Citation: YOU Li-Xin, WANG Shu-Ju, XIONG Gang, DING Fu, SUN Ya-Guang. Two Coordination Polymers Generated via in situ Decarboxylation of 3-(2,4-Dicarboxylphenyl)-2,6-dicarboxylpyridine: Structure and Magnetism[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 323-328. doi: 10.11862/CJIC.2015.049 shu

Two Coordination Polymers Generated via in situ Decarboxylation of 3-(2,4-Dicarboxylphenyl)-2,6-dicarboxylpyridine: Structure and Magnetism

1.
Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: SUN Ya-Guang,
Received Date: 13 October 2014
Available Online: 9 November 2014
Fund Project: 国家自然科学基金(No.21071100) (No.21071100)辽宁特聘教授资助项目(No.2013204)资助项目 (No.2013204)

Two coordination polymers, [Cu(H₂dpcp)₂]_n (1) and [Mn₂(Hdpcp)₂(H₂O)₂·2H₂O]_n (2) [H₃dpcp=5-(2,4-dicarboxylphenyl)-2-carboxylpyridine] have been synthesized under hydrothermal conditions, and the H₃dpcp ligand was formed in situ via decarboxylation of the initial 3-(2,4-dicarboxylphenyl)-2,6-dicarboxylpyridine (H₄dpdp). Crystal structural analyses indicate that two complexes crystallize in the same monoclinic system, and space group P2₁/c for complex 1 with a=0.639(13) nm, b=1.835(4) nm, c=1.115(2) nm, β=102.29(3)°, Z=2, and space group C2/c for complex 2 with a=3.126(6) nm, b=1.004(2) nm, c=1.080(2) nm, β=93.73(3)°, Z=4. For 1, Cu(Ⅱ) were bridged by H₂dpcp-ligands to form a 1Dchain structure. For 2, Mn(Ⅱ) were linked by Hdpcp2-ligands to form 2Dlayers and further extend to a 3Dstructure through the hydrogen bonding interaction. The negative value of θ shows the existence of antiferromagnetic coupling in 2. CCDC: 1021238, 1; 1021239, 2.
- coordination polymers;in situ decarboxylation;3-(2,4-dicarboxylphenyl)-2,6-dicarboxylpyridine;magnetism
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沈阳化工大学材料科学与工程学院沈阳 110142