Citation: ZHANG Qi-Long, WANG Huan-Yu, HU Peng, ZHU Bi-Xue. Synthesis, Crystal Structures, and Fluorescent Properties of Ag(I) Complex Containing 1,3-Bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 353-360. doi: 10.11862/CJIC.2015.030 shu

Synthesis, Crystal Structures, and Fluorescent Properties of Ag(I) Complex Containing 1,3-Bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol Ligand

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1. Department of Chemistry, Guiyang Medical College, Guiyang 550004, China;
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2. Key laboratory of Macrocycle and Supramolecular Chemistry, Guiyang 550025, China

Corresponding author: ZHANG Qi-Long,
Received Date: 1 August 2014
Available Online: 17 September 2014
Fund Project: 国家自然科学基金(No.21061003)资助项目 (No.21061003)

1,3-bis(2-formylphenoxy)-2-propanol underwent an ammonium acetate-catalyzed condensation reaction with dicyanomethane to afford the ligand 1,3-bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol (L). Further, the ligand Lwas made to react with hexafluoroantimonate(AgSbF₆) which resulted in the formation of coordination polymer [AgLSbF₆]_n·nCHCl3 (1). Complex 1 so-obtained was characterized by Fourier transform infrared spectroscopy, elemental analysis, and single crystal X-ray diffraction. The results of X-ray crystallographic analysis indicated that the ligand L crystallized in the monoclinic system, space group P2₁/n, with the following crystal cell parameters: a=0.9902(11) nm, b=2.181(2) nm, c=1.0122(11) nm, β=109.374(10)°, V=2.062(4) nm³, Z=4, D_c=1.277 g·cm^-3, M_r=396.40, μ=0.087 mm^-1, F(000)=824, R₁=0.0642, and wR₂=0.1174 (observed reflections with I >2σ(I)). Complex 1 crystallized in the monoclinic system, space group P2₁/n, with the following crystallographic data: a=1.27057(11) nm, b=1.45644(13) nm, c=1.66985(14) nm, β=105.643(3)°, V=2.9756(4) nm 3, Z=4, D_c=1.918 g·cm^-3, M_r=859.39, μ=1.907 mm^-1, F(000)=1664, R₁=0.0417, and wR₂=0.1032 (observed reflections with I >2σ(I)). In the crystal structure, each ligand L acted as a tetradentate ligand coordinating four Ag(Ⅰ) centers, and each Ag(Ⅰ) was connected to four ligands L, forming two-dimensional layered structure. Moreover, the fluorescent properties of ligand L and complex 1 were investigated in the solid state at room temperature. CCDC:1008802, L; 1008804, 1.
- 3-bis(2-(2,2-dicyanovinyl)phenoxy)-2-propanol;crystal structure;Silver(Ⅰ) Complex;Fluorescent property
1. [1]
  [1] CHENG Xiao-Ning(程小宁), ZHANG Wei-Xiong(张伟雄), XUE Wei(薛玮), et al. Chinese. J. Inorg. Chem. (无机化学学报), 2014,30(1):142-148
2. [2]
  [2] Chen X Y , Huang R B, Zheng L S, et al. Inorg. Chem., 2014,53:5246-5252
3. [3]
  [3] Manus L M, Holbrook R J, Atesin T A, et al. Inorg. Chem., 2013,52:1069-1076
4. [4]
  [4] ZHANG Chun-Li(张春丽), QIN Ling(覃玲), ZHENG He-Gen (郑和根). Chinese J. Inorg. Chem. (无机化学学报), 2014,30 (4):800-804
5. [5]
  [5] Halper S R, Do L, Stork J R, et al. J. Am. Chem. Soc., 2006,128:15255-15268
6. [6]
  [6] Fan L M, Zhang X T, Sun Z, et al. Cryst. Growth Des., 2013,13,2462-2475
7. [7]
  [7] Zhou X, Lu Y, Zhai L L, et al. RSC Adv., 2013,3:1732-1734
8. [8]
  [8] ZHANG Qi-Long(张奇龙), ZHANG Yun-Qian(张云黔), ZHU Bi-Xue(朱必学). Chinese J. Inorg. Chem. (无机化学学报), 2011,27(11):2191-2194
9. [9]
  [9] Omary M A, Elbjeirami O, Gamage C S, et al. Inorg. Chem., 2009,48:1784-1786
10. [10]
  [10] Hu X H, Liang Y, Li C, et al. Dalton Trans., 2014,43:2458-2464
11. [11]
  [11] Zhang Q L, Zhu B X, Zhang Y Q, et al. Cryst. Growth Des., 2011,11:5688-5695
12. [12]
  [12] Liu S J, Huang Y B, Lin Z J, et al. RSC Adv., 2013,3:9279-9287
13. [13]
  [13] Ma L F, Wang L Y, Du M, et al. Inorg. Chem., 2010,49: 365-367
14. [14]
  [14] Yang Y, Yang J, Du P, et al. CrystEngComm, 2014,16: 6380-6390
15. [15]
  [15] Wang X L, Sui F F, Lin H Y, et al. CrystEngComm, 2013,15:7274-7284
16. [16]
  [16] Dong Y B, Jiang Y Y, Li J, et al. J. Am. Chem. Soc., 2007,129:4520-4521
17. [17]
  [17] ZHAO Bin(赵斌), XIA Min(夏闽), WANG Xue-Zhi(王学之), et al. Chinese J. Chemical Reagents (化学试剂), 2000,22: 224-227
18. [18]
  [18] Sheldrick G M. Acta Crystallogr., 1990,A46,467
19. [19]
  [19] Sheldrick G M. SHELX-97, University of Göttingen, Germany, 1997.
20. [20]
  [20] Zhang X T, Fan L M, Sun Z, et al. CrystEngComm, 2013,15:4910-4916
21. [21]
  [21] Liu F J, Sun D, Hao H J, et al. Cryst. Growth Des., 2012,12:354-361
22. [22]
  [22] Zheng S L, Zhang J P, Chen X M, et al. J. Solid State Chem., 2003,172:45-52
23. [23]
  [23] Yi L, Zhu L N, Ding B, et al. Inorg. Chem. Commun., 2003,6:1209-1212
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