Citation: CHEN Shui-Sheng, LÜ Dan-Long, QIAO Rui, ZHU Juan-Juan, SHENG Liang-Quan. Syntheses, Structures and Properties of Two Supramolecular Polymers Constructed from 4Imidazole Carboxylate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 420-428. doi: 10.11862/CJIC.2015.025 shu

Syntheses, Structures and Properties of Two Supramolecular Polymers Constructed from 4Imidazole Carboxylate Ligand

1.
1. College of Chemistry & Chemical Engineering, Fuyang Normal College, Fuyang, Anhui 236041, China;
2.
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: CHEN Shui-Sheng,
Received Date: 7 October 2014
Available Online: 14 October 2014
Fund Project: 国家自然科学基金(No.21171040,21302019) (No.21171040,21302019)南京大学配位化学重点实验室开放基金、国家大学生创新项目(No.201310371004) (No.201310371004)有机教研项目(No.2013JCJS01)资助项目 (No.2013JCJS01)

Two complexes, [Cd(L₁)(HL₁)I] (1, HL₁=4-(1H-imidazol-4-yl)benzoic acid) and [Co₂(L₁)₄(H₂O)₈] (2), have been hydrothermally prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IRspectroscopy, photoluminescence property, TGand PXRD. Complex 1 crystallizes in monoclinic, space group P2₁/c. The L¹-ligands link Cd(Ⅱ) atoms to form one-dimensional chains, which are further bridged to form a three-dimensional three-fold interpenetrating α-Po supramolecular polymer by hydrogen bonds. X-ray diffraction analysis revealed three different kinds of Co(Ⅱ) centre mononuclear molecules in the asymmetric unit. The independent mononuclear units are bridged to form a three-dimensional supramolecular polymer by extensive hydrogen bonds interactions. Solid state luminescent property of 1 and sorption property of 2 have been investigated. CCDC: 983657, 1; 1027672, 2.
- synthesis;supramolecular polymer;photoluminescence property;sorption property
1. [1]
  [1] Chen S S, Liu Q, Zhao Y, et al. Cryst. Growth Des., 2014, 14:3727-3741
2. [2]
  [2] MA Zhi-Feng(马志峰), ZHANG Ying-Hui(章应辉), HU Tong-Liang(胡同亮), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014,30(1):204-212
3. [3]
  [3] ZHAO Yue(赵越), ZHAI Ling-Ling(翟玲玲), SUN Wei-Yin (孙为银). Chinese J. Inorg. Chem.(无机化学学报), 2014,30 (1):99-105
4. [4]
  [4] BAI Zheng-Shuai(白正帅), CHEN Shui-Sheng(陈水生), ZHANG Zheng-Hua(张正华), et al. Sci. China Ser. B Chem. (中国科学:化学), 2009,52(4):459-464
5. [5]
  [5] Su Z, Chen M, Okamura T, et al. Inorg. Chem., 2011,50:985-991
6. [6]
  [6] Chen M, Chen S S, Okamura T, et al. Cryst. Growth Des., 2011,11:1901-1912
7. [7]
  [7] CHEN Shui-Sheng(陈水生), ZHANG Shu-Ping(张淑萍), YANG Song(杨松), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(6):1000-1004
8. [8]
  [8] HU Chun-Yan(胡春燕), XIAO Wei(肖伟), TAO Bai-Long(陶白龙), et al. Chinese J. Inorg. Chem.(无机化学学报), 2014, 30(2):257-263
9. [9]
  [9] Wang L C, Sun J L, Huang Z T, et al. Cryst. Growth Des., 2013,13:1-5
10. [10]
  [10] Chen S S, Zhao Y, Fan J, et al. CrystEngComm, 2012,14: 3564-3576
11. [11]
  [11] Chen S S, Chen M, Takamizawa S, et al. Chem. Commun., 2011,47:752-754
12. [12]
  [12] Bruker 2000, SMART Version 5.0, SAINT-plus Version 6, SHELXTL Version 6.1, SADABS Version 2.03. Bruker AXS Inc.: Madison, WI, 2000.
13. [13]
  [13] Du M, Li C. P, Zhao X. J, et al. CrystEngComm, 2007,9: 1011-1028
14. [14]
  [14] Chen S S, Fan J, Okamura T. A, et al. Cryst. Growth Des., 2010,10:812-822
15. [15]
  [15] Ma T, Li M X, Wang Z X, et al. Cryst. Growth Des., 2014, 14:4155-4165
16. [16]
  [16] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordinated Compounds, 5th Ed. New York: Wiley & Sons, 1997.
17. [17]
  [17] Chen S S, Qiao R, Sheng L Q, et al. Z. Anorg. Allg. Chem., 2013,639:1808-1814
18. [18]
  [18] Lu J, Li Y, Zhao K, et al. Inorg. Chem. Commun., 2004,7: 1154-1156
19. [19]
  [19] Wang X, Qin C, Wang E, et al. Inorg. Chem., 2004,43:1850-1856
20. [20]
  [20] Lyons E M, Braverman M A, Supkowski R M, et al. Inorg. Chem. Commun., 2008,11:855-858
21. [21]
  [21] Wu G, Wang X F, Okamura T A, et al. Inorg. Chem., 2006, 45:8523-8532
22. [22]
  [22] Luo L, Wang P, Xu G C, et al. Cryst. Growth Des., 2012,12: 2634-2645
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
6. [6]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
7. [7]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
8. [8]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
9. [9]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
10. [10]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
11. [11]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
12. [12]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
13. [13]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
14. [14]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
15. [15]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
16. [16]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
17. [17]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
18. [18]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(125)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142