Citation: DENG Bing-Xin, ZHANG Bo, JIANG Jian-Feng. Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 153-158. doi: 10.11862/CJIC.2015.014 shu

Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction

1.
Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: ZHANG Bo,
Received Date: 5 July 2014
Available Online: 13 October 2014

5%ZrO₂/MCM-41 and 5%ZrO₂-5%M₂O₃/MCM-41(M=La,Ce,Sm,Gd)were prepared by the impregnation method. The hydrogen transfer reduction of acetophenone with 2-propanol was investigated over these catalysts. The catalysts were characterized with XRD, N₂ adsorption-desorption and FTIR spectra of adsorbed pyridine. The results show that ZrO₂ and rare-earth metal oxides disperse on the surface of MCM-41 supports in an amorphous phase or as tiny crystal particles lower than the detection limit of XRD. The catalytic activity obviously varies upon loading rare-earth metal oxides on₅%ZrO₂-MCM-41, The activities of the catalysts decrease in the order of 5%ZrO₂-5%La₂O₃/MCM-41 > 5%ZrO₂-5%Sm₂O₃/MCM-41 > 5%ZrO₂-5%Gd₂O₃/MCM-41 > 5%ZrO₂/MCM-41 > 5%ZrO₂-5%Ce₂O₃/MCM-41. Addition of rare-earth metal oxides leads to strengthening the acidity of Zr-OH, Lewis acid sites and Brönsted acid sites on the catalyst surface. On the other hand, the addition of La₂O₃ can obviously enhance the number of acid sites on the catalyst surface. On the contrary, the loading of Sm₂O₃、Gd₂O₃ results in the slight decrease in the number of acid sites on the catalyst surface, especially, the addition of Ce₂O₃ leads to a significant drop in the number of acid sites.
- zirconia;MCM-41 mesoporous molecular sieve;rare-earth metal oxides;acetophenone;hydrogen transfer reaction
1. [1]
  [1] Arai M, Takahashi H, Shirai M, et al. Appl. Catal. A, 1999, 176:229-236
2. [2]
  [2] Sudhindra N M , Ram S S, Minaz A G, et al. J. Colloid Interface Sci., 2005,281(1):164-170
3. [3]
  [3] Uysal B, Buyuktas B S. Arkivoc, 2007,14:134-140
4. [4]
  [4] Corma A, Domine M E, Nemeth L, et al. J. Am. Chem. Soc., 2002.124(13):3194-3195
5. [5]
  [5] Akata B, Warzywoda J, Albert S J. J. Catal., 2004.222(2): 397-403
6. [6]
  [6] Zhu Y Z, Liu S H, Janenicke S. J. Catal., 2004,227(1):1- 10
7. [7]
  [7] LIU Jian-Hong(刘建红), XIA Feng(夏峰), FAN Bin-Bin (范彬彬), et al. Chinese J. Inorg. Chem.(无机化学学报), 2009,25(6):980-985
8. [8]
  [8] Samuel P P, Shylesh S, Singh A P. J. Mol. Catal. A: Chem., 2007,266(1/2):11-20
9. [9]
  [9] JIN Bin(金滨), ZHANG Bo(张波), LI Xiu-Juan(李秀娟), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2008, 22(2):270-276
10. [10]
  [10] ZHANG Bo(张波), TANG Min-Hui(汤明慧), YUAN Jian (袁剑), et al. Chin. J. Catal.(催化学报), 2012,33:914-922
11. [11]
  [11] Zhu Y Z, Liu S H, Jaenicke S, et al. Catal. Today, 2004,97 (4):249-255
12. [12]
  [12] XU Chun-Lei(徐春雷), ZHANG Bo(张波) ,YUAN Jian (袁剑), et al. Acta Chim. Sinica(化学学报), 2011,69(4):368 -374
13. [13]
  [13] Aramendia M A, Borau V, Jimenez C, et al. J. Catal., 1999, 183(1):119-127
14. [14]
  [14] YUAN Jian(袁剑), ZHANG Bo(张波), TANG Ming-Hui (汤明慧), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2013,27(5):818-824
15. [15]
  [15] YUAN Jian(袁剑), ZHANG Bo(张波), TANG Ming-Hui (汤明慧), et al. Chem. J. Chinese Universities(高等学校化学学报), 2012,33(6):1326-1332
16. [16]
  [16] ZHANG Bo(张波), SHEN Lian(慎炼), ZHOU Chun-Hui (周春晖), et al. J. Chem. Eng. Chin. Univ.(高校化学工程学报), 2001,15(1):29-35
17. [17]
  [17] Rana S, Mallick S, Rath D, et al. J. Chem. Sci., 2012,124 (5):1117-1125
18. [18]
  [18] Gregori M, Benito P, Fornasari G, et al. Microporous Mesoporous Mater., 2014,190:1-9
19. [19]
  [19] Saraiva M S, Fernandes C I, Nunes T G, et al. J. Organomet. Chem., 2014,751:443-452
20. [20]
  [20] Mekhemer G A H. Phys. Chem. Chem. Phys., 2002,4:5400 -5405
21. [21]
  [21] Damyanova S, Petrov L, Centeno M A, et al. Appl. Catal. A: Gen., 2002,224(1/2):271-284
22. [22]
  [22] Zhang B, Shi N F, Xu C L, et al. J. Fluorine Chem., 2010, 131(5):554-560
23. [23]
  [23] Marques J P, Gener I, Ayrault P, et al. Microporous Mesoporous Mater., 2003,60:251-262
24. [24]
  [24] Martins A, Silva J M, Henriques C, et al. Catal. Today, 2005,107-108:663-670
25. [25]
  [25] Chuah G K, Jaenicke S, Zhu Y Z, et al. Curr. Org. Chem., 2006,10(13):1639-1654
26. [26]
  [26] Zhu Y Z, Jaenicke S, Chuah G K. J. Catal., 2003,218(2):396 -404
27. [27]
  [27] Warner B P, D'Alessio J A, Morgan A N, et al. Inorg. Chim. Acta, 2000,309(1):45-48
28. [28]
  [28] Axpuac S, Aramendøa M A, Carrillo J H, et al. Catal. Today, 2012,187(1):183-190
29. [29]
  [29] Urbano F J, Aramendia M A, Marinas A, et al. J. Catal., 2009,268(1):79-88
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通讯作者: 陈斌, bchen63@163.com

Effect of Rare Earth Element in ZrO₂-M₂O₃/MCM-41 (M=La, Ce, Sm, Gd) on Hydrogen Transfer Reaction