Citation: CHEN Jun-Gang, PENG Tong-Jiang, SUN Hong-Juan, LIU Bo, ZHAO Er-Zheng. Influence of Reduction Temperature on Functional Groups, Structures and Humidity Sensitivity of Graphite Oxide[J]. Chinese Journal of Inorganic Chemistry, ;2014, 30(4): 779-785. doi: 10.11862/CJIC.2014.153 shu

Influence of Reduction Temperature on Functional Groups, Structures and Humidity Sensitivity of Graphite Oxide

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1 School of Science, Southwest University of Science & Technology, Mianyang, Sichuan 621010, China;

Corresponding author: PENG Tong-Jiang,
Received Date: 28 July 2013
Available Online: 11 December 2013
Fund Project: 国家自然科学基金资助项目(No.41272051)；西南科技大学博士基金(No.11ZX7135)。 (No.41272051)；西南科技大学博士基金(No.11ZX7135)

Based on the various functional groups of graphite oxide, the influence of reduction temperature on structures and humidity sensitivity of graphite oxide has been studied. High oxidized graphene oxide samples prepared by modified Hummers method were reduced at different temperature. And the humidity sensors were made with the reduction products. Functional groups and structures changes of the experiment process samples were carried out by FTIR, XRD and Raman spectrum. The results show that functional groups of -OH, epoxy group, C=O and COOH were combined with the structure layer of carbon atoms during oxidation process. And the basal spacing of graphite oxide is about 0.9084 nm. As the increase of reduction temperature, functional groups were gradually thermal decomposition and the graphitization area gradually restored, but the relative sizes were decreased and the defects were increased. Furthermore, the basal spacing of graphite oxide was decreased from 0.9084 nm to 0.4501 nm along the c axis. The resistances of the graphite oxide thin film were decreased from 10.32 MΩ to 41.1 Ω. In the relative humidity of 11.3%~93.6%, the resistance of the graphite oxide thin film humidity elements was significantly reduced with increasing of humidity. The higher of the reduction degree was, the longer of element's response time was and the shorter of the element's desorption time was. The graphite oxide film humidity element of 150 ℃ reduction was the best humidity sensitive performance.
- reduction temperature;graphite oxide;functional groups;structure;humidity-sensitive properties and mechanism
1. [1]
  [1] WAN Chen(万臣), PENG Tong-Jiang(彭同江), SUN Hong-Juan(孙红娟), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(5):915-921
2. [2]
  [2] Buchsteiner A, Lerf A, Pieper J. J. Phys. Chem. B, 2006, 110 (45):22328-22338
3. [3]
  [3] XIAO Min(肖敏), DU Xu-Sheng(杜续生), MENG Yue-Zhong (孟跃中), et al. New Carbon Mater.(新型炭材料), 2004, 19 (2):92-96
4. [4]
  [4] ZOU Yan-Hong(邹艳红), LIU Hong-Bo(刘洪波), FU Ling(傅玲), et al. J. Chinese Ceram. Soc.(硅酸盐学报), 2006, 34(3): 318-323
5. [5]
  [5] Jeong H K, Lee Y P, Jin M H, et al. Chem. Phys. Lett., 2009, 470(4):255-258
6. [6]
  [6] HANG Qiao(黄桥), SUN Hong-Juan(孙红娟), YANG Yong-Hui(杨勇辉). Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(9):1721-1726
7. [7]
  [7] Xu J, Hu Y, Song L, et al. Polym. Degrad. Stabil., 2001, 73 (1):29-31
8. [8]
  [8] Wang X, Dou W. Thermochim. Acta, 2012, 529:25-28
9. [9]
  [9] Tulliani J M, Cavalieri A, Musso S, et al. Sensor Actuat. B-Chem., 2011, 152(2):144-154
10. [10]
  [10] Akhavan O. Carbon, 2010, 48(2):509-519
11. [11]
  [11] WANG Ya-Ling(王亚玲), GAO Peng(高鹏), WU Xiao-Jing (吴晓婧), et al. Chinese J. Inorg. Chem.(无机化学学报), 2012, 28(2):391-397
12. [12]
  [12] HAN Zhi-Dong(韩志东), WANG Jian-Qi(王建祺). Chinese J. Inorg. Chem.(无机化学学报), 2003, 19(5):459-461
13. [13]
  [13] LIU Xiu-Ying(刘秀影), SONG Ying(宋英), LI Cun-Mei(李存梅), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(11):2128-2132
14. [14]
  [14] Cerveny S, Barroso-Bujans F, Alegria A, et al. J. Phys. Chem. C, 2010, 114(6):2604-2612
15. [15]
  [15] Acik M, Mattevi C, Gong C, et al. ACS Nano., 2010, 4(10): 5861-5868
16. [16]
  [16] Yao Y, Chen X, Guo H, et al. Appl. Surf. Sci., 2011, 257 (17):7778-7782
17. [17]
  [17] Lu G, Ocola L E, Chen J. Nanotechnology, 2009, 20(44): 445502
18. [18]
  [18] Ferrari A C. Solid State Commun., 2007, 143(1):47-57
19. [19]
  [19] WANG Zhi-Min(王智民), HAN Ji-Xin(韩基新), LIU Jing-Bo (刘静波). J. Inorg. Mater.(无机材料学报), 2002, 17(6):1187-1193
20. [20]
  [20] Marliere C, Poncharal P, Vaccarini L, et al. MRS Proceedings. Boston: Cambridge University Press, 1999, 593(1):173-179
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沈阳化工大学材料科学与工程学院沈阳 110142