Citation: WANG Yue-Hui, WANG Ting, ZHOU Ji. Effects of Silver Nanoparticles on the Luminescent Properties of Europium Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1179-1186. doi: 10.11862/CJIC.2014.161 shu

Effects of Silver Nanoparticles on the Luminescent Properties of Europium Complex

1.
1 Department of Chemistry and Biology, University of Electronic Science and Technology of China Zhongshan Institute, Zhongshan, Guangdong 528402, China;

Received Date: 30 August 2013
Available Online: 12 December 2013
Fund Project: 国家自然科学基金(No.61302044) (No.61302044)广东省自然科学基金(No.S2012010010646)资助项目。 (No.S2012010010646)

Adetailed study of the effects of silver nanoparticles on the luminescent properties of the europium complex (Eu(Ⅲ)C₇H₅NO₄, Eu(Ⅲ)DPA), where DPAis dipicolinic acid, in the aqueous solution system was reported. The emission intensity of the Eu(Ⅲ)DPA solution initially increased with increasing of the amount of silver colloids and then decreased. The large silver nanoparticles resulted in the high enhancement efficiency and the low amount at which the enhancement efficiency reaches the maximum. The emission intensity was quenched by silver nanoparticles in high concentration of Eu(Ⅲ)DPA solution. The enhancement for the emission of electric dipole transition was stronger than that of magnetic dipole transition. The observed silver nanoparticles dependences of the luminescent intensity were regarded as the result of a stronger coupling between the surface plasmon resonance and the excited luminescence centers and re-absorption of surface plasmon resonance of silver nanoparticles. Meanwhile, the asymmetric ratio of the europium luminescence affected by silver nanoparticles was discussed in terms of the local electromagnetic field enhancement, refractive index, and the ligand field around europium ion.
- europium complex;silver nanoparticles;luminescence enhancement;surface plasmon resonance;local electromagnetic field
1. [1]
  [1] Eltzov E, Prilutsky D, Kushmaro A, et al. Appl. Phys. Lett., 2009, 94:083901-1-3
2. [2]
  [2] Aslan K, Zhang Y, Geddes C D. Anal. Chem., 2009, 81:6913-6922
3. [3]
  [3] Xie F, Baker M S, Goldys E M. Chem. Mater., 2008, 20:1788-1797
4. [4]
  [4] Wang Z, Zong S, Yang J, e al. Biosens Bioelectron, 2011, 26: 2883-2889
5. [5]
  [5] Aslan K, Malyn S N, Geddes C D. Chem. Phys. Lett., 2008, 453:222-228
6. [6]
  [6] Ming T, Zhao L, Chen H J, et al. Nano Lett., 2011, 11:2296-2303
7. [7]
  [7] Previte J R M, Zhang Y, Aslan K, et al. Appl. Phys. Lett., 2007, 91:151902-1-3
8. [8]
  [8] Ray K, Chowdhury M H, Lakowicz J R. Anal. Chem., 2007, 79:6480-6487
9. [9]
  [9] Aslan K, Geddes C D. Appl. Phys. Lett., 2009, 94:073104-1-3
10. [10]
  [10] Tovmachenko O G, Graf C, Heuvel D J, et al. Adv. Mater., 2006, 18:91-95
11. [11]
  [11] Stender A S, Wang G, Sun W. ACS Nano, 2010, 4:7667-7675
12. [12]
  [12] Lu G, Zhang T, Li W, et al. J. Phys. Chem. C, 2011, 115: 15822-1-3
13. [13]
  [13] Geddes C D, Parfenov A, Roll D, et al. J. Fluorescence, 2003, 13:267-276
14. [14]
  [14] Liaw J W, Tsai H, Huang C. Plasmonics, 2012, 7:543-553
15. [15]
  [15] Campion A, Gallo A R, Harris C B, et al. Chem. Phys. Lett., 1980, 73:447-450
16. [16]
  [16] Hayakawa T, Furuhashi K, Nogami M. J. Phys. Chem. B, 2004, 108:11301-11307
17. [17]
  [17] Wu M, Lakowicz J R, Geddes C D. J. Fluorescence, 2005, 15:53-59
18. [18]
  [18] Ipe B I, Yoosaf K, Thomas K G. J. Am. Chem. Soc., 2006, 128:1907-1913
19. [19]
  [19] Wang Y, Zhou J, Wang T. Mater. Lett., 2008, 62:1937-1940
20. [20]
  [20] Lakowicz J R, Maliwal B P, Malicka J, et al. J. Fluorescence, 2002, 12:431-437
21. [21]
  [21] Fu Y, Zhang J, Lakowicz J R. J. Am. Chem. Soc., 2010, 132: 5540-5541
22. [22]
  [22] Hayakawa T, Selvan S T, Nogami M. J. Non-Cryst. Solids, 1999, 259:16-22
23. [23]
  [23] Nabika H, Deki S. Eur. Phys. J. D, 2003, 24:369-372
24. [24]
  [24] Nabika H, Deki S. J. Phys. Chem. B, 2003, 107:9161-9164
25. [25]
  [25] Wang Y, Zhou X, Wang T, et al. Materials Letters, 2008, 62: 3582-3584
26. [26]
  [26] WANG Yue-Hui(王悦辉), WANG Ting(王婷), ZHOU Ji(周济). Chinese Journal of Inorganic Chemistry(无机化学学报), 2008, 24:205-210
27. [27]
  [27] WANG Yue-Hui(王悦辉), ZHOU Ji(周济), SHI Shikao(石士考). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27:1555-1559
28. [28]
  [28] Messinger B J, Ulrich K, Raben R K, et al. Phys. Rev. B, 1981, 24:649-657
29. [29]
  [29] Viste P, Plain J, Jaffiol R, et al. ACS Nano., 2011, 4:759-764
30. [30]
  [30] Selvan S T, Hayakawa T, Nogami M. J. Phys. Chem. B, 1999, 103:7064-7067
1. [1]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
2. [2]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
3. [3]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
4. [4]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
5. [5]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
8. [8]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
9. [9]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
10. [10]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
11. [11]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
12. [12]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
13. [13]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
14. [14]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
15. [15]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
16. [16]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
17. [17]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
18. [18]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
19. [19]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
20. [20]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(321)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142