Citation: CHEN Yan-Min, CHU Zhao-Hua, HAO Gui-Xia, XIE Qing-Fan. Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 317-322. doi: 10.11862/CJIC.2015.044 shu

Syntheses, Crystal Structures and Fluorescence Properties of a Hydrazone Schiff Base and its Zinc Coordination Polymer

1.
1. College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China;
2.
2. Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China

Corresponding author: CHU Zhao-Hua,
Received Date: 8 October 2014
Available Online: 13 November 2014
Fund Project: 福建省教育厅A类重点项目(No.JA14261) (No.JA14261)广东省科技厅科技项目(No.2011B090400521)资助 (No.2011B090400521)

Ahydrazone Schiff base monohydrate, C₁₇H₂₀N₄O₂·H₂O (1), was synthesized by rection of 4-diethylamino -salicylaldehyde and isoniazide, and its zinc(Ⅱ) coordination polymer, [Zn(L)(Phen)]_∞ (2) with double helix structure, was prepared. They have been characterized by elemental analysis, IR, UV-vis spectra and X-ray diffraction single crystal analysis and the fluorescence property of the compounds were investigated, which result showed that the crystal of 1 belongs to the triclinic system,space group P1 with cell parameters a=0.71058(4) nm, b=1.0045(2) nm, c=1.3054(3) nm, α=97.383(11)°, β=102.989(12)°, γ=104.038(10)°, V=8.641(3) nm³, Z=2, M_r=330.39, D_c=1.270 g·cm^-3 and the crystal of 2 belongs to the trigonal system,space group P₃₂ with cell parameters a=1.68654(12) nm, b=1.68654(12) nm, c=0.79656(12) nm, V=1.9622(5) nm³, Z=3, M_r=555.93, D_c=1.411 g·cm^-3. The compounds 1 and 2 exhibit luminescence with emission maximum at 524 and 535 nm at room temperature, respectively. CCDC: 995121, 1; 994066, 2.
- zinc complex;crystal structure;fluorescence properties;salicylaldehyde;isonicotinoyl hydrazone
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