Citation: WANG Wei-Na, ZHENG Yuan-Mei, CHEN Xue-Mei. A Fluorescence Enhancement Probe for Visual Detection of Zn²⁺ with Receptor Based on DPA[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 872-878. doi: 10.11862/CJIC.2014.159 shu

A Fluorescence Enhancement Probe for Visual Detection of Zn²⁺ with Receptor Based on DPA

1.
1 Higher Vocational Technical School, Hubei Polytechnic University, Huangshi, Hubei 435003, China;

Corresponding author: WANG Wei-Na,
Received Date: 13 October 2013
Available Online: 9 December 2013
Fund Project: 国家自然科学基金资助项目(No.51173060)。 (No.51173060)

Afluorescence enhancement probe WNfor detection of Zn²⁺ with receptor based on di-2-picolylamine (DPA) was synthesized and structurally characterized. Its recognition properties with Zn²⁺ had been investigated in CH₃CH₂OH/Tris-HCl buffer solution (1:9, V/V, pH=7.4). The results showed that WN exhibited good sensitivity and selectivity to Zn²⁺, and the stoichiometry of WN-Zn²⁺ complex was estimated to be 1:1, the detection limit of Zn²⁺ was estimated to be 1.14×10^-8 mol·L^-1. WN was used for fast visual detection of Zn²⁺ and its intracelluar Zn²⁺ imaging in living HeLa cells, indicated that it could be applied in biological detection.
- DPA;zinc ion;fluorescent probe;visual detection;fluorescent imaging
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A Fluorescence Enhancement Probe for Visual Detection of Zn2+ with Receptor Based on DPA

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通讯作者: 陈斌, bchen63@163.com

A Fluorescence Enhancement Probe for Visual Detection of Zn²⁺ with Receptor Based on DPA