Citation: FAN Dong, MA Zhi-Hong, LI Su-Zhen, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses and Structures of Metal Carbonyl Complexes Based on Two Substituted Tetramethylcyclopentadienyl Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 198-204. doi: 10.11862/CJIC.2015.038 shu

Syntheses and Structures of Metal Carbonyl Complexes Based on Two Substituted Tetramethylcyclopentadienyl Ligands

  • Corresponding author: LIN Jin, 
  • Received Date: 14 July 2014
    Available Online: 10 November 2014

    Fund Project: 国家自然科学基金(No.21372061) (No.21372061)河北省自然科学基金(No.B2013205025,B2014205018) (No.B2013205025,B2014205018)河北师范大学重点基金(No.L2012Z02)资助项目. (No.L2012Z02)

  • Via thermal reactions of the substituted tetramethylcyclopentadienes [C5Me4HR] [R=4-BrPh (1), (MeC5H3N)CH2 (2)] with Mo(CO)6, Ru3(CO)12 and Fe(CO)5, respectively in refluxing xylene, the responding dinuclear metal carbonyl complexes trans-[η5-C5Me4R]2Mo2(CO)6 (3, 4), trans-[(η5-C5Me4R)Ru(CO)(μ-CO)]2 (5, 6), and trans-[η5-(C5Me4R)Fe(CO)(μ-CO)]2 (7, 8) have been obtained. These complexes have been characterized by elemental analysis, IR, and 1H NMR spectra. The crystal structures of 3, 5, 6 and 8 have been determined by X-ray crystallography. CCDC: 934733, 3; 944267, 5; 926404, 6; 926405, 8.
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