Citation: ZHU Jie, GE Feng-Juan. CuO/CeO₂/γ-Al₂O₃ Catalysts: Effect of Pretreating Atmosphere on Surface Properties and Catalytic Performance in Selective Catalytic Reduction of NO with CO[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 191-197. doi: 10.11862/CJIC.2015.021 shu

CuO/CeO₂/γ-Al₂O₃ Catalysts: Effect of Pretreating Atmosphere on Surface Properties and Catalytic Performance in Selective Catalytic Reduction of NO with CO

ZHU Jie ^, ,
GE Feng-Juan

1.
School of Chemistry and Chemical Engineering, Xuzhou Institute of Technology, Xuzhou, Jiangsu 221111, China

Corresponding author: ZHU Jie,
Received Date: 3 July 2014
Available Online: 15 October 2014
Fund Project: 江苏省高校自然科学基金(No.12KJD530002)资助项目. (No.12KJD530002)

The CeO₂/γ-Al₂O₃ supports were prepared and pretreated in different atmospheres to adjust the valence state of surface Ce element, then Cu(CH₃COO)₂ was impregnated as the precursor to prepare CuCeAl samples. XRD and H₂-TPR results indicate that the CeO₂/γ-Al₂O₃ support pretreated by reducing atmosphere has more active oxygen atoms, consequently has more dispersed Cu²⁺/Cu⁺ species on the surface. The "NO+CO" reaction tests reveal that the dispersed Cu²⁺/Cu⁺ are the active species for NO conversion, while crystalline Cu⁰ promotes the N₂ selectivity at low temperatures. Hence, the catalysts containing both dispersed Cu²⁺/Cu⁺ and a few crystalline Cu⁰ have the optimal catalytic efficiency.
- heterogeneous catalysis;nitrogen oxides;waste prevention;pretreating atmosphere;CeO₂/γ-Al₂O₃;"NO+CO" reaction
1. [1]
  [1] Schneider H, Scharf U, Baiker A, et al. J. Catal., 1994,146: 545-556
2. [2]
  [2] Parvulescu V, Grange P, Delmon B. Catal. Today, 1998,46: 233-316
3. [3]
  [3] Guimaraes A, Dieguez L, Schmal M. J. Phys. Chem. B, 2003,107:4311-4319
4. [4]
  [4] Shan W J, Shen W J, Li C. Chem. Mater., 2003,15:4761- 4767
5. [5]
  [5] Zhu H Y, Shen M M, Gao F, et al. Catal. Commun., 2004,5: 453-456
6. [6]
  [6] Hennings U, Reimert R. Appl. Catal. A: Gen., 2007,325:41 -49
7. [7]
  [7] Bernal S, Blanco G, Pintado J, et al. Catal. Commun., 2005,6:582-585
8. [8]
  [8] Liang Q, Wu X D, Weng D, et al. Catal. Commun., 2008,9: 202-206
9. [9]
  [9] Qi G, Yang R T. J. Catal., 2003,217:434-441
10. [10]
  [10] Dyakonov A J, Little C A. Appl. Catal. B: Environ., 2006,67:52-59
11. [11]
  [11] He H, Dai H X, Wong K W. Appl. Catal. A: Gen., 2003, 251:61-74
12. [12]
  [12] Hu Y, Dong L, Wang J, et al. J. Mol. Catal. A, 2000,162: 307-316
13. [13]
  [13] Stranick M A, Houalla M, Hercules D M. J. Catal., 1987,106:362-368
14. [14]
  [14] Chen Y, Dong L, Jin Y S, et al. Stud. Surf. Sci. Catal., 1996,101:1293-1302
15. [15]
  [15] Xia W S, Wan H L, Chen Y. J. Mol. Catal. A: Chem., 1999,138:185-195
16. [16]
  [16] Schuit G A, Gates B C. AIChE J., 1973,19:417-438
17. [17]
  [17] Chen Y, Zhang L F. Catal. Lett., 1992,12:51-62
18. [18]
  [18] Jimenez-Gonzalez J, Schmeisser D. Surf. Sci., 1991,250:59- 70
19. [19]
  [19] Trovarelli A. Catalysis by Ceria and Related Materials. Singapore: World Scientific, 2013.
20. [20]
  [20] Zou H B, Dong X F, Lin W M. Appl. Surf. Sci., 2006,253: 2893-2898
21. [21]
  [21] Li Y, Zhang B C, Tang X L, et al. Catal. Commun., 2006,7: 380-386
22. [22]
  [22] Zhu Jie, Gao Fei, Dong Li-Hui, et al. Appl. Catal. B: Environ., 2010,95:144-152
23. [23]
  [23] Sagar G V, Rao P V R, Srikanth C S, et al. J. Phys. Chem. B, 2006,110:13881-13888
1. [1]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
4. [4]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
5. [5]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Yulong Shi , Fenbei Chen , Mengyuan Wu , Xin Zhang , Runze Meng , Kun Wang , Yan Wang , Yuheng Mei , Qionglu Duan , Yinghong Li , Rongmei Gao , Yuhuan Li , Hongbin Deng , Jiandong Jiang , Yanxiang Wang , Danqing Song . Chemical construction and anti-HCoV-OC43 evaluation of novel 10,12-disubstituted aloperine derivatives as dual cofactor inhibitors of TMPRSS2 and SR-B1. Chinese Chemical Letters, 2024, 35(5): 108792-. doi: 10.1016/j.cclet.2023.108792
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
13. [13]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
14. [14]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
15. [15]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
16. [16]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
17. [17]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
18. [18]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
19. [19]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(168)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

CuO/CeO2/γ-Al2O3 Catalysts: Effect of Pretreating Atmosphere on Surface Properties and Catalytic Performance in Selective Catalytic Reduction of NO with CO

Metrics

通讯作者: 陈斌, bchen63@163.com

CuO/CeO₂/γ-Al₂O₃ Catalysts: Effect of Pretreating Atmosphere on Surface Properties and Catalytic Performance in Selective Catalytic Reduction of NO with CO