Citation: CHEN Shui-Sheng, LÜ Dan-Long, QIAO Rui, ZHU Juan-Juan, SHENG Liang-Quan. Syntheses, Structures and Properties of Two Supramolecular Polymers Constructed from 4Imidazole Carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 420-428. doi: 10.11862/CJIC.2015.025 shu

Syntheses, Structures and Properties of Two Supramolecular Polymers Constructed from 4Imidazole Carboxylate Ligand

1.
1. College of Chemistry & Chemical Engineering, Fuyang Normal College, Fuyang, Anhui 236041, China;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: CHEN Shui-Sheng,
Received Date: 7 October 2014
Available Online: 14 October 2014
Fund Project: 国家自然科学基金(No.21171040,21302019) (No.21171040,21302019)南京大学配位化学重点实验室开放基金、国家大学生创新项目(No.201310371004) (No.201310371004)有机教研项目(No.2013JCJS01)资助项目 (No.2013JCJS01)

Two complexes, [Cd(L₁)(HL₁)I] (1, HL₁=4-(1H-imidazol-4-yl)benzoic acid) and [Co₂(L₁)₄(H₂O)₈] (2), have been hydrothermally prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IRspectroscopy, photoluminescence property, TGand PXRD. Complex 1 crystallizes in monoclinic, space group P2₁/c. The L¹-ligands link Cd(Ⅱ) atoms to form one-dimensional chains, which are further bridged to form a three-dimensional three-fold interpenetrating α-Po supramolecular polymer by hydrogen bonds. X-ray diffraction analysis revealed three different kinds of Co(Ⅱ) centre mononuclear molecules in the asymmetric unit. The independent mononuclear units are bridged to form a three-dimensional supramolecular polymer by extensive hydrogen bonds interactions. Solid state luminescent property of 1 and sorption property of 2 have been investigated. CCDC: 983657, 1; 1027672, 2.
- synthesis;supramolecular polymer;photoluminescence property;sorption property
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沈阳化工大学材料科学与工程学院沈阳 110142