Citation: ZHANG Qi-Long, WANG Huan-Yu, HU Peng, ZHU Bi-Xue. Synthesis, Crystal Structures, and Fluorescent Properties of Ag(I) Complex Containing 1,3-Bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 353-360. doi: 10.11862/CJIC.2015.030 shu

Synthesis, Crystal Structures, and Fluorescent Properties of Ag(I) Complex Containing 1,3-Bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol Ligand

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1. Department of Chemistry, Guiyang Medical College, Guiyang 550004, China;
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2. Key laboratory of Macrocycle and Supramolecular Chemistry, Guiyang 550025, China

Corresponding author: ZHANG Qi-Long,
Received Date: 1 August 2014
Available Online: 17 September 2014
Fund Project: 国家自然科学基金(No.21061003)资助项目 (No.21061003)

1,3-bis(2-formylphenoxy)-2-propanol underwent an ammonium acetate-catalyzed condensation reaction with dicyanomethane to afford the ligand 1,3-bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol (L). Further, the ligand Lwas made to react with hexafluoroantimonate(AgSbF₆) which resulted in the formation of coordination polymer [AgLSbF₆]_n·nCHCl3 (1). Complex 1 so-obtained was characterized by Fourier transform infrared spectroscopy, elemental analysis, and single crystal X-ray diffraction. The results of X-ray crystallographic analysis indicated that the ligand L crystallized in the monoclinic system, space group P2₁/n, with the following crystal cell parameters: a=0.9902(11) nm, b=2.181(2) nm, c=1.0122(11) nm, β=109.374(10)°, V=2.062(4) nm³, Z=4, D_c=1.277 g·cm^-3, M_r=396.40, μ=0.087 mm^-1, F(000)=824, R₁=0.0642, and wR₂=0.1174 (observed reflections with I >2σ(I)). Complex 1 crystallized in the monoclinic system, space group P2₁/n, with the following crystallographic data: a=1.27057(11) nm, b=1.45644(13) nm, c=1.66985(14) nm, β=105.643(3)°, V=2.9756(4) nm 3, Z=4, D_c=1.918 g·cm^-3, M_r=859.39, μ=1.907 mm^-1, F(000)=1664, R₁=0.0417, and wR₂=0.1032 (observed reflections with I >2σ(I)). In the crystal structure, each ligand L acted as a tetradentate ligand coordinating four Ag(Ⅰ) centers, and each Ag(Ⅰ) was connected to four ligands L, forming two-dimensional layered structure. Moreover, the fluorescent properties of ligand L and complex 1 were investigated in the solid state at room temperature. CCDC:1008802, L; 1008804, 1.
- 3-bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol;crystal structure;Silver(Ⅰ) Complex;Fluorescent property
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