Citation: LI Shi-Xiong, LIAO Bei-Ling, LUO Pei, JIANG Yi-Min. Syntheses, Structures, Fluorescence and Anticancer Activity of Co(Ⅱ) and Ag(Ⅰ) Complexes with 4-(3H)-Quinazolinone[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 291-296. doi: 10.11862/CJIC.2015.045 shu

Syntheses, Structures, Fluorescence and Anticancer Activity of Co(Ⅱ) and Ag(Ⅰ) Complexes with 4-(3H)-Quinazolinone

LI Shi-Xiong ^1,2 ,
LIAO Bei-Ling ^1,2,, ,
LUO Pei ¹ ,
JIANG Yi-Min ¹

1.
1. College of Chemistry and Pharmacy, Guangxi Normal University, Guilin, Guangxi 541004, China;
2.
2. College of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi 546300, China

Corresponding author: LIAO Bei-Ling,
Received Date: 30 August 2014
Available Online: 29 October 2014
Fund Project: 桂林市科学研究与技术开发计划(No.20110330) (No.20110330)广西教育厅基础研究(No.200807MS090)资助项目 (No.200807MS090)

Complexes [Co(L)₂(H₂O)₂(NO₃)₂] (1) and [Ag(L)₂(NO₃)] (2) were synthesized (L=4-(3H)-quinazolinone), and were both characterized by single crystal X-ray diffraction analysis and thermogravimetric analysis. Single crystal X-ray diffraction analysis showed that they all belong to triclinic space group, but 1 is six-coordinated and 2 is three-coordinated. Meanwhile, the solid-state fluorescence and anticancer activity of 2 also were studied. CCDC: 1011403, 1; 1011401, 2.
- complex;4-(3H)-quinazolinone;fluorescence;anticancer activity
1. [1]
  [1] Kaur N, Kaur P J, Singh K. RSC Adv., 2014,4:29340-29343
2. [2]
  [2] Mohamedally K. Chem. Soc. Rev., 2009,38:1353-1379
3. [3]
  [3] Wang R J, Deng L J, Fu M, et al. J. Mater. Chem., 2012,22: 23454-23460
4. [4]
  [4] Zhou H, Yan X F, Peng Z G, et al. J. Coord. Chem., 2009, 62:655-664
5. [5]
  [5] CHEN Hui-Qing(陈慧卿), ZHANG Kun(张坤), XU Feng(许峰), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29 (11):2265-2275
6. [6]
  [6] Nai K M, Chung Y L, XiaoY W, et al. Biochem. Pharmacol., 2004,67:167-174
7. [7]
  [7] Bekhit A A, HABIB N S, EL-Din A. Boll. Chim. Farm., 2001, 140:297-301
8. [8]
  [8] LI Ling(李玲), DONG Tong-Yi(董同义),LI Xiu-Lu(李修禄), et al. Acta Pharmaceutica Sinica(药学学报), 1994,29:128-131
9. [9]
  [9] Cao S L, Feng Y P, Jiang Y Y, et al. Bioorg. Med. Chem. Lett., 2005,15:1915-1917
10. [10]
  [10] Liu S, Liu F, Yu X, et al. Bioorg. Med. Chem., 2006,14: 1425-1430
11. [11]
  [11] Refaie F M, Esmat A, Gawad S M, et al. Lipids Health Dis., 2005,4:22
12. [12]
  [12] Habib N S , Ismail K A , Eltombary A A, et al. Pharmazie, 2000,55:495-499
13. [13]
  [13] Kurogi Y, Inoue Y, Tsumi K, et al. J. Med. Chem., 1996,39: 1433-1437
14. [14]
  [14] Dolomanov O V, Bourhis L J, Gildea R J. et al. J. Appl. Cryst., 2009,42:339-341
15. [15]
  [15] Jin F, Zhu H Z, Yan Y, et al. J. Coord. Chem., 2014,67: 1198-1207
16. [16]
  [16] Liang Y J, Meng X J, Huang F P. J. Coord. Chem., 2011,64: 3751-3757
17. [17]
  [17] Eberhard J, Stoll I, Brockhinke R, et al. CrystEngComm, 2013,15:4225-4248
18. [18]
  [18] Qi R L, Shen M W, Cao X Y, et al. Analyst, 2011,136: 2897-2906
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