Citation: FAN Dong, MA Zhi-Hong, LI Su-Zhen, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses and Structures of Metal Carbonyl Complexes Based on Two Substituted Tetramethylcyclopentadienyl Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 198-204. doi: 10.11862/CJIC.2015.038 shu

Syntheses and Structures of Metal Carbonyl Complexes Based on Two Substituted Tetramethylcyclopentadienyl Ligands

1.
1. The College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;
2.
2. College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China;
3.
3 Hebei College of Industry and Technology, Shijiazhuang 050091, China

Corresponding author: LIN Jin,
Received Date: 14 July 2014
Available Online: 10 November 2014
Fund Project: 国家自然科学基金(No.21372061) (No.21372061)河北省自然科学基金(No.B2013205025,B2014205018) (No.B2013205025,B2014205018)河北师范大学重点基金(No.L2012Z02)资助项目. (No.L2012Z02)

Via thermal reactions of the substituted tetramethylcyclopentadienes [C₅Me₄HR] [R=4-BrPh (1), (MeC₅H₃N)CH₂ (2)] with Mo(CO)₆, Ru₃(CO)₁₂ and Fe(CO)₅, respectively in refluxing xylene, the responding dinuclear metal carbonyl complexes trans-[η5-C₅Me₄R]₂Mo₂(CO)₆ (3, 4), trans-[(η5-C₅Me₄R)Ru(CO)(μ-CO)]₂ (5, 6), and trans-[η5-(C₅Me₄R)Fe(CO)(μ-CO)]₂ (7, 8) have been obtained. These complexes have been characterized by elemental analysis, IR, and ¹H NMR spectra. The crystal structures of 3, 5, 6 and 8 have been determined by X-ray crystallography. CCDC: 934733, 3; 944267, 5; 926404, 6; 926405, 8.
- cyclopentadiene;metal carbonyl complex;X-ray diffraction;structure
1. [1]
  [1] Borah M, Bhattacharyya P K, Das P. Appl. Organometal. Chem., 2012,26:130-134
2. [2]
  [2] Stanowski S, Nicholas K M, Srivastava R S. Organometallics, 2012,31:515-518
3. [3]
  [3] Do Y, Han J, Rhee Y H, et al. Adv. Synth. Catal., 2011,353: 3363-3366
4. [4]
  [4] Kuninobu Y, Uesugi T, Kawata A, et al. Angew. Chem. Int. Ed., 2011,50:10406-10408
5. [5]
  [5] Butenschn H. Chem. Rev., 2000,100:1527-1564
6. [6]
  [6] Siemeling U. Chem. Rev., 2000,100:1495-1526
7. [7]
  [7] Lin J, Zhao M X, Ma Z H, et al. J. Chem. Crystallogr., 2009, 39:642-645
8. [8]
  [8] Lin J, Ma Z H, Li F, et al. Transition Met. Chem., 2009,34: 855-859
9. [9]
  [9] Ma Z H, Zhao M X, Li F, et al. Transition Met. Chem., 2010, 35:387-391
10. [10]
  [10] Tian L J, Ma Z H, Han Z G, et al. Transition Met. Chem., 2011,36:151-156
11. [11]
  [11] Ma Z H, Tian L J, Li S Z, et al. Transition Met. Chem., 2012,37:135-140
12. [12]
  [12] Ma Z H, Wang N, Guo K M, et al. Inorg. Chim. Acta, 2013, 399:126-130
13. [13]
  [13] Bensley D M, Mintz E A Jr, Sussangkarn S J. J. Org. Chem., 1988,53:4417-4419
14. [14]
  [14] Enders M, Ludwig G, Pritzkow H. Organometallics, 2001,20: 827-833
15. [15]
  [15] Lin J, Gao P, Li B, et al. Inorg. Chim. Acta, 2006,359:4503- 4510
16. [16]
  [16] MA Zhi-Hong(马志宏), ZHAO Ming-Xia(赵明霞), LIN Li- Zhi(林丽枝), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26:1908-1911
17. [17]
  [17] Adams R D, Collins D M, Cotton F A. Inorg. Chem., 1974, 13:1086-1090
18. [18]
  [18] CHEN Shou-Shan(陈寿山), WANG Jia-Xi(王家喜), WANG Xu-Kun(王序昆), et al. Chinese J. Struct. Chem.(结构化学), 1993,12:229-232
19. [19]
  [19] Williams N A, Uchimaru Y, Tanaka M J. J. Chem. Soc. Chem. Commun., 1995,2010:1129-1130
20. [20]
  [20] Alphonse F A, Yudin A K. J. Am. Chem. Soc., 2006,128: 11754-11755
21. [21]
  [21] Mills O S, Nice N P. J. Organomet. Chem., 1967,9:339- 344
22. [22]
  [22] Chen D F, Xu S S, Song H B, et al. Eur. J. Inorg. Chem., 2008:1854-1864
23. [23]
  [23] MA Zhi-Hong(马志宏), ZHAO Ming-Xia(赵明霞), LIN Li- Zhi(林丽枝), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26:1121-1124
24. [24]
  [24] Schumann H, Stenz S, Girgsdies F, et al. Z. Naturforsch., 2002,57b:1017-1026
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
3. [3]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
4. [4]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
5. [5]
  Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
6. [6]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
7. [7]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
8. [8]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
9. [9]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
10. [10]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
11. [11]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
14. [14]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
15. [15]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
16. [16]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
17. [17]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
18. [18]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
19. [19]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
20. [20]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(415)
HTML views(79)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142