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Citation: LUAN Jing-Fei, HU Wen-Hua, CHEN Biao-Hang, PEI Dong-Hua. Structural and Photocatalytic Properties of Fe2BiTaO7 Nanocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 385-398. doi: 10.11862/CJIC.2015.046 shu

Structural and Photocatalytic Properties of Fe2BiTaO7 Nanocatalyst

  • 1.

    State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

  • Corresponding author: LUAN Jing-Fei, 
  • Received Date: 17 September 2014
    Available Online: 13 November 2014

    Fund Project: 国家自然科学基金(No.21277067) (No.21277067)中以科学与战略研究开发专项资金(No.5)资助项目 (No.5)

  • Fe2BiTaO7 powder photocatalyst was synthesized by a solid state reaction method. The structural and photocatalytic properties of Fe2BiTaO7 were characterized by XRD, SEM, TEMand UV-Vis diffuse reflectance spectroscopy. The results show that Fe2BiTaO7 crystallizes with the pyrochlore-type structure, cubic crystal system and space group Fd3m. The estimated band gap of Fe2BiTaO7 is 1.72 eV. The photocatalytic degradation of rhodamine Bover Fe2BiTaO7, P25 TiO2, N-doped TiO2 and Bi2InTaO7 was investigated under visible light irradiation. The photocatalytic efficiency with Fe2BiTaO7 catalyst is 1.5 times of N-doped TiO2 catalyst after 140 minutes under visible light irradiation. Fe2BiTaO7 has higher visible-light photocatalytic performance and shows much better activity than that of other photocatalysts. The photocatalytic degradation of rhodamine Bfollows the first-order reaction kinetics, and the first-order rate constant is 0.02293 min-1 for Fe2BiTaO7. The possible photocatalytic degradation pathway of rhodamine Bunder visible light irradiation is suggested. In addition, the photocatalytic degradation of phenol over Fe2BiTaO7 catalyst was investigated under visible light irradiation. Fe2BiTaO7 (visible light) photocatalysis system is confirmed to be suitable for textile industry wastewater treatment.
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    1. [1]

      [1] Annadurai G, Juang R S, Lee D J. J. Hazard. Mater., 2002, 92(3):263-274

    2. [2]

      [2] Bhatnagar A, Jain A K. J. Colloid Interface Sci., 2005,281 (1):49-55

    3. [3]

      [3] Su L, GanY X. Composites Part B, 2012,43(2):170-182

    4. [4]

      [4] Wang S B, Boyjoo Y, Choueib A. Chemosphere, 2005,60 (10):1401-1407

    5. [5]

      [5] Shakir K, Elkafrawy A F, Ghoneimy H F, et al. Water Res., 2010,44(5):1449-1461

    6. [6]

      [6] Shen C S, Shen Y, Wen Y Z, et al. Water Res., 2011,45(16): 5200-5210

    7. [7]

      [7] Zhang F L, Zhao J C, Zang L, et al. J. Mol. Catal. A: Chem., 1997,120(1/2/3):173-178

    8. [8]

      [8] Brustein V P, Cavalcanti C L B, de Melo M R, et al. Appl. Biochem. Biotechnol., 2012,166(2):268-275

    9. [9]

      [9] Wang S B, Li H, Xu L Y. J. Colloid Interface Sci., 2006, 295(1):71-78

    10. [10]

      [10] Guo Y P, Zhao J Z, Zhang H, et al. Dyes Pigm., 2005,66 (2):123-128

    11. [11]

      [11] Fu H B, Pan C S, Yao W Q, et al. J. Phys. Chem. B, 2005, 109(47):22432-22439

    12. [12]

      [12] Ashraf U, Chat O A, Dar A A. Chemosphere, 2014,99:199-206

    13. [13]

      [13] Parida K M, Sahu N, Biswal N R, et al. J. Colloid Interface Sci., 2008,318(2):231-237

    14. [14]

      [14] Mahmoodi N M, Najafi F. Microporous Mesoporous Mater., 2012,156:153-160

    15. [15]

      [15] Park H O, Oh S, Bade R, et al. KSCE J. Civ. Eng., 2011,15 (3):453-461

    16. [16]

      [16] Chatha S A S, Asgher M, Ali S, et al. Carbohydr. Polym., 2012,87(2):1476-1481

    17. [17]

      [17] Xie Y B, Yuan C W, Li X Z. Colloid Surf. A, 2005,252 (1):87-94

    18. [18]

      [18] Pan H Q, Li X K, Zhuang Z J, et al. J. Mol. Catal. A: Chem., 2011,345(1/2):90-95

    19. [19]

      [19] Luan J F, Wang S, Ma K, et al. J. Phys. Chem. C, 2010,114 (20):9398-9407

    20. [20]

      [20] Rauf M A, Ashraf S S. Chem. Eng. J., 2009,151(1/2/3):10-18

    21. [21]

      [21] Chatterjee D, Mahata A. J. Photochem. Photobiol. A-Chem., 2002,153(1/2/3):199-204

    22. [22]

      [22] Kyung H, Lee J, Choi W Y. Environ. Sci. Technol., 2005,39 (7):2376-2382

    23. [23]

      [23] Su L S, Gan Y X. Composities Part B, 2012,43(2):170-182

    24. [24]

      [24] Dubal D P, Dhawale D S, More A M, et al. J. Mater. Sci., 2011,46(7):2288-2293

    25. [25]

      [25] Bao N, Li Y, Yu X H, et al. Environ. Sci. Pollut. Res. Int., 2013,20(2):897-906

    26. [26]

      [26] Qu P, Zhao J C, Shen T, et al. J. Mol. Catal. A: Chem., 1998,129(2-3):257-268

    27. [27]

      [27] Ghosh J P, Sui R H, Langford C H, et al. Water Res., 2009, 43(18):4499-4506

    28. [28]

      [28] Adhikari R, Gyawali G, Sekino T, et al. J. Solid State Chem., 2013,197:560-565

    29. [29]

      [29] Zhang X, Ai Z H, Jia F L, et al. Mater. Chem. Phys., 2007, 103(1):162-167

    30. [30]

      [30] Zhou J K, Zou Z G, Ray A K, et al. Ind. Eng. Chem. Res., 2007,46(3):745-749

    31. [31]

      [31] Zhang G K, Zou X, Gong J, et al. J. Alloys Compd., 2006, 425(1/2):76-80

    32. [32]

      [32] Feng P, Chen C L, Hao Y, et al. Mater. Chem. Phys., 2009, 116(1):294-299

    33. [33]

      [33] Li J P, Zhang X, Ai Z H, et al. J. Phys. Chem. C, 2007,111 (18):6832-6836

    34. [34]

      [34] Li X K, Kako T, Ye J H. Appl. Catal. A: Gen., 2007,326(1): 1-7

    35. [35]

      [35] Hou L R, Yuan C Z, Peng Y. J. Mol. Catal. A: Chem., 2006, 252(1/2):132-135

    36. [36]

      [36] Tang X D, Ye H Q, Liu H, et al. Chem. Phys. Lett., 2009, 484(1/2/3):48-53

    37. [37]

      [37] Dong H J, Chen G, Sun J X, et al. Appl. Catal. B: Environ., 2013,134:46-54

    38. [38]

      [38] Li K W, Wang H, Yan H. J. Mol. Catal. A: Chem., 2006,249 (1/2):65-70

    39. [39]

      [39] Luan J F, Pan B C, Paz Y, et al. Phys. Chem. Chem. Phys., 2009,11(29):6289-6298

    40. [40]

      [40] Luan J F, Li M, Ma K, et al. Chem. Eng. J., 2011,167(1): 162-171

    41. [41]

      [41] Yang H, Li J, Wang L Y, et al. Catal. Commun., 2013,35: 101-104

    42. [42]

      [42] Nashim A, Parida K M. Chem. Eng. J., 2013,215:608-615

    43. [43]

      [43] Luan J F, Zhao W, Feng J W, et al. J. Hazard. Mater., 2009, 164(2/3):781-789

    44. [44]

      [44] Marugan J, Hufschmidt D, Sagawe G, et al. Water Res., 2006,40(4):833-839

    45. [45]

      [45] Sakthivel S, Shankar M V, Palanichamy M, et al. Water Res., 2004,38(13):3001-3008

    46. [46]

      [46] Fazey P G, Oconnor B H, Hammond L C. Clays Clay Miner., 1991,39(3):248-253

    47. [47]

      [47] Zou Z, Ye J, Arakawa H. J. Mater. Sci. Lett., 2000,19(21): 1909-1911

    48. [48]

      [48] Tauc J, Grigorov R, Vancu A. Phys. Status Solidi, 1966,15 (2):627-637

    49. [49]

      [49] Butler M A. J. Appl. Phys., 1977,48(5):1914-1920

    50. [50]

      [50] Liu G M, Wu T X, Zhao J C, et al. Environ. Sci. Technol., 1999,33(12):2081-2087

    51. [51]

      [51] Li J Y, Ma W H, Lei P X, et al. J. Environ. Sci., 2007,19 (7):892-896

    52. [52]

      [52] He Z, Yang S G, Ju Y M, et al. J. Environ. Sci., 2009,21(2): 268-272

    53. [53]

      [53] He Z, Sun C, Yang S G, et al. J. Hazard. Mater., 2009,162 (2/3):1477-1486

    54. [54]

      [54] Oshikiri M, Boero M, Ye J H, et al. J. Chem. Phys., 2002, 117(15):7313-7318

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