Citation: PAN Xu-Chen, TANG Jing, XUE Hai-Rong, GUO Hu, FAN Xiao-Li, ZHU Ze-Tao, HE Jian-Ping. Synthesis and Electrocatalytic Performance of N-Doped Ordered Mesoporous Carbon-Ni Nanocomposite[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 282-290. doi: 10.11862/CJIC.2015.039 shu

Synthesis and Electrocatalytic Performance of N-Doped Ordered Mesoporous Carbon-Ni Nanocomposite

1.
College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Corresponding author: HE Jian-Ping,
Received Date: 12 August 2014
Available Online: 5 November 2014
Fund Project: 国家自然科学基金(No.51372115)资助项目 (No.51372115)

Highly ordered mesoporous carbon co-modified with Ni-Ncan be prepared via homogeneous phase route as well as dual-phase route, named as Ni-N-OMC-1 and Ni-N-OMC-2 respectively. Triblock copolymer Pluronic F127 were employed as the template agent, urea as the Nprecursor, NiCl₂ as the Ni source and resorcinol-formaldehyde resin as the carbon precursor. X-ray diffraction (XRD), Raman, and transmission electron microscope (TEM) showed that nickel particles dispersed in the carbon matrix in forms of metal nickel, in situ catalyzing the graphitization of amorphous carbon. X-ray photoelectron spectroscopy (XPS) revealed that urea existed in four different Nspecies after heat treatment: sp³ nitrogen atoms bonded to carbon atoms, pyridine-like N, sp³ nitrogen atoms bonded to carbon atoms and quaternary-Natoms. The co-modification of nitrogen and nickel changed the physicochemical properties of carbon matrix, thus making for the loading and dispersing of Pt. Pt nanoparticles deposited on Ni-N-OMC-1 nanocompsite showed excellent electrocatalytic activity. The electrochemical active surface area of hydrogen oxidation was 138.53 m²·g^-1 and the limiting current density in ORRwas 5.32 mA·cm^-2, which indicated higher electrocatalytic ability than that of the commercial 20% Pt/Ccatalysts (4.49 mA·cm^-2, 96.98 m²·g^-1).
- homogeneous phase route;dual-phase route;ordered mesoporous carbon;co-modified with Ni-N;electrocatalytic activity
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