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Citation: WANG Hui-Sheng, PAN Zhi-Quan. Synthesis, Crystal Structure and Magneto-Structural Correlation of a [Mn8Ce] Cluster Substituted by Four Pyrazoles[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1104-1110. doi: 10.11862/CJIC.2014.188 shu

Synthesis, Crystal Structure and Magneto-Structural Correlation of a [Mn8Ce] Cluster Substituted by Four Pyrazoles

  • 1.

    Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430074, China

  • Received Date: 28 November 2013
    Available Online: 27 January 2014

    Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助项目。 (No.10122012)

  • One [Mn8Ce] mixed metal cluster, namely, [Mn8O8Ce(O2CCH3)12(pyr)4]·2CH3OH (2·2CH3OH, pyr=pyrozole) has been obtained by adding (NH4)2Ce(NO3)6 to the acetonitrile/methanol solution containing Mn(O2CCH3)2·4H2O, pyrozole and acetic acid. The complex was fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis and magnetic investigation. The structural analysis indicates that the complex crystallized in the monoclinic system, P21/c space group, and the eight MnⅢ ions formed a nonplanar loop, which was further attached to the central CeⅣ ion via eight μ3-O2- ions. Magnetic studies indicate that, within the cluster, the magnetic coupling interactions between Mn3+ ions are weak ferromagnetic, with the ground state Sbeing 6. Moreover, there are only very weak frequency-dependent signals from ac magnetic susceptibility investigations. By analyzing magneto-structural correlation of a series of [Mn8Ce] complexes, we found that with the angles at monoatomically bridging O2- increasing and with the angle at monoatomically bridging carboxylate Odecreasing, the ferromagnetic interactions between Mn atoms will be strengthened, which further lead to larger S.
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    1. [1]

      [1] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993, 115:1804-1816

    2. [2]

      [2] (a)Zaleski C M, Depperman E C, Kampf J W, et al. Angew. Chem. Int. Ed., 2004, 43:3912-3914

    3. [3]

      (b)WANG Hui-Sheng(王会生), PAN Zhi-Quan(潘志权). Chinese J. Inorg. Chem.(无机化学学报), 2013, 29(7):1459-1464

    4. [4]

      [3] Lin P H, Burchell T J, Clerac R, et al. Angew. Chem. Int. Ed., 2008, 47:8848-8851

    5. [5]

      [4] Chilton N F, Langley S K, Moubaraki B, et al. Chem. Sci., 2013, 4:1719-1730

    6. [6]

      [5] Przychodzeń P, Korzeniak T, Podgajny R, et al. Coord. Chem. Rev., 2006, 250:2234-2260

    7. [7]

      [6] Leuenberger M, Loss D. Nature, 2001, 410:789-793

    8. [8]

      [7] Aromi G, Aguila D, Gamez F, et al. Chem. Soc. Rev., 2012, 41:537-546

    9. [9]

      [8] Ardavan A, Rival O, Morton, J J L, et al. Phys. Rev. Lett., 2007, 98:057201(1-4)

    10. [10]

      [9] Christou G, Gatteschi D, Hendrickson D N, et al. MRS Bull., 2000, 25:66-71

    11. [11]

      [10] Wang H S, Zhang Z C, Song X J, et al. Dalton Trans., 2011, 40:2703-2706

    12. [12]

      [11] Miyazaki Y, Bhattacharjee A, Nakano M, et al. Inorg. Chem., 2001, 40:6632-6636

    13. [13]

      [12] Schake A R, Tsai H L, de Vries N, et al. Chem. Commun., 1992:181-183

    14. [14]

      [13] King P, Wernsdorfer W, Abboud K A, et al. Inorg. Chem., 2005, 44:8659-8669

    15. [15]

      [14] Chakov Ni E, Soler M, Wernsdorfer W, et al. Inorg. Chem., 2005, 44:5304-5321

    16. [16]

      [15] Chakov N E, Lee S C, Harter A G, et al. J. Am. Chem. Soc., 2006, 128:6975-6989

    17. [17]

      [16] Soler M, Artus P, Folting K, et al. Inorg. Chem., 2001, 40: 4902-4912

    18. [18]

      [17] Boskovic C, Pink M, Huffman J C, et al. J. Am. Chem. Soc., 2001, 123:9914-9915

    19. [19]

      [18] Artus P, Boskovic C, Yoo J, et al. Inorg. Chem., 2001, 40: 4199-4210

    20. [20]

      [19] Soler M, Wernsdorfer W, Abboud K A, et al. J. Am. Chem. Soc., 2003, 125:3576-3588

    21. [21]

      [20] Soler M, Chandra S K, Ruiz D, et al. Polyhedron, 2001, 20: 1279-1283

    22. [22]

      [21] Tasiopoulos A J, Wernsdorfer W, Moulton B, et al. J. Am. Chem. Soc., 2003, 125:15724-15725

    23. [23]

      [22] Wang H S, Ma C B, Wang M, et al. J. Mol. Struct., 2008, 875:288-294

    24. [24]

      [23] Mishra A, Tasiopoulos A J, Wernsdorfer W, et al. Inorg. Chem., 2008, 47:4832-4843

    25. [25]

      [24] Canty A J, Minchin N J, Patrick J M, et al. Dalton Trans., 1983:1253-1259

    26. [26]

      [25] SAINT-Plus, Version 6.02; Bruker Analytical X-ray System, Madison, WI, 1999.

    27. [27]

      [26] Sheldrick G M. SHELXTL-97, Universitt of Göttingen, Göttingen, Germany, 1997.

    28. [28]

      [27] (a)Liu W, Thorp H H. Inorg. Chem., 1993, 32:4102-4105

    29. [29]

      (b)Brown I D, Shannon R D. Acta Crystallogr., 1973, A29: 266-282

    30. [30]

      (c)Roulhac P L, Palenik G J. Inorg. Chem., 2003, 42:118-121

    31. [31]

      [28] Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002, 124:2279-2292

    32. [32]

      [29] Scott R T W, Parsons S, Murugesu M, et al. Angew. Chem., Int. Ed., 2005, 44:6540-6543

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