Advanced Search

Citation: GUO Ying-Chen, FENG Yu-Quan, QIAO Zhan-Ping, CHEN Shu-Yang, HUANG Shen-Zhen. Syntheses, Crystal Structures and Antibacterial Activities of Dithiocarbamate Complexes ([M(MeBnNCS2)3], M=Sb(Ⅲ), Bi(Ⅲ))[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1031-1037. doi: 10.11862/CJIC.2014.178 shu

Syntheses, Crystal Structures and Antibacterial Activities of Dithiocarbamate Complexes ([M(MeBnNCS2)3], M=Sb(Ⅲ), Bi(Ⅲ))

  • 1.

    College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

  • Received Date: 28 March 2013
    Available Online: 16 February 2014

    Fund Project: 河南省国际合作计划项目(No.134300510013)；河南省教育厅自科基金(No.2011B150025)资助项目。 (No.134300510013)；河南省教育厅自科基金(No.2011B150025)

  • Two novel complexes [Sb(Ⅲ)(MeBnNCS2)3] (1) and [Bi(Ⅲ)(MeBnNCS2)3] (2) were synthesized and characterized by elemental analysis, IR, 1H NMR, TG-DTG and X-ray single-crystal diffraction. Both complexes belong to monoclinic system, P21/c space group, for 1: a=0.9551(7) nm, b=1.3575(10) nm, c=2.4681(17) nm, β=104.01(2)°, Z=4, V=3.105 (4) nm3, Dc=1.520 g·cm-3, F(000)=1440, μ=1.314 mm-1, the final R1=0.0339, wR2=0.0832, S=1.010, for 2: a=1.3390(6) nm, b=0.9975(5) nm, c=2.4261(5) nm, β=98.433(7)°, Z=4, V=3.205(2) nm3, Dc=1.653 g·cm-3, F(000)=1568, μ=5.912 mm-1, the final R1=0.0398, wR2=0.0864, S=1.089. The central M(Ⅲ) are coordinated by six sulfur atoms from three legends, completing distorted octahedral coordination environment in 1 and pentagonal pyramid configuration in 2. For 2, the adjacent molecules are formed the dimmer structure by the weak interactions of Bi…S. The complexes were valued for their antimicrobial activities by agar diffusion method. The results indicate that the complex 1 to be active against the four test bacterial organisms.
  • 加载中
    1. [1]

      [1] HU Sheng-Zhi(胡盛志), LIN Wen-Feng(林文锋). Chinese J. Struct. Chem.(结构化学), 1989, 8(4):249-250

    2. [2]

      [2] Lecureur V, Lagadic-Gossmann D, Fardel O. Int. J. Oncol., 2002, 20(5):1071-1076

    3. [3]

      [3] GUO Ying-Chen(郭应臣), ZHUO Li-Hong(卓立宏), QIAO Zhan-Ping(乔占平). Chinese J. Inorg. Chem.(无机化学学 报), 2006, 22(1):134-138

    4. [4]

      [4] Kasuga N C, Onodera K, Nakano S, et al. J. Inorg. Biochem., 2006, 100:1176-1186

    5. [5]

      [5] Sun R Z, Guo Y C, Liu W M, et al. Chinese J. Struct. Chem., 2012, 31(5):655-660

    6. [6]

      [6] Hadjikakou S K, Antoniadis C D, Hadjiliadis N, et al. Inorg. Chim. Acta, 2005, 358(10): 2861-2866

    7. [7]

      [7] Kafetzis D A, Velissariou I M, Stabouli S, et al. Int. J. Antimicrob. Agents, 2005, 25(1):26-30

    8. [8]

      [8] YANG Nan(杨楠), SUN Hong-Zhe(孙红哲). Prog. Chem.(化 学进展), 2009, 21(5):856-864

    9. [9]

      [9] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), XU Fu-Quan(许福泉). Chinese J. Inorg. Chem.(无机化学学报), 2004, 20(3):345-348

    10. [10]

      [10] Kiran S, Sharma P K, Dubey S N. Indian J. Chem., 1994, 33A:266-268

    11. [11]

      [11] Sun H, Szeto K Y. J. Inorg. Biochem., 2003, 94:114-120

    12. [12]

      [12] Sun H, Szeto K Y, Zhang L. Met. Ions Biol. Syst., 2004, 41: 333-378

    13. [13]

      [13] Wang X, Zhang X, Lin J, et al. J. Chem. Soc., Dalton Trans., 2003(12):2379-2380

    14. [14]

      [14] Tiekink E R T. Crit. Rev. Oncol. Hematol., 2002, 42:217-224

    15. [15]

      [15] Li H Y, Lai C S, Wu J Z, et al. J. Inorg. Biochem., 2007, 101:809-816

    16. [16]

      [16] Xie J, Funakoshi T, Shimada H, et al. Res. Commun. Mol. Pathol. Pharmacol., 1994, 86(2):245-255

    17. [17]

      [17] Gringeri A, Keng P C, Borch R F. Cancer Res., 1988, 48: 5708-5713

    18. [18]

      [18] ZHANG Zhi-Peng(张志朋), ZHONG Guo-Qing(钟国清), JIANG Qi-Ying(蒋琪英). Fine Chem. Icals.(精细化工), 2010, 27(2):201-204

    19. [19]

      [19] Sheldrick G M. SHELX-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.

    20. [20]

      [20] Sheldrick G M. SHELX-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.

    21. [21]

      [21] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), WANG Da-Qi(王大奇), et al. Chinese J. Org. Chem.(有机 化学), 2004, 24(6):658-662

    22. [22]

      [22] ZHANG Xin(张 欣), GU Si(杜聪), CHEN Dan(陈丹), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010, 26(3):489-494

    23. [23]

      [23] ZHANG Zhi-Peng(张志朋), ZHONG Guo-Qing(钟国清), JIANG Qi-Ying(蒋琪英). Prog. Chem.(化学进展), 2008, 20 (9):1315-1323

  • 加载中
    1. [1]

      Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

    2. [2]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    3. [3]

      Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    4. [4]

      Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278

    5. [5]

      Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe3+ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402

    6. [6]

      Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395

    7. [7]

      Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003

    8. [8]

      Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009

    9. [9]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    10. [10]

      Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416

    11. [11]

      Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two SmⅢ4 complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

    12. [12]

      Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078

    13. [13]

      Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173

    14. [14]

      Ruiying WANG , Hui WANG , Fenglan CHAI , Zhinan ZUO , Benlai WU . Three-dimensional homochiral Eu(Ⅲ) coordination polymer and its amino acid configuration recognition. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 877-884. doi: 10.11862/CJIC.20250052

    15. [15]

      Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207

    16. [16]

      Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271

    17. [17]

      Jinfeng Chu ,  Lan Jin ,  Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016

    18. [18]

      Yan Liu ,  Yuexiang Zhu ,  Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084

    19. [19]

      Weina Wang ,  Fengyi Liu ,  Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

    20. [20]

      Junqiao Zhuo ,  Xinchen Huang ,  Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(360)
  • HTML views(27)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return