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Citation: CHEN Yan-Min, XIE Qing-Fan, LIU Jin-Hua, HE Xue-Qian, ZHANG Qiong-Ru. Syntheses, Crystal Structures and Properties of Nickel(Ⅱ) and Copper(Ⅱ) Complexes with2-Acetylpyridine Isonicotinoyl Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 74-80. doi: 10.11862/CJIC.2015.033 shu

Syntheses, Crystal Structures and Properties of Nickel(Ⅱ) and Copper(Ⅱ) Complexes with2-Acetylpyridine Isonicotinoyl Hydrazone Schiff Base

  • 1.

    College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China

  • Corresponding author: XIE Qing-Fan, 
  • Received Date: 27 June 2014
    Available Online: 22 September 2014

    Fund Project: 泉州师范学院学科建设资金和国家级大学生创新创业训练计划项目(201310399018)资助 (201310399018)

  • The nickel(Ⅱ) and copper(Ⅱ) complexes [NiL2] (1) and [Cu(Ac)L] (2) were synthesized by reaction of 2-acetylpyridine isonicotinoyl hydrazone Schiff base(HL) with metal acetate, and characterized by elemental analysis, IR, UV-Vis, FLspectra, TGA and X-ray crystal diffraction. The crystal of 1 belongs to the orthorhombic system,space group Aba2 with cell parameters a=1.2059 (3) nm, b=2.0741(5) nm, c=0.9115 (2) nm, V=2.2798 (10) nm3, Z=4, Mr=537.21, Dc=1.565 g·cm-3, F(000)=1113 and the crystal of 2 belongs to the monoclinic system,space group P21/c with cell parameters a=0.86477(13) nm, b=1.3383(2) nm, c=1.3631(2) nm, β=105.650 (4)°, V=1.5190(4) nm3, Z=4, Mr=361.85, Dc=1.582 g·cm-3, F(000)=740. The tests showed the two complexes displayed good thermal stability below 340 ℃(1)和296 ℃(2), respectively. The complexes exhibits blue luminescence with emission maximum at 430 and 428 nm at room temperature, respectively. CCDC: 952992, 1; 993273, 2.
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