Citation: ZHAO Xin-Hong, WEN Juan-Juan, CHEN Jing, ZHAO Jiang-Bo, QI Yong-Dong, LI Gui-Xian. Ionothermal Synthesis of Hierarchical Structured CuAPO-5 Molecular Sieve[J]. Chinese Journal of Inorganic Chemistry, ;2015, (1): 29-36. doi: 10.11862/CJIC.2015.003 shu

Ionothermal Synthesis of Hierarchical Structured CuAPO-5 Molecular Sieve

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School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China

Corresponding author: ZHAO Xin-Hong,
Received Date: 12 May 2014
Available Online: 6 October 2014
Fund Project: 国家自然科学基金(No.21306072) (No.21306072)红柳青年(No.201113)资助项目 (No.201113)

Hierarchical structured CuAPO-5 molecular sieve has been ionothermally synthesized by microwave irradiation and using eutectic mixture based on succinic acid, choline chloride and tetraethyl ammonium bromide as solvent and template. The effects of the ratio of P₂O₅/Al₂O₃, HF/Al₂O₃ and CuO/Al₂O₃, aluminum and copper sources on the crystallization of CuAPO-5 were systematically investigated. The resulting CuAPO-5 molecular sieve was characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscopy (TEM), and N₂ physical adsorption-desorption, respectively. SEM analysis reveals that CuAPO-5 molecular sieve with hexagonal nanometer-disc morphology can be synthesized under specific synthesis conditions. N₂ physisorption, SEM and TEM characterizations show that the resultant material is one kind of hierarchical structured aluminophosphate molecular sieve possesses both micropore and mesopore.
- ionothermal synthesis;CuAPO-5;hierarchical structured;eutectic mixture
1. [1]
  [1] XU Ru-Ren(徐如人), PANG Wen-Qin(庞文琴), YU Ji-Hong (于吉红), et al. Chemistry-Zeolites and Porous Materials(分子筛与多孔材料化学). Beijing: Science Press, 2004:15-19
2. [2]
  [2] Chen L H, Tang Y, Xiao F S, et al. J. Mater. Chem., 2012, 22:17381-17403
3. [3]
  [3] Hua Z L, Zhou J, Shi J L. Chem. Commun., 2011,47(38): 10536-10547
4. [4]
  [4] Naydenov V, Tosheva L, Antzutkin O N, et al. Microporous Mesoporous Mater., 2005,78(2/3):181-188
5. [5]
  [5] Egeblad K, Kustova M, Klitgaard S K, et al. Microporous Mesoporous Mater., 2007,101(1/2):214-223
6. [6]
  [6] Yang X M, Lu T L, Chen C, et al. Microporous Mesoporous Mater., 2011,144(1/2/3):176-182
7. [7]
  [7] Choi M, Srivastava R, Ryoo R. Chem. Commun., 2006(42): 4380-4382
8. [8]
  [8] Kim J, Bhattacharjee S, Ahn W S, et al. New J. Chem., 2010,34(12):2971-2978
9. [9]
  [9] Danilina N, Krumeich F, van Bokhoven J A. J. Catal., 2010, 272(1):37-43
10. [10]
  [10] Fan Y, Xiao H, Shi G, et al. J. Catal., 2012,285(1):251-259
11. [11]
  [11] Alicia M S, Manuel S S, Pedro M G, et al. Microporous Mesoporous Mater., 2010,131(1/2/3):331-341
12. [12]
  [12] Kanchana U, Sujitra W. Microporous Mesoporous Mater., 2010,135(1/2/3):116-123
13. [13]
  [13] Zhao X H, Chen J, Sun Z P, et al. Microporous Mesoporous Mater., 2013,182:8-15
14. [14]
  [14] Dang T T H, Zubowa H L, Bentrup U, et al. Microporous Mesoporous Mater., 2009,123:209-220
15. [15]
  [15] HE Ye(何月), DONG Mei(董梅), Li Jun-Fen(李俊汾), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2010,26(5):1305-1310
16. [16]
  [16] Wan Y, Williams C D, Duke C V A, et al. J. Mater. Chem., 2000,10:2857-2862
17. [17]
  [17] Zhao X H, Wang H, Li G X, et al. Microporous Mesoporous Mater., 2012,151:56-63
18. [18]
  [18] Wragg D S, Slawin A M Z, Morris R E. Solid State Sci., 2009, 11(2):411-416
19. [19]
  [19] Oliver S, Kuperman A, Ozin G A. Angew. Chem., Int. Ed. Engl., 1998,37(1/2):46-62
20. [20]
  [20] Hentit H, Bachari K, Ouali M S, et al. J. Mol. Catal. A: Chem., 2007,275(1/2):158-166
21. [21]
  [21] Tian D Y, Yan W F, Cao X J, et al. Chem. Mater., 2008,20: 2160-2164
22. [22]
  [22] Tian D Y, Yan W F, Wang Z X, et al. Cryst. Growth Des., 2009,9(3):1411-1414
23. [23]
  [23] Danilina N, Castelanelli S A, Troussard E, et al. Catal. Today, 2011,168(1):80-85
24. [24]
  [24] Murthy K, Kulkarni S J, Masthan S K. Microporous Mesoporous Mater., 2001,43(2):201-209
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沈阳化工大学材料科学与工程学院沈阳 110142