Citation: WANG Yue-Hui, WANG Ting, ZHOU Ji. Effects of Silver Nanoparticles on the Luminescent Properties of Europium Complex[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(5): 1179-1186. doi: 10.11862/CJIC.2014.161 shu

Effects of Silver Nanoparticles on the Luminescent Properties of Europium Complex

1.
1 Department of Chemistry and Biology, University of Electronic Science and Technology of China Zhongshan Institute, Zhongshan, Guangdong 528402, China;

Received Date: 30 August 2013
Available Online: 12 December 2013
Fund Project: 国家自然科学基金(No.61302044) (No.61302044)广东省自然科学基金(No.S2012010010646)资助项目。 (No.S2012010010646)

Adetailed study of the effects of silver nanoparticles on the luminescent properties of the europium complex (Eu(Ⅲ)C₇H₅NO₄, Eu(Ⅲ)DPA), where DPAis dipicolinic acid, in the aqueous solution system was reported. The emission intensity of the Eu(Ⅲ)DPA solution initially increased with increasing of the amount of silver colloids and then decreased. The large silver nanoparticles resulted in the high enhancement efficiency and the low amount at which the enhancement efficiency reaches the maximum. The emission intensity was quenched by silver nanoparticles in high concentration of Eu(Ⅲ)DPA solution. The enhancement for the emission of electric dipole transition was stronger than that of magnetic dipole transition. The observed silver nanoparticles dependences of the luminescent intensity were regarded as the result of a stronger coupling between the surface plasmon resonance and the excited luminescence centers and re-absorption of surface plasmon resonance of silver nanoparticles. Meanwhile, the asymmetric ratio of the europium luminescence affected by silver nanoparticles was discussed in terms of the local electromagnetic field enhancement, refractive index, and the ligand field around europium ion.
- europium complex;silver nanoparticles;luminescence enhancement;surface plasmon resonance;local electromagnetic field
1. [1]
  [1] Eltzov E, Prilutsky D, Kushmaro A, et al. Appl. Phys. Lett., 2009, 94:083901-1-3
2. [2]
  [2] Aslan K, Zhang Y, Geddes C D. Anal. Chem., 2009, 81:6913-6922
3. [3]
  [3] Xie F, Baker M S, Goldys E M. Chem. Mater., 2008, 20:1788-1797
4. [4]
  [4] Wang Z, Zong S, Yang J, e al. Biosens Bioelectron, 2011, 26: 2883-2889
5. [5]
  [5] Aslan K, Malyn S N, Geddes C D. Chem. Phys. Lett., 2008, 453:222-228
6. [6]
  [6] Ming T, Zhao L, Chen H J, et al. Nano Lett., 2011, 11:2296-2303
7. [7]
  [7] Previte J R M, Zhang Y, Aslan K, et al. Appl. Phys. Lett., 2007, 91:151902-1-3
8. [8]
  [8] Ray K, Chowdhury M H, Lakowicz J R. Anal. Chem., 2007, 79:6480-6487
9. [9]
  [9] Aslan K, Geddes C D. Appl. Phys. Lett., 2009, 94:073104-1-3
10. [10]
  [10] Tovmachenko O G, Graf C, Heuvel D J, et al. Adv. Mater., 2006, 18:91-95
11. [11]
  [11] Stender A S, Wang G, Sun W. ACS Nano, 2010, 4:7667-7675
12. [12]
  [12] Lu G, Zhang T, Li W, et al. J. Phys. Chem. C, 2011, 115: 15822-1-3
13. [13]
  [13] Geddes C D, Parfenov A, Roll D, et al. J. Fluorescence, 2003, 13:267-276
14. [14]
  [14] Liaw J W, Tsai H, Huang C. Plasmonics, 2012, 7:543-553
15. [15]
  [15] Campion A, Gallo A R, Harris C B, et al. Chem. Phys. Lett., 1980, 73:447-450
16. [16]
  [16] Hayakawa T, Furuhashi K, Nogami M. J. Phys. Chem. B, 2004, 108:11301-11307
17. [17]
  [17] Wu M, Lakowicz J R, Geddes C D. J. Fluorescence, 2005, 15:53-59
18. [18]
  [18] Ipe B I, Yoosaf K, Thomas K G. J. Am. Chem. Soc., 2006, 128:1907-1913
19. [19]
  [19] Wang Y, Zhou J, Wang T. Mater. Lett., 2008, 62:1937-1940
20. [20]
  [20] Lakowicz J R, Maliwal B P, Malicka J, et al. J. Fluorescence, 2002, 12:431-437
21. [21]
  [21] Fu Y, Zhang J, Lakowicz J R. J. Am. Chem. Soc., 2010, 132: 5540-5541
22. [22]
  [22] Hayakawa T, Selvan S T, Nogami M. J. Non-Cryst. Solids, 1999, 259:16-22
23. [23]
  [23] Nabika H, Deki S. Eur. Phys. J. D, 2003, 24:369-372
24. [24]
  [24] Nabika H, Deki S. J. Phys. Chem. B, 2003, 107:9161-9164
25. [25]
  [25] Wang Y, Zhou X, Wang T, et al. Materials Letters, 2008, 62: 3582-3584
26. [26]
  [26] WANG Yue-Hui(王悦辉), WANG Ting(王婷), ZHOU Ji(周济). Chinese Journal of Inorganic Chemistry(无机化学学报), 2008, 24:205-210
27. [27]
  [27] WANG Yue-Hui(王悦辉), ZHOU Ji(周济), SHI Shikao(石士考). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27:1555-1559
28. [28]
  [28] Messinger B J, Ulrich K, Raben R K, et al. Phys. Rev. B, 1981, 24:649-657
29. [29]
  [29] Viste P, Plain J, Jaffiol R, et al. ACS Nano., 2011, 4:759-764
30. [30]
  [30] Selvan S T, Hayakawa T, Nogami M. J. Phys. Chem. B, 1999, 103:7064-7067
1. [1]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
2. [2]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
3. [3]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
4. [4]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
5. [5]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
6. [6]
  Feng Lu , Tao Wang , Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005
7. [7]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
8. [8]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
9. [9]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
12. [12]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
13. [13]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
14. [14]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
15. [15]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
16. [16]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
17. [17]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
18. [18]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Zijuan LI , Xuan LÜ , Jiaojiao CHEN , Haiyang ZHAO , Shuo SUN , Zhiwu ZHANG , Jianlong ZHANG , Yanling MA , Jie LI , Zixian FENG , Jiahui LIU . Synthesis of visual fluorescence emission CdSe nanocrystals based on ligand regulation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 308-320. doi: 10.11862/CJIC.20240138

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(455)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142