Citation: YUAN Hou-Qun, HU Chun-Yan, BAO Guang-Ming, XIAO Wei, SUN Ting-Ting, XING Yong-Heng. Synthesis, Crystal Structures of Cyclic Dinuclear Zn(Ⅱ) and Cd(Ⅱ) Complexes with 3-Nitrophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1195-1200. doi: 10.11862/CJIC.2014.166
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Two complexes [Zn2(npa)2(Im)4] (1) and [Cd2(npa)2(2,2'-bipy)2(H2O)2]·2H2O (2) (H2npa=3-nitrophthalic acid, Im=imidazole, 2,2'-bipy=2,2'-bipyridine) were constructed by the use of 3-nitrophthalic acid and imidazole or 2,2'-bipyridine, respectively. The complexes were characterized by elemental analysis, IR, and the crystal structures were determined by single X-ray diffraction. The thermal stabilities of the complexes were studied by thermal gravimetric analysis. The two complexes are dinuclear structures, and both contain M2C8O4 14-membered rings. The dinuclear units extend to 3D network through intermolecular hydrogen bonding interactions for complex 1, while a 2D sheet structure is formed for complex 2 by hydrogen bonding and π-π stacking interactions.
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