Citation: FEI Bao-Li, WANG Ping-Ping, WANG Hao-Rong, YAN Qing-Ling, LI Yang-Guang. 1D Chains of Copper(Ⅱ) Schiff Base Complexes as Efficient Photo-Fenton-Like Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 399-404. doi: 10.11862/CJIC.2015.028 shu

1D Chains of Copper(Ⅱ) Schiff Base Complexes as Efficient Photo-Fenton-Like Catalysts

  • Corresponding author: FEI Bao-Li, 
  • Received Date: 19 September 2014
    Available Online: 17 October 2014

    Fund Project: 江苏省普通高校研究生科研创新计划(No.CXLX13_517) (No.CXLX13_517)江苏省高校自然科学研究面上项目(No.13KJB220006) (No.13KJB220006)南京林业大学引进高层次留学回国人员科研基金项目,南京大学配位化学重点实验室开放基金项目和江苏省高校优势学科建设工程资助项目(PAPD)资助 (PAPD)

  • Two copper(Ⅱ) Schiff base complexes [Cu(HL1)ClO4]n (1) and [Cu(HL2)NO3]n (2) (H2L1=N-[(2-oxy-acetate)benzyl]-2-amino ethanol, H2L2=N-salicylidene-3-amino propanol) have been synthesized and explored as photo-Fenton-like catalysts for the degradation of methyl orange (MO) without acidification process. 1 and 2 show 1Dchain motifs and each copper(Ⅱ) ion is six-coordinated in elongated octahedral environment. They are the first 1Dchains of copper(Ⅱ) Schiff base complexes with excellent photocatalytic performance. 1 has advantages on catalyzing efficient MOdegradation through homogeneous photo-Fenton-like reaction. The results indicate that the coordinated ligands have some effect on the photocatalytic activity of copper(Ⅱ) complexes in this study. CCDC: 996021, 1; 996020, 2.
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    1. [1]

      [1] Banerjee S, Adhikary C, Rizzoli C, et al. Inorg. Chim. Acta, 2014,409:202-207

    2. [2]

      [2] Omer M A S, Liu J C, Deng W T, et al. Polyhedron, 2014, 69:10-14

    3. [3]

      [3] El-sharkawy R G, El-din A S B, Etaiw S E H. Spectrochim. Acta A, 2011,79:1969-1975

    4. [4]

      [4] Núñez L, García-Hortal J A, Torrades F. Dyes Pigm., 2007, 75:647-652

    5. [5]

      [5] Wang W, Qu Y, Yang B, Liu X, et al. Chemosphere, 2012,86:376-382

    6. [6]

      [6] Ntampegliotis K, Riga A, Karayannis V, et al. J. Hazard. Mater., 2006,136:75-84

    7. [7]

      [7] Lam F L Y, Yip A C K, Hu X. Ind. Eng. Chem. Res., 2007,46:3328-3333

    8. [8]

      [8] Guo S, Zhang G, Guo Y, et al. Carbon, 2013,60:437-444

    9. [9]

      [9] Verma P, Shah V, Baldrian P, et al. Chemosphere, 2004,54: 291-295

    10. [10]

      [10] Emmons D W. Organic Synthesis: Vol.46. New York: John Wiley and Sons Inc., 1996:28-29

    11. [11]

      [11] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.

    12. [12]

      [12] Lin T Y, Wu C H. J. Catal., 2005,232:117-126

    13. [13]

      [13] Nguyen T D, Phan N H, Do M H, et al. J. Hazard. Mater., 2011,185:653-661

    14. [14]

      [14] Zugle R, Nyokong T. J. Mol. Catal. A: Chem., 2013,366: 247-253

    15. [15]

      [15] Lu X, Ma H, Zhang Q, et al. Res. Chem. Intermed., 2013,39:4189-4203

  • 加载中
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