Citation: LUAN Jing-Fei, HU Wen-Hua, CHEN Biao-Hang, PEI Dong-Hua. Structural and Photocatalytic Properties of Fe₂BiTaO₇ Nanocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 385-398. doi: 10.11862/CJIC.2015.046 shu

Structural and Photocatalytic Properties of Fe₂BiTaO₇ Nanocatalyst

1.
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

Corresponding author: LUAN Jing-Fei,
Received Date: 17 September 2014
Available Online: 13 November 2014
Fund Project: 国家自然科学基金(No.21277067) (No.21277067)中以科学与战略研究开发专项资金(No.5)资助项目 (No.5)

Fe₂BiTaO₇ powder photocatalyst was synthesized by a solid state reaction method. The structural and photocatalytic properties of Fe₂BiTaO₇ were characterized by XRD, SEM, TEMand UV-Vis diffuse reflectance spectroscopy. The results show that Fe₂BiTaO₇ crystallizes with the pyrochlore-type structure, cubic crystal system and space group Fd3m. The estimated band gap of Fe₂BiTaO₇ is 1.72 eV. The photocatalytic degradation of rhodamine Bover Fe₂BiTaO₇, P25 TiO₂, N-doped TiO₂ and Bi₂InTaO₇ was investigated under visible light irradiation. The photocatalytic efficiency with Fe₂BiTaO₇ catalyst is 1.5 times of N-doped TiO₂ catalyst after 140 minutes under visible light irradiation. Fe₂BiTaO₇ has higher visible-light photocatalytic performance and shows much better activity than that of other photocatalysts. The photocatalytic degradation of rhodamine Bfollows the first-order reaction kinetics, and the first-order rate constant is 0.02293 min^-1 for Fe₂BiTaO_7. The possible photocatalytic degradation pathway of rhodamine Bunder visible light irradiation is suggested. In addition, the photocatalytic degradation of phenol over Fe₂BiTaO₇ catalyst was investigated under visible light irradiation. Fe₂BiTaO₇ (visible light) photocatalysis system is confirmed to be suitable for textile industry wastewater treatment.
- catalysis;Fe₂BiTaO₇;optical properties;visible light;photocatalytic degradation;rhodamine B
1. [1]
  [1] Annadurai G, Juang R S, Lee D J. J. Hazard. Mater., 2002, 92(3):263-274
2. [2]
  [2] Bhatnagar A, Jain A K. J. Colloid Interface Sci., 2005,281 (1):49-55
3. [3]
  [3] Su L, GanY X. Composites Part B, 2012,43(2):170-182
4. [4]
  [4] Wang S B, Boyjoo Y, Choueib A. Chemosphere, 2005,60 (10):1401-1407
5. [5]
  [5] Shakir K, Elkafrawy A F, Ghoneimy H F, et al. Water Res., 2010,44(5):1449-1461
6. [6]
  [6] Shen C S, Shen Y, Wen Y Z, et al. Water Res., 2011,45(16): 5200-5210
7. [7]
  [7] Zhang F L, Zhao J C, Zang L, et al. J. Mol. Catal. A: Chem., 1997,120(1/2/3):173-178
8. [8]
  [8] Brustein V P, Cavalcanti C L B, de Melo M R, et al. Appl. Biochem. Biotechnol., 2012,166(2):268-275
9. [9]
  [9] Wang S B, Li H, Xu L Y. J. Colloid Interface Sci., 2006, 295(1):71-78
10. [10]
  [10] Guo Y P, Zhao J Z, Zhang H, et al. Dyes Pigm., 2005,66 (2):123-128
11. [11]
  [11] Fu H B, Pan C S, Yao W Q, et al. J. Phys. Chem. B, 2005, 109(47):22432-22439
12. [12]
  [12] Ashraf U, Chat O A, Dar A A. Chemosphere, 2014,99:199-206
13. [13]
  [13] Parida K M, Sahu N, Biswal N R, et al. J. Colloid Interface Sci., 2008,318(2):231-237
14. [14]
  [14] Mahmoodi N M, Najafi F. Microporous Mesoporous Mater., 2012,156:153-160
15. [15]
  [15] Park H O, Oh S, Bade R, et al. KSCE J. Civ. Eng., 2011,15 (3):453-461
16. [16]
  [16] Chatha S A S, Asgher M, Ali S, et al. Carbohydr. Polym., 2012,87(2):1476-1481
17. [17]
  [17] Xie Y B, Yuan C W, Li X Z. Colloid Surf. A, 2005,252 (1):87-94
18. [18]
  [18] Pan H Q, Li X K, Zhuang Z J, et al. J. Mol. Catal. A: Chem., 2011,345(1/2):90-95
19. [19]
  [19] Luan J F, Wang S, Ma K, et al. J. Phys. Chem. C, 2010,114 (20):9398-9407
20. [20]
  [20] Rauf M A, Ashraf S S. Chem. Eng. J., 2009,151(1/2/3):10-18
21. [21]
  [21] Chatterjee D, Mahata A. J. Photochem. Photobiol. A-Chem., 2002,153(1/2/3):199-204
22. [22]
  [22] Kyung H, Lee J, Choi W Y. Environ. Sci. Technol., 2005,39 (7):2376-2382
23. [23]
  [23] Su L S, Gan Y X. Composities Part B, 2012,43(2):170-182
24. [24]
  [24] Dubal D P, Dhawale D S, More A M, et al. J. Mater. Sci., 2011,46(7):2288-2293
25. [25]
  [25] Bao N, Li Y, Yu X H, et al. Environ. Sci. Pollut. Res. Int., 2013,20(2):897-906
26. [26]
  [26] Qu P, Zhao J C, Shen T, et al. J. Mol. Catal. A: Chem., 1998,129(2-3):257-268
27. [27]
  [27] Ghosh J P, Sui R H, Langford C H, et al. Water Res., 2009, 43(18):4499-4506
28. [28]
  [28] Adhikari R, Gyawali G, Sekino T, et al. J. Solid State Chem., 2013,197:560-565
29. [29]
  [29] Zhang X, Ai Z H, Jia F L, et al. Mater. Chem. Phys., 2007, 103(1):162-167
30. [30]
  [30] Zhou J K, Zou Z G, Ray A K, et al. Ind. Eng. Chem. Res., 2007,46(3):745-749
31. [31]
  [31] Zhang G K, Zou X, Gong J, et al. J. Alloys Compd., 2006, 425(1/2):76-80
32. [32]
  [32] Feng P, Chen C L, Hao Y, et al. Mater. Chem. Phys., 2009, 116(1):294-299
33. [33]
  [33] Li J P, Zhang X, Ai Z H, et al. J. Phys. Chem. C, 2007,111 (18):6832-6836
34. [34]
  [34] Li X K, Kako T, Ye J H. Appl. Catal. A: Gen., 2007,326(1): 1-7
35. [35]
  [35] Hou L R, Yuan C Z, Peng Y. J. Mol. Catal. A: Chem., 2006, 252(1/2):132-135
36. [36]
  [36] Tang X D, Ye H Q, Liu H, et al. Chem. Phys. Lett., 2009, 484(1/2/3):48-53
37. [37]
  [37] Dong H J, Chen G, Sun J X, et al. Appl. Catal. B: Environ., 2013,134:46-54
38. [38]
  [38] Li K W, Wang H, Yan H. J. Mol. Catal. A: Chem., 2006,249 (1/2):65-70
39. [39]
  [39] Luan J F, Pan B C, Paz Y, et al. Phys. Chem. Chem. Phys., 2009,11(29):6289-6298
40. [40]
  [40] Luan J F, Li M, Ma K, et al. Chem. Eng. J., 2011,167(1): 162-171
41. [41]
  [41] Yang H, Li J, Wang L Y, et al. Catal. Commun., 2013,35: 101-104
42. [42]
  [42] Nashim A, Parida K M. Chem. Eng. J., 2013,215:608-615
43. [43]
  [43] Luan J F, Zhao W, Feng J W, et al. J. Hazard. Mater., 2009, 164(2/3):781-789
44. [44]
  [44] Marugan J, Hufschmidt D, Sagawe G, et al. Water Res., 2006,40(4):833-839
45. [45]
  [45] Sakthivel S, Shankar M V, Palanichamy M, et al. Water Res., 2004,38(13):3001-3008
46. [46]
  [46] Fazey P G, Oconnor B H, Hammond L C. Clays Clay Miner., 1991,39(3):248-253
47. [47]
  [47] Zou Z, Ye J, Arakawa H. J. Mater. Sci. Lett., 2000,19(21): 1909-1911
48. [48]
  [48] Tauc J, Grigorov R, Vancu A. Phys. Status Solidi, 1966,15 (2):627-637
49. [49]
  [49] Butler M A. J. Appl. Phys., 1977,48(5):1914-1920
50. [50]
  [50] Liu G M, Wu T X, Zhao J C, et al. Environ. Sci. Technol., 1999,33(12):2081-2087
51. [51]
  [51] Li J Y, Ma W H, Lei P X, et al. J. Environ. Sci., 2007,19 (7):892-896
52. [52]
  [52] He Z, Yang S G, Ju Y M, et al. J. Environ. Sci., 2009,21(2): 268-272
53. [53]
  [53] He Z, Sun C, Yang S G, et al. J. Hazard. Mater., 2009,162 (2/3):1477-1486
54. [54]
  [54] Oshikiri M, Boero M, Ye J H, et al. J. Chem. Phys., 2002, 117(15):7313-7318
1. [1]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255
2. [2]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
3. [3]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Qilin YU , Yifei XU , Pengjun ZHANG , Shuwei HAO , Chongqiang ZHU , Chunhui YANG . Effect of regulating K⁺/Na⁺ ratio on the structure and optical properties of double perovskite Cs₂NaBiCl₆: Mn²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418
6. [6]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
7. [7]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
8. [8]
  Yuan CONG , Yunhao WANG , Wanping LI , Zhicheng ZHANG , Shuo LIU , Huiyuan GUO , Hongyu YUAN , Zhiping ZHOU . Construction and photocatalytic properties toward rhodamine B of CdS/Fe₃O₄ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2241-2249. doi: 10.11862/CJIC.20240219
9. [9]
  Tongyan Yu , Pan Xu . Visible-Light Photocatalyzed Radical Rearrangement Reaction. University Chemistry, 2025, 40(7): 169-176. doi: 10.12461/PKU.DXHX202409070
10. [10]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
11. [11]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
12. [12]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
13. [13]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
14. [14]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
15. [15]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
16. [16]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
19. [19]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
20. [20]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(545)
HTML views(65)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Structural and Photocatalytic Properties of Fe2BiTaO7 Nanocatalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Structural and Photocatalytic Properties of Fe₂BiTaO₇ Nanocatalyst