Citation: FEI Bao-Li, WANG Ping-Ping, WANG Hao-Rong, YAN Qing-Ling, LI Yang-Guang. 1D Chains of Copper(Ⅱ) Schiff Base Complexes as Efficient Photo-Fenton-Like Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 399-404. doi: 10.11862/CJIC.2015.028 shu

1D Chains of Copper(Ⅱ) Schiff Base Complexes as Efficient Photo-Fenton-Like Catalysts

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1. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China;
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2. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, China;
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3. Institute Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: FEI Bao-Li,
Received Date: 19 September 2014
Available Online: 17 October 2014
Fund Project: 江苏省普通高校研究生科研创新计划(No.CXLX13_517) (No.CXLX13_517)江苏省高校自然科学研究面上项目(No.13KJB220006) (No.13KJB220006)南京林业大学引进高层次留学回国人员科研基金项目,南京大学配位化学重点实验室开放基金项目和江苏省高校优势学科建设工程资助项目(PAPD)资助 (PAPD)

Two copper(Ⅱ) Schiff base complexes [Cu(HL¹)ClO₄]_n (1) and [Cu(HL²)NO₃]_n (2) (H₂L¹=N-[(2-oxy-acetate)benzyl]-2-amino ethanol, H₂L²=N-salicylidene-3-amino propanol) have been synthesized and explored as photo-Fenton-like catalysts for the degradation of methyl orange (MO) without acidification process. 1 and 2 show 1Dchain motifs and each copper(Ⅱ) ion is six-coordinated in elongated octahedral environment. They are the first 1Dchains of copper(Ⅱ) Schiff base complexes with excellent photocatalytic performance. 1 has advantages on catalyzing efficient MOdegradation through homogeneous photo-Fenton-like reaction. The results indicate that the coordinated ligands have some effect on the photocatalytic activity of copper(Ⅱ) complexes in this study. CCDC: 996021, 1; 996020, 2.
- schiff base;copper(Ⅱ) complex;photo-fenton-like;methyl orange
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