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Citation: GUO Ying-Chen, FENG Yu-Quan, QIAO Zhan-Ping, CHEN Shu-Yang, HUANG Shen-Zhen. Syntheses, Crystal Structures and Antibacterial Activities of Dithiocarbamate Complexes ([M(MeBnNCS2)3], M=Sb(Ⅲ), Bi(Ⅲ))[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1031-1037. doi: 10.11862/CJIC.2014.178 shu

Syntheses, Crystal Structures and Antibacterial Activities of Dithiocarbamate Complexes ([M(MeBnNCS2)3], M=Sb(Ⅲ), Bi(Ⅲ))

  • 1.

    College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

  • Received Date: 28 March 2013
    Available Online: 16 February 2014

    Fund Project: 河南省国际合作计划项目(No.134300510013)；河南省教育厅自科基金(No.2011B150025)资助项目。 (No.134300510013)；河南省教育厅自科基金(No.2011B150025)

  • Two novel complexes [Sb(Ⅲ)(MeBnNCS2)3] (1) and [Bi(Ⅲ)(MeBnNCS2)3] (2) were synthesized and characterized by elemental analysis, IR, 1H NMR, TG-DTG and X-ray single-crystal diffraction. Both complexes belong to monoclinic system, P21/c space group, for 1: a=0.9551(7) nm, b=1.3575(10) nm, c=2.4681(17) nm, β=104.01(2)°, Z=4, V=3.105 (4) nm3, Dc=1.520 g·cm-3, F(000)=1440, μ=1.314 mm-1, the final R1=0.0339, wR2=0.0832, S=1.010, for 2: a=1.3390(6) nm, b=0.9975(5) nm, c=2.4261(5) nm, β=98.433(7)°, Z=4, V=3.205(2) nm3, Dc=1.653 g·cm-3, F(000)=1568, μ=5.912 mm-1, the final R1=0.0398, wR2=0.0864, S=1.089. The central M(Ⅲ) are coordinated by six sulfur atoms from three legends, completing distorted octahedral coordination environment in 1 and pentagonal pyramid configuration in 2. For 2, the adjacent molecules are formed the dimmer structure by the weak interactions of Bi…S. The complexes were valued for their antimicrobial activities by agar diffusion method. The results indicate that the complex 1 to be active against the four test bacterial organisms.
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