Citation: CHEN Yao-Yao, SHEN Jun-Hai, KONG Wei-Qiu, LI Liang-Chao. Preparation and Electromagnetic Loss Properties of Nickel-Zinc Ferrite Expanded Graphite Polyaniline Composites[J]. Chinese Journal of Inorganic Chemistry, ;2015, (2): 243-252. doi: 10.11862/CJIC.2015.008 shu

Preparation and Electromagnetic Loss Properties of Nickel-Zinc Ferrite Expanded Graphite Polyaniline Composites

1.
College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: LI Liang-Chao,
Received Date: 10 July 2014
Available Online: 15 October 2014
Fund Project: 国家自然科学基金(No.21071125) (No.21071125)浙江省大学学生科技创新计划(No.2014R404056)资助项目 (No.2014R404056)

Nickel-Zinc Ferrite (Ni_xZn_1-xFe₂O₄), Ni_0.7Zn_0.3Fe₂O₄/expanded graphite binary composites (NZF/EG) and its ternary composites coated by Polyaniline (NZF/EG/PANI) were prepared by co-precipitation methods and in situ polymerization, respectively. The composition, structure, morphology and electromagnetic properties of the as-prepared samples were characterized by the modern testing technologies. The results showed that the NZFparticles had been embed into the interlamination of EG, and NZF/EGparticles had been well coated by PANI. The magnetic properties of ternary composites weaken with the decrease of magnetic component, while its electrical conductivities related to the natural characteristic and relative content of EGand PANI. In addition, it presented the excellent electrical and magnetic loss property, and its loss properties were better than those of binary composites. The minimum reflection loss values (corresponding vailable bandwidth) of the ternary composites with ω_PANIof 70wt% at thicknesses of 1.5, 2.0 and 2.5 mm reached^-19.99 dB (5.82 GHz), -20.33 dB (4.08 GHz) and -25.28 dB (3.67 GHz), respectively, presenting the excellent absorbing effect on electromagnetic wave.
- nickel-zinc ferrite;expanded graphite;polyaniline;composites;electromagnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142