Citation: CHEN Qi, FEI Xia, HE Qin-Qin, LÜ Meng-Meng, WU Qi-Liang, LIU Xue-Ting, HE Bing. Preparation and Photocatalytic Properties of MIL-101/P25 Composites[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 993-1000. doi: 10.11862/CJIC.2014.175 shu

Preparation and Photocatalytic Properties of MIL-101/P25 Composites

1.
School of Chemical Engineering, Hefei University of Technology, Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China

Received Date: 18 December 2013
Available Online: 18 December 2013
Fund Project: 安徽高校省级自然科学研究重点资助项目(No.KJ2010A271)。 (No.KJ2010A271)

Via hydrothermal method, MIL-101 was loaded on to the pretreated P25 to obtain MIL-101/P25 composites that were structurally characterized using X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), N₂ adsorption-desorption (BET), thermogravimetry (TG), field emission transmission electron microscopy (FETEM) and photoluminescence (PL), meanwhile, the stability of MIL-101 and the composites was investigated, and the synergistic effect induced by compounding was quantitatively evaluated by the proposed synergistic factor. The results show that MIL-101 has sheet-like morphology, and a portion of it combined with P25. After compounding, the stability of MIL-101 is promoted. Compounding can bring the synergistic effect at the appropriate ratio, and when the molar ratio of Cr(NO₃)₃·9H₂O to P25 is 1:1, the composite exhibits the highest activity for the visible light photocatalytic degradation of rhodamine B, and the synergistic factor is 1.64. The composite also exhibits high photocatalytic activity for the degradation of colorless organic pollutant salicylic acid.
- MIL-101;photocatalysis;P25;compounding;synergistic effect
1. [1]
  [1] WU Jun-Min(吴俊明), WANG Ya-Ping(王亚平), YANG Han-Pei(杨汉培), et al. Chinese J. Inorg. Chem. (无机化学学报), 2010, 26(2):203-210
2. [2]
  [2] LIU Su-Qin(刘素芹), DAI Gao-Peng(戴高鹏), LIANG Ying (梁英), et al. Acta Phys.-Chim. Sin. (物理化学学报), 2013, 29(3):585-589
3. [3]
  [3] Bux H, Liang F Y, Li Y S, et al. J. Am. Chem. Soc., 2009, 131(44):16000-16001
4. [4]
  [4] Du J J, Yuan Y P, Sun J X, et al. J. Hazard. Mater., 2011, 190(1/2/3):945-951
5. [5]
  [5] Yu H, Takashi T, Masakazu S, et al. J. Phys. Chem. C, 2012, 116(39):20848-20853
6. [6]
  [6] Vallet-Regi M, Balas F, Arcos D. Angew. Chem. Int. Ed., 2007, 46(40):7548-7558
7. [7]
  [7] Wu F, Qiu L G, Ke F, et al. Inorg. Chem. Commun., 2013, 32:5-8
8. [8]
  [8] Murray L J, Dinc M, Long J R. Chem. Soc. Rev., 2009, 38(5): 1294-1314
9. [9]
  [9] Hong D Y, Hwang Y K, Serre C, et al. Adv. Funct. Mater., 2009, 19(10):1537-1552
10. [10]
  [10] Vallet-Regi M, Balas F, Arcos D. Angew. Chem. Int. Ed., 2007, 46(40):7548-7558
11. [11]
  [11] Tsuruoka T, Kawasaki H, Nawafune H, et al. ACS Appl. Mater. Inter., 2011, 3(10):3788-3791
12. [12]
  [12] Sun Z G, Li G, Liu L P, et al. Catal. Comm., 2012, 27:200-205
13. [13]
  [13] Xiang Z, Peng X, Cheng X, et al. J. Phys. Chem. C, 2011, 115(40):19864-19871
14. [14]
  [14] Lim D W, Yoon J W, Ryu K Y, et al. Angew. Chem. Int. Ed., 2012, 51(39):9814-9817
15. [15]
  [15] Zhou G M, Wang D W, Yin L C, et al. ACS Nano, 2012, 6 (4):3214-3223
16. [16]
  [16] Zhong R Q, Zou R Q, Nakagawa T, et al. Inorg. Chem., 2012, 51(5):2728-2730
17. [17]
  [17] Glover T G, Sabo D, Vaughan L A, et al. Langmuir, 2012, 28(13):5695-5702
18. [18]
  [18] Ferey G, Mellot-Draznieks C, Serre C, et al. Science, 2005, 309:2040-2042
19. [19]
  [19] Prasanth K P, Rallapalli P, Raj M C, et al. Int. J. Hydrogen Energ., 2011, 36(13):7594-7601
20. [20]
  [20] Chen C, Zhang M, Guan Q X, et al. Chem. Eng. J., 2012, 183:60-67
21. [21]
  [21] Butler M A. J. Appl. Phys., 1977, 48:1914-1920
22. [22]
  [22] Chen X B, Liu L, Yu P Y, et al. Science, 2011, 331:746-749
23. [23]
  [23] Wu T X, Liu G M, Zhao J C. J. Phys. Chem. B, 1998, 102 (30):5845-5851
1. [1]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
2. [2]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
3. [3]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013
4. [4]
  Jia Wang , Qing Qin , Zhe Wang , Xuhao Zhao , Yunfei Chen , Liqiang Hou , Shangguo Liu , Xien Liu . P-Doped Carbon-Supported Zn_xP_yO_z for Efficient Ammonia Electrosynthesis under Ambient Conditions. Acta Physico-Chimica Sinica, 2024, 40(3): 2304044-0. doi: 10.3866/PKU.WHXB202304044
5. [5]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083
6. [6]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
7. [7]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
8. [8]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
9. [9]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
10. [10]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
11. [11]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
14. [14]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 913-922. doi: 10.11862/CJIC.20240255
15. [15]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
16. [16]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
17. [17]
  Jiajia Wang , Sibo Huang , Xijing Gao , Chaoxun Liu , Haibo Zhang . 光催化硝酸根还原产氨的综合实验设计. University Chemistry, 2025, 40(8): 241-248. doi: 10.12461/PKU.DXHX202410050
18. [18]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-0. doi: 10.3866/PKU.WHXB202312014
19. [19]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
20. [20]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(582)
HTML views(139)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142