows lower surface area (22 m²·g^-1) and metal surface area (5 m²·g^-1), larger Ni particle and worse dispersion of Ni and the worst methanation catalytic performance with COconversion and CH₄ selectivity of 41% and 89%, respectively.
- catalysis;catalyst prepration;slurry-bed reactor;CO methanantion;solution combustion method;Ni-based catalyst;support
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沈阳化工大学材料科学与工程学院沈阳 110142