Citation: WANG Yan-En, CAO Shuang, LIU Shu-Jing, FENG Tao, LIU Ning, TANG Ya-Wen, LU Tian-Hong. Carbon Supported Alloy Pd-Fe Catalyst: Preperation and Electrocatalytic Activity for Oxygen Reduction[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 23-28. doi: 10.11862/CJIC.2015.024 shu

Carbon Supported Alloy Pd-Fe Catalyst: Preperation and Electrocatalytic Activity for Oxygen Reduction

1.
1. Department of Morden Science & Technology, College of Science, Agricultural University of Hebei, Baoding, Hebei 071000, China;
2.
2. School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, China

Corresponding author: CAO Shuang,
Received Date: 12 May 2014
Available Online: 17 October 2014
Fund Project: 国家自然科学基金项目(No.21073094,21273116,61171015) (No.21073094,21273116,61171015)江苏高校优势学科建设工程(No.10KJB150007)资助项目 (No.10KJB150007)

The Pd-Fe/C catalyst was prepared by the complexing reduction method using NH₄Cl as the complex agent at the low temperature. The high alloy Pd-Fe/C catalyst Pd and Fe could be prepared at low temperature due to the complex formation by NH₄Cl and Pd, which leads to a negative shift for the reduction potential of PdCl₂, making the reduction potential of PdCl₂ closer to that of FeCl₃. The XPS results show that the alloying of Pd with Fe could affect the binding energies of Pd and increase the content of Pd⁰ in the catalyst. Thus, the electrocatalytic activity of the Pd-Fe/C catalyst obtained for the oxygen reduction is higher than that of the Pd/C catalyst prepared with the same method. Furthermore, this Pd-Fe/C catalyst has no electrocatalytic activity for the methanol oxidation.
- catalyst;complexing reduction method;Pd-Fe/C catalyst;reduction potential;high alloy;oxygen reduction
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